|CAS #: 460-19-5|
| UN #: 1026
|EC Number: 207-306-5
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire. Gas/air mixtures are explosive. Risk of fire and explosion on contact with strong oxidizing agents.||NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting.||Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with dry powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water.|
|AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Convulsions. Cough. Dizziness. Headache. Laboured breathing. Sore throat. Unconsciousness. Vomiting.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. No mouth-to-mouth artificial respiration. Refer for medical attention. See Notes.|
|Skin||ON CONTACT WITH LIQUID: FROSTBITE.||Cold-insulating gloves.||ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .|
|Eyes||Redness. Pain.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: gas-tight chemical protection suit including self-contained breathing apparatus. Ventilation. Remove all ignition sources. NEVER direct water jet on liquid.||
According to UN GHS Criteria
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 5 ppm as STEL.
MAK: 11 mg/m3, 5 ppm; peak limitation category: II(2); skin absorption (H); pregnancy risk group: D
|The substance is very toxic to aquatic organisms.|
|Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
The odour warning when the exposure limit value is exceeded is insufficient.
Turn leaking cylinder with the leak up to prevent escape of gas in liquid state.
Symbol: F, T, N; R: 11-23-50/53; S: (1/2)-23-45-60-61
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