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1975

CIS 76-1222 Korol'čenko A.Ja., Ivanov A.V., Aristova E.M.
Fire and explosion hazards of fluorene and its derivatives
Požaro- i vzryvoopasnost' fluorena i ego proizvodnyh [in Russian]
Results of research to establish flammability limts and the lower explosive limits of aerosols of fluorene and its derivatives. Aerogels (except for those of 2-dimorpholinoacetylfluorenone) do not ignite when in contact with weak sources of energy, but aerosols liberated at temperatures above the melting point are easily flammable. The flammability of aerogels of fluorene derivatives depends on the nature of the aliphatic substituent in the lateral chain. The explosibility of the aerosols of these derivatives can be inhibited by the presence of 2 bromine atoms or the SO₃Na group in the molecule.
Himičeskaja promyšlennost', Dec. 1975, No.12, p.23. 6 ref.

CIS 76-1219 Fire protection in storage depots for highly flammable liquids and liquid fuel
Protection contre le feu dans les parcs de stockage de liquides facilement inflammables et de carburants liquides. [in French]
Translation of: Brandschutz in Tanklagern für leichtentzündliche Flüssigkeiten und Flüssigtreibstoffe. Communication by the USSR delegation to the 8th Symposium of the International Technical Committee for the Prevention and Extinction of Fire (CTFI), Luxembourg, 25-29 Sep. 1974. Photocopy. 31p. Illus. 7 ref. A system of measures determined by the Government has been established in the USSR for protecting liquid fuel depots against fire hazards. Principal causes of fire outbreaks (dangerous concentration of air/vapour mixtures in tanks; calculation of hazard; calculation of time between fire outbreak and projection of tank contents; calculation of area of explosion hazard zones). Fire protection methods (prevention of loss of petroleum products; protection of tanks against overpressure and underpressure, etc.). General directives for the layout and equipment of storage depots. Calculation of safe distances. Fire extinguishing systems.
Traduction INRS 96 B-75, Institut national de recherche et de sécurité, 30 rue Olivier-Noyer, 75680 Paris Cedex 14, France, 1975. 36p. Illus. 7 ref.

CIS 76-1218 Gonzalbez P.B.
Ministry of Labour, General Directorate of Social Services, Occupational Safety and Health Social Service, (Ministerio de Trabajo, Dirección General de Servicios Sociales, Servicio Social de Higiene y Seguridad del Trabajo), Madrid.
Fire and explosion hazards with power transformers
Riesgos de incendio y explosión en transformadores de potencia [in Spanish]
This information sheet is devoted to the prevention of fires and explosions which may occur (a) in mineral oil-cooled high-voltage (2,000kVA or over) power transformers (flashpoint of mineral oil 130-140°C; causes of fires and explosions (overloading; overheating; insufficient ventilation; electric arc due to rupture of installation; faulty insulation; short circuit); prevention; diagrams of safety systems and circuits) and (b) in low-voltage distribution transformers cooled with pyralene (a polychlorinated biphenyl). Disadvantages of pyralene (human toxicity in liquid and vapour form, release of toxic gas in contact with electric arc); hazards of transformer overloading, overheating and short circuits. Permissible durations of overloading of oil-cooled transformers and a list of insulating materials with their characteristic properties are appended in tabular form.
Documento D-11-75, Centro Nacional de Información y Documentación, Servicio Social de Higiene y Seguridad del Trabajo, Instituto Territorial, Barcelona, Spain, 1975. 22p. Illus. 5 ref.

CIS 76-1215 Losansky G.
Protection against the fire hazard associated with the use of liquefied petroleum gases on building sites
Protection contre l'incendie lors de l'utilisation des gaz de pétrole liquéfiés sur les chantiers. [in French]
Translation of: Brandschutz beim Umgang mit Flüssiggas auf Baustellen. Hochbau, München, Germany (Fed.Rep.), Jan.-Feb. 1974, Vol.62, No.1, p.9-13 and 19. Illus. (CIS 74-1212). Review of the major causes of fire: recommendations concerning portable dry powder or CO₂ extinguishers; fire prevention and fire fighting techniques.
Traduction INRS 41 B-75, Institut national de recherche et de sécurité, 30 rue Olivier-Noyer, 75680 Paris Cedex 14, France, 1975. 15p. Illus.

CIS 76-1436 Arhangel'skij Ju.A., Kogan Ė.I., Hajkin V.A.
Occupational safety and fire protection in road transport undertakings
Ohrana truda i protivopožarnaja zaščita na avtomobil'nom transporte [in Russian]
Contents: Soviet occupational safety and health regulations; occupational safety and health organisation; training in occupational safety and health; notification and statistics of occupational accidents; analysis of occupational accidents and diseases; safety rules for garages and maintenance and repair shops; personal protective equipment; ventilation, heating and lighting; noise and vibration; layout and design of workposts and workers' welfare; safe work with compressed gases and gaseous fuels; antifreeze mixtures, brake fluids, acids, etc.; prevention of accidents during loading and unloading, and transport; pressure vessels and equipment under pressure; electrical safety; fire protection.
Izdatel'stvo "Transport", Basmannyj tup. 6a, Moskva B-174, USSR, 1975. 176p. Illus. Price: Rbl.0.55.

