|CAS #: 123-91-1|
| UN #: 1165
|EC Number: 204-661-8
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire. Vapour/air mixtures are explosive. Risk of fire and explosion on contact with incompatible substances. See Chemical Dangers.||NO open flames, NO sparks and NO smoking. NO contact with strong oxidizing agents. NO contact with hot surfaces. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling. Use non-sparking handtools.||Use powder, alcohol-resistant foam, water spray, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|PREVENT GENERATION OF MISTS!|
|Inhalation||Cough. Sore throat. Nausea. Dizziness. Headache. Drowsiness. Vomiting. Unconsciousness. Abdominal pain.||Use ventilation (not if powder), local exhaust or breathing protection.||Fresh air, rest. Refer immediately for medical attention.|
|Skin||MAY BE ABSORBED!||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse skin with plenty of water or shower.|
|Eyes||Redness. Pain.||Wear face shield or eye protection in combination with breathing protection.||Rinse with plenty of water for several minutes (remove contact lenses if easily possible).|
|Ingestion||See Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Do NOT induce vomiting. Seek medical attention if you feel unwell.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking liquid in sealable air tight containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer.||
According to UN GHS Criteria
DANGERHighly flammable liquid and vapour
Causes eye irritation
May cause respiratory irritation
Suspected of causing cancer
May be harmful if swallowed and enters airways
|Fireproof. Separated from strong oxidants, strong acids and incompatible materials. Cool. Dry. Well closed. Keep in the dark. Store only if stabilized. Store in an area without drain or sewer access.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 20 ppm as TWA; (skin); A3 (confirmed animal carcinogen with unknown relevance to humans).
MAK: 37 mg/m3, 10 ppm; peak limitation category: I(2); skin absorption (H); carcinogen category: 4; pregnancy risk group: C.
EU-OEL: 73 mg/m3, 20 ppm as TWA
|Refer for medical attention if breathing difficulties and/or fever develop.
Check for peroxides prior to distillation; eliminate if found.
Symbol: F, Xn; R: 11-19-36/37-40-66; S: (2)-9-16-36/37-46; Note: D
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