Fresh air, rest. Half-upright position. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
Watering of the eyes. Redness. Pain. Blurred vision.
Wear safety goggles or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Abdominal pain. Burning sensation in the throat and chest. Cough. Diarrhoea. Nausea. Vomiting.
Do not eat, drink, or smoke during work.
Rinse mouth. Give one or two glasses of water to drink. Refer for medical attention .
CLASSIFICATION & LABELLING
Evacuate danger area! Personal protection: complete protective clothing including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable containers as far as possible. Wash away remainder with plenty of water.
According to UN GHS Criteria
Transportation UN Classification
UN Hazard Class: 6.1; UN Subsidiary Risks: 3; UN Pack Group: II
Separated from strong oxidants and food and feedstuffs. Well closed. Keep in a well-ventilated room.
Do not transport with food and feedstuffs.
PHYSICAL & CHEMICAL INFORMATION
Physical State; Appearance COLOURLESS LIQUID. TURNS VIOLET ON EXPOSURE TO LIGHT.
Chemical dangers Decomposes on burning. This produces toxic fumes including hydrogen bromide. Reacts with oxidants.
Molecular mass: 137.0
Boiling point: 137°C Melting point: -36.5°C Relative density (water = 1): 1.63 Solubility in water: poor Vapour pressure, kPa at 20°C: 1.1 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.04 Flash point: 51.1°C Octanol/water partition coefficient as log Pow: 0.11
EXPOSURE & HEALTH EFFECTS
Routes of exposure The substance can be absorbed into the body by inhalation of its vapour and by ingestion.
Effects of short-term exposure Lachrymation. The substance is severely irritating to the eyes, skin and respiratory tract.
Inhalation risk No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.
Effects of long-term or repeated exposure See Notes.
OCCUPATIONAL EXPOSURE LIMITS
Health effects of exposure to the substance have not been investigated adequately.
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