|CHLOROSULFONIC ACID||ICSC: 1039 (October 2001)|
| CAS #: 7790-94-5
| UN #: 1754
|EC Number: 232-234-6
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Not combustible but enhances combustion of other substances. Many reactions may cause fire or explosion. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion on contact with many substances.||NO contact with alcohol, combustible substances, reducing agents or water.||In case of fire in the surroundings, use appropriate extinguishing media. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water.|
|PREVENT GENERATION OF MISTS! AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing. Symptoms may be delayed. See Notes.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.|
|Skin||Pain. Redness. Serious skin burns.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .|
|Eyes||Pain. Redness. Severe deep burns.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Burning sensation. Abdominal pain. Nausea. Shock or collapse.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Ventilation. Collect leaking liquid in sealable containers. Cautiously neutralize remainder with alkaline materials, crushed limestone, sodium bicarbonate or soda ash. Then wash away with plenty of water. Do NOT absorb in saw-dust or other combustible absorbents.||
According to UN GHS Criteria
|Separated from food and feedstuffs. See Chemical Dangers. Dry. Well closed.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|CHLOROSULFONIC ACID||ICSC: 1039|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: ClHO3S / SO2(OH)Cl
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
|Reacts violently with fire extinguishing agents such as water.
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation are therefore essential.
Depending on the degree of exposure, periodic medical examination is suggested.
Symbol: C; R: 14-35-37; S: (1/2)-26-45
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