|ALLYL ALCOHOL||ICSC: 0095 (April 2000)|
| CAS #: 107-18-6
| UN #: 1098
|EC Number: 203-470-7
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Flammable. Above 21°C explosive vapour/air mixtures may be formed.||NO open flames, NO sparks and NO smoking. Above 21°C use a closed system, ventilation and explosion-proof electrical equipment.||Use water in large amounts, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|STRICT HYGIENE! PREVENT GENERATION OF MISTS!|
|Inhalation||Headache. Nausea. Vomiting.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest.|
|Skin||MAY BE ABSORBED! Pain. Blisters.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap.|
|Eyes||Redness. Pain. Blurred vision. Loss of vision. Severe deep burns. Photophobia.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Unconsciousness.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Give one or two glasses of water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: complete protective clothing including self-contained breathing apparatus. Remove all ignition sources. Do NOT let this chemical enter the environment. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Fireproof. Separated from strong oxidants and food and feedstuffs.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|ALLYL ALCOHOL||ICSC: 0095|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C3H6O / CH2=CHCH2OH
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.5 ppm as TWA; (skin); A4 (not classifiable as a human carcinogen).
EU-OEL: 4,8 mg/m3, 2 ppm as TWA; 12,1 mg/m3, 5 ppm as STEL; (skin).
MAK: skin absorption (H); carcinogen category: 3
|The substance is very toxic to aquatic organisms.|
|Depending on the degree of exposure, periodic medical examination is suggested.
The odour warning when the exposure limit value is exceeded is insufficient.
Symbol: T, N; R: 10-23/24/25-36/37/38-50; S: (1/2)-36/37/39-38-45-61
|All rights reserved. The published material is being distributed without warranty of any kind, either expressed or implied. Neither ILO nor WHO nor the European Commission shall be responsible for the interpretation and use of the information contained in this material.|