|CYCLOPENTADIENYL MANGANESE TRICARBONYL||ICSC: 0977 (May 2010)|
| CAS #: 12079-65-1
| UN #: 3466
|EC Number: 235-142-4
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Heating will cause rise in pressure with risk of bursting.||NO open flames.||Use powder, alcohol-resistant foam, water spray, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|See EFFECTS OF LONG-TERM OR REPEATED EXPOSURE. PREVENT DISPERSION OF DUST! STRICT HYGIENE!|
|Inhalation||Cough. Convulsions.||Avoid inhalation of dust. Use local exhaust or breathing protection.||Fresh air, rest. Refer immediately for medical attention.|
|Skin||Redness.||Protective gloves.||Remove contaminated clothes. Rinse and then wash skin with water and soap.|
|Eyes||Redness.||Wear safety goggles or eye protection in combination with breathing protection if powder.||Rinse with plenty of water (remove contact lenses if easily possible). Refer for medical attention.|
|Ingestion||Convulsions.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Give one or two glasses of water to drink. Refer immediately for medical attention.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: complete protective clothing including self-contained breathing apparatus. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
DANGERFatal if swallowed or if inhaled
Causes damage to the lungs and the central nervous system through prolonged or repeated exposure if inhaled
|Separated from strong oxidants and food and feedstuffs.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|CYCLOPENTADIENYL MANGANESE TRICARBONYL||ICSC: 0977|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C8H5MnO3 / C5H5Mn(CO)3
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
|TLV: (as Mn): 0.1 mg/m3, as TWA; (skin)|
|Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken.
Do NOT take working clothes home.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|