|CAS #: 78-95-5|
| UN #: 1695 (stabilized)
|EC Number: 201-161-1
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 35°C explosive vapour/air mixtures may be formed.||NO open flames, NO sparks and NO smoking. Above 35°C use a closed system, ventilation and explosion-proof electrical equipment.||Use water spray, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.|
|Inhalation||Sore throat. Cough. Burning sensation. Shortness of breath.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Redness. Pain. Blisters. See Notes.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .|
|Eyes||Redness. Watering of the eyes. Pain. Burns.||Wear face shield or eye protection in combination with breathing protection.||Rinse with plenty of water for several minutes (remove contact lenses if easily possible). Refer immediately for medical attention.|
|Ingestion||Burning sensation in the throat and chest.||Do not eat, drink, or smoke during work.||Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Ventilation. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
Flammable liquid and vapour
Toxic if swallowed
Fatal in contact with skin or if inhaled
Causes skin irritation
Causes serious eye damage
May cause respiratory irritation
|Store only if stabilized. Fireproof. Separated from strong oxidants and food and feedstuffs. Keep in the dark.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C3H5ClO / ClCH2COCH3
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
|TLV: 1 ppm as STEL; (skin)|
|After contact with liquid blister formation may be delayed until several hours have passed.
Explosive limits are unknown in literature, although the substance is combustible and has a flash point < 61°C.
The occupational exposure limit value should not be exceeded during any part of the working exposure.
The odour warning when the exposure limit value is exceeded is insufficient.
An added stabilizer or inhibitor can influence the toxicological properties of this substance; consult an expert.
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