Highly flammable. Vapour/air mixtures are explosive.
NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling.
Use water spray, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.
Cough. Sore throat.
Use ventilation, local exhaust or breathing protection.
Fresh air, rest.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
Wear safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Nausea. Diarrhoea. Vomiting.
Do not eat, drink, or smoke during work.
Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .
CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Ventilation. Remove all ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer. Remove vapour with fine water spray.
According to UN GHS Criteria
Transportation UN Classification
UN Hazard Class: 3; UN Pack Group: II
Fireproof. Well closed. Cool.
PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH CHARACTERISTIC ODOUR.
Physical dangers The vapour mixes well with air, explosive mixtures are easily formed.
Chemical dangers The substance can presumably form explosive peroxides. The substance may polymerize due to warming and under the influence of inorganic acids and bases. This generates fire or explosion hazard.
Formula: C5H10O / CH3(CH2)3CHO
Molecular mass: 86.1
Boiling point: 103°C Melting point: -91°C Relative density (water = 1): 0.8 Solubility in water, g/100ml at 20°C: 1.4 (moderate) Vapour pressure, kPa at 20°C: 3.4 Relative vapour density (air = 1): 3 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.07 Flash point: 12°C o.c. Auto-ignition temperature: 222°C Explosive limits, vol% in air: 1.4-7.2 Octanol/water partition coefficient as log Pow: 1.31
EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour.
Effects of short-term exposure The substance is irritating to the eyes, skin and respiratory tract.
Inhalation risk A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20°C.
Effects of long-term or repeated exposure
OCCUPATIONAL EXPOSURE LIMITS
TLV: 50 ppm as TWA
The substance is harmful to aquatic organisms.
Check for peroxides prior to distillation; eliminate if found.
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