ICSC 1380 - NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (<0.1% w/w BENZENE)

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NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (<0.1% w/w BENZENE)	ICSC: 1380 (November 2023)
Low boiling point hydrogen treated naphtha Naphtha (petroleum), hydrotreated heavy (C6-C13)

CAS #: 64742-48-9

UN #: 3295

EC Number: 265-150-3

	ACUTE HAZARDS	PREVENTION	FIRE FIGHTING
FIRE & EXPLOSION	Flammable. Vapour/air mixtures are explosive. Risk of fire and explosion on contact with strong oxidants.	NO open flames, NO sparks and NO smoking. NO contact with oxidizing agents. Above 40°C use a closed system, ventilation and explosion-proof electrical equipment. Prevent build-up of electrostatic charges (e.g., by grounding).	Use water spray, alcohol-resistant foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.

PREVENT GENERATION OF MISTS!
	SYMPTOMS	PREVENTION	FIRST AID
Inhalation	Cough. Shortness of breath. Euphoria. Headache. Dizziness. Drowsiness. Unconsciousness.	Use ventilation, local exhaust or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	Redness. Dry skin.	Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower. Rinse and then wash skin with water and soap.
Eyes	Redness.	Wear safety spectacles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Ingestion	Aspiration hazard! Sore throat. Nausea. Vomiting. Abdominal pain. Further see Inhalation.	Do not eat, drink, or smoke during work.	Rinse mouth. Give nothing to drink. Do NOT induce vomiting. Refer immediately for medical attention. See Notes.

SPILLAGE DISPOSAL	CLASSIFICATION & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.	According to UN GHS Criteria DANGER Flammable liquid and vapour May be fatal if swallowed and enters airways Toxic to aquatic life See Notes Transportation UN Classification UN Hazard Class: 3; UN Pack Group: III
STORAGE
Fireproof. Well closed. Store only in original container. Separated from strong oxidants.
PACKAGING

NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (<0.1% w/w BENZENE)

ICSC: 1380

PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID WITH MILD ODOUR. Physical dangers Chemical dangers Reacts with strong oxidants. This generates fire and explosion hazard. This produces irritating or toxic fumes (or gases).	Boiling point: 65-230°C Melting point: -60°C Density: 0.62-0.88 g/cm³ Solubility in water: none Vapour pressure, kPa at 20°C: 0.1-0.3 Flash point: 40-62 °C c.c. (technical grade) Auto-ignition temperature: 255-270°C Explosive limits, vol% in air: 0.7-6.0 Viscosity: 1 mm²/s at 25°C

PHYSICAL & CHEMICAL INFORMATION

Physical State; Appearance
COLOURLESS LIQUID WITH MILD ODOUR.

Physical dangers

Chemical dangers
Reacts with strong oxidants. This generates fire and explosion hazard. This produces irritating or toxic fumes (or gases).

Boiling point: 65-230°C
Melting point: -60°C
Density: 0.62-0.88 g/cm³
Solubility in water: none
Vapour pressure, kPa at 20°C: 0.1-0.3
Flash point: 40-62 °C c.c. (technical grade)
Auto-ignition temperature: 255-270°C
Explosive limits, vol% in air: 0.7-6.0
Viscosity: 1 mm²/s at 25°C

EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour and by ingestion. Effects of short-term exposure The substance is mildly irritating to the eyes, skin and respiratory tract. The substance may cause effects on the central nervous system. Exposure to high concentrations of vapour could cause unconsciousness. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. See Notes.	Inhalation risk A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C. Effects of long-term or repeated exposure The substance defats the skin, which may cause dryness or cracking. See Notes.

EXPOSURE & HEALTH EFFECTS

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour and by ingestion.

Effects of short-term exposure
The substance is mildly irritating to the eyes, skin and respiratory tract. The substance may cause effects on the central nervous system. Exposure to high concentrations of vapour could cause unconsciousness. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis. See Notes.

Inhalation risk
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.

Effects of long-term or repeated exposure
The substance defats the skin, which may cause dryness or cracking. See Notes.

OCCUPATIONAL EXPOSURE LIMITS
MAK: 300 mg/m³, 50 ppm; peak limitation category: II(2); pregnancy risk group: D

ENVIRONMENT
The substance is toxic to aquatic organisms.

NOTES
Ingestion of this substance, regardless of the amount ingested, can cause aspiration and thus risk of chemical pneumonitis. The symptoms of chemical pneumonitis do not become manifest until a few hours or even a few days have passed. Depending on the raw material and the production processes, the composition and physical properties of this solvent can vary considerably. The GHS classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1% w/w benzene (see also ICSC 0015). The GHS classification as a reproductive and developmental toxicity need not apply if substance contains less than 3% w/w toluene (see also ICSC 0078) and/or n-hexane (see also ICSC 0279).

NOTES

Ingestion of this substance, regardless of the amount ingested, can cause aspiration and thus risk of chemical pneumonitis.
The symptoms of chemical pneumonitis do not become manifest until a few hours or even a few days have passed.
Depending on the raw material and the production processes, the composition and physical properties of this solvent can vary considerably.
The GHS classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1% w/w benzene (see also ICSC 0015). The GHS classification as a reproductive and developmental toxicity need not apply if substance contains less than 3% w/w toluene (see also ICSC 0078) and/or n-hexane (see also ICSC 0279).

ADDITIONAL INFORMATION

EC Classification

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