Refrigerant gas R1114
|CAS #: 116-14-3|
| UN #: 1081
|EC Number: 204-126-9
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Highly flammable. Cylinder may explode in heat of fire. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion on contact with air. See Chemical Dangers. Gas/air mixtures are explosive.||NO open flames, NO sparks and NO smoking. NO contact with air. Closed system, ventilation, explosion-proof electrical equipment and lighting. Use non-sparking handtools.||Evacuate area, fight fires only from an explosion-resistant location. Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with water spray. In case of fire: keep cylinder cool by spraying with water.|
|AVOID ALL CONTACT!|
|Inhalation||Dizziness. Headache. Visual disturbances. Suffocation. Unconsciousness.||Use ventilation.||Fresh air, rest. Seek medical attention if you feel unwell.|
|Skin||ON CONTACT WITH LIQUID: FROSTBITE.||Cold-insulating gloves. Protective clothing.||ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer immediately for medical attention.|
|Eyes||ON CONTACT WITH LIQUID: FROSTBITE.||Wear face shield.||ON FROSTBITE: rinse with plenty of water. Refer immediately for medical attention.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Remove all ignition sources. Shut off cylinder if possible. Ventilation. Remove gas with fine water spray.||
According to UN GHS Criteria
DANGERExtremely flammable gas
Contains gas under pressure; may explode if heated
May cause cancer if inhaled
May cause damage to kidneys, liver and blood if inhaled
|Fireproof. Cool. Keep in a well-ventilated room. Refer to the manufacturer's instructions for proper storage conditions. Separated from : see Chemical Dangers.|
|Transport only if stabilized.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 8.2 mg/m3, 2 ppm, as TWA; A3 (confirmed animal carcinogen with unknown relevance to humans).
MAK: carcinogen category: 2
|Check oxygen content before entering area.
High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.
If not stabilized, the substance may spontaneously polymerize on contact with air and under the influence of increasing temperature and/or pressure. Consult your supplier.
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|