|PHOSPHORUS TRICHLORIDE||ICSC: 0696 (August 1997)|
| CAS #: 7719-12-2
| UN #: 1809
|EC Number: 231-749-3
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Not combustible. Many reactions may cause fire or explosion. Gives off irritating or toxic fumes (or gases) in a fire.||NO contact with water.||NO hydrous agents. NO water. In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water.|
|AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Sore throat. Cough. Burning sensation. Nausea. Vomiting. Shortness of breath. Laboured breathing. Symptoms may be delayed. See Notes.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.|
|Skin||Pain. Redness. Blisters. Skin burns.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .|
|Eyes||Pain. Redness. Watering of the eyes. Severe deep burns. Loss of vision.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Burning sensation. Abdominal pain. Shock or collapse. Further see Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Do NOT induce vomiting. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations. Personal protection: chemical protection suit including self-contained breathing apparatus.||
According to UN GHS Criteria
|Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. See Chemical Dangers. Dry. Well closed. Ventilation along the floor.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|PHOSPHORUS TRICHLORIDE||ICSC: 0696|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.2 ppm as TWA; 0.5 ppm as STEL.
MAK: 0.57 mg/m3, 0.1 ppm; peak limitation category: I(1); pregnancy risk group: C
|Reacts violently with fire extinguishing agents such as water.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation are therefore essential.
Immediate administration of an appropriate inhalation therapy by a doctor, or by an authorized person, should be considered.
Symbol: T+, C; R: 14-26/28-35-48/20; S: (1/2)-7/8-26-36/37/39-45
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