|CAS #: 100-40-3|
| UN #: 1993
|EC Number: 202-848-9
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Highly flammable. Vapour/air mixtures are explosive.||NO open flames, NO sparks and NO smoking. NO contact with oxidizing agents. Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling.||Use foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|Inhalation||Cough. Headache.||Use ventilation, local exhaust or breathing protection.||Fresh air.|
|Skin||Redness.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse skin with plenty of water or shower.|
|Eyes||Redness.||Wear safety goggles or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Aspiration hazard!||Do not eat, drink, or smoke during work.||Do NOT induce vomiting. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Consult an expert! Remove all ignition sources. Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in dry sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
DANGERHighly flammable liquid and vapour
Causes skin irritation
Suspected of causing cancer
May be fatal if swallowed and enters airways
Toxic to aquatic life with long lasting effects
|Fireproof. Separated from oxidants. Cool. Store only if stabilized. Well closed.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C6H9CH=CH2 / C8H12
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.1 ppm as TWA; A3 (confirmed animal carcinogen with unknown relevance to humans).
MAK: skin absorption (H); carcinogen category: 2
|The substance is toxic to aquatic organisms. Bioaccumulation of this chemical may occur along the food chain, for example in fish.|
|Do NOT take working clothes home.
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
Check for peroxides prior to distillation; eliminate if found.
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|