|NITROGLYCERIN||ICSC: 0186 (June 2015)|
| CAS #: 55-63-0
| UN #: 0143 (desensitized)
|EC Number: 200-240-8
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Many reactions may cause fire or explosion. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion. Explosive.||NO open flames, NO sparks and NO smoking. NO contact with hot surfaces. Closed system, ventilation, explosion-proof electrical equipment and lighting. Use non-sparking handtools. Do NOT expose to friction or shock.||Use water spray, powder, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position.|
|STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Headache. Nausea. Flushing of the face. Dizziness.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Flushing of the face. Headache. Dizziness. Nausea. Vomiting. Shock or collapse.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer immediately for medical attention.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: complete protective clothing including self-contained breathing apparatus. Remove all ignition sources. Do NOT wash away into sewer. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
DANGERExplosive; mass explosion hazard
Fatal if swallowed or in contact with skin
May cause damage to cardiovascular system
May cause damage to heart through prolonged or repeated exposure
Toxic to aquatic life
|Store only if stabilized. Store in an area without drain or sewer access. Fireproof. Well closed. Separated from food and feedstuffs.|
|Do not transport with food and feedstuffs.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C3H5N3O9 / C3H5(NO3)3
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.05 ppm as TWA; (skin).
MAK: 0.094 mg/m3, 0.01 ppm; peak limitation category: II(1); skin absorption (H); carcinogen category: 3; pregnancy risk group: C.
EU-OEL: 0.095 mg/m3, 0.01 ppm as TWA; 0.19 mg/m3, 0.02 ppm as STEL; (skin)
|The substance is toxic to aquatic organisms.|
|Combustion in a confined space may turn into detonation.
Use of alcoholic beverages enhances the harmful effect.
Other UN numbers are: UN 0144 Nitroglycerin, solution in alcohol with more than 1% but not more than 10% nitroglycerin; UN Haz Class 1.1D.
UN 1204 Nitroglycerin, solution in alcohol with not more than 1% of nitroglycerin; UN Haz Class 3, Pack Group II.
UN 3064 Nitroglycerin, solution in alcohol with more than 1% but not more than 5% of nitroglycerin, UN Haz Class 3, Pack Group II.
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
Symbol: E, T+, N; R: 3-26/27/28-33-51/53; S: (1/2)-33-35-36/37-45-61
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