CIS 76-1079 Truffert L., Girard-Wallon C., Ripault J., Tarneaud M.
Research on an experimental method of assessing toxic hazards of thermal decomposition or of combustion of various materials
Recherche d'une méthode expérimentale permettant d'évaluer les dangers toxiques liés à la décomposition thermique ou à la combustion de divers matériaux. [in French]
Description of an experimental method and device allowing various materials, especially wood-based, to be tested in realistic conditions. Tests employing this method were carried out in mice with natural wood and bonded materials containing 80% wood (standard grade, water-proof grade, fire-proof grade, grade covered with a decorative film). The strict conditions of the tests (low rate of air renewal, large heat supply and quantity of material employed) permitted the degree of carbon monoxide intoxication measured in the mice that died to be established as sole cause of death, although it may have been accelerated by the action of other toxic or harmful agents.
Archives des maladies professionnelles, Sep. 1975, Vol.36, No.9, p.457-464. Illus.

CIS 76-925 Young R.A., Nash P.
The testing of sprinkler installations.
This paper deals with the testing of some sprinkler system components to the requirements of the installation tests and maintenance procedures of the British Fire Offices' Committee. The approval tests described are concerned with wet and dry pipe alarm valves, the water motor and pressure switches. There follow some considerations on false alarms, requirements on installation of a system, proving tests of water supplies, and maintenance of automatic sprinkler systems.
CP 77/75, Building Research Establishment, Fire Research Station, Borehamwood, Hertfordshire WD6 2BL, United Kingdom, Aug. 1975. 9p. Illus. 4 ref.

CIS 76-914 Nash P., Young R.A.
The testing of sprinklers.
British test procedures for the approval of new sprinkler design, annual tests and follow-up tests are described. They are based largely on the procedures of the British Joint Fire Research Organisation and a standard of the Comité européen des assurances. After examination of the marking and metal quality a sprinkler is subjected to the following tests: pressure test, functional test, thermal tests (hot-air wind tunnel and heated-bath tests), physical tests (fatigue test, thermal shock, strength of glass bulb and frame), chemical corrosion tests, flow and distribution tests. In the USA there are some additional tests, especially a fire test and hydraulic tests.
CP 78/75, Building Research Establishment, Fire Research Station, Borehamwood, Hertfordshire WD6 2BL, United Kingdom, Aug. 1975. 9p. Illus. 7 ref.

CIS 76-913 Fire prevention code 1975.
This Code was drawn up to meet the need expressed for a document covering all aspects of fire protection and prevention in buildings, ships and vehicles, incorporating all other NFPA standards and codes. Contents: administration and enforcement; right of entry and inspection (industrial buildings, marine vessels, etc.); definitions; general fire safety regulations. There are 12 appendices listing NFPA standards, codes and publications, giving the text of fire safety regulations, etc., covering such aspects as: fire protection in drycleaning plants, hospitals, on piers and wharves; flammable and combustible liquids, compressed and liquefied gases, hazardous materials and processes, transport, fire extinguishing systems, portable fire extinguishers, storage, building construction, etc.
NFPA No. 1-1975, National Fire Protection Association, 470 Atlantic Avenue, Boston, Massachusetts 02210, USA, 1975. 95p. 210 ref. Price: US-$3.50.

CIS 76-624 Robertson J.C.
Introduction to fire prevention.
This textbook summarises the administrative, legal and organisational aspects of fire prevention and fire protection in the light of conditions prevailing in the USA. It does not include technical data on fire hazards, fire prevention techniques, fire detection and protection systems and equipment, or fire fighting. Its 14 chapters include an account of the efforts devoted by the private and public sectors, an outline of the codes and regulations in force in the USA, and advice on the compilation of fire statistics and on inspection procedures, etc.
Glencoe Press, 8701 Wilshire Boulevard, Beverly Hills, California 90211, USA, 1975. 318p. Illus. 88 ref. Price: US-$10.95.

CIS 76-623 Pardon N., Pommier, Perrot M.P., De Frémont H., Ogier J., François R.C., Lebeaupin R., Monsaingeon A., Bansillon.
Fire and burns at work
Incendie et brûlures au travail. [in French]
This number, largely concerned with the problems of burns, groups a series of articles constituting a multidisciplinary approach to this question. Contents: burns as occupational accidents; the plant physician and risk of burns; clothing and fire; personal protection against thermal burns; fire protection and prevention of hazard; electrical burns; resuscitation, measures against shock and laboratory tests in victims of severe burns; development of treatment of burns in France over the past decades; arguments in favour of burn treatment centres.
Cahiers de médecine interprofessionnelle, 2nd quarter 1975, Vol.15, No.58, p.5-75. 99 ref.

CIS 76-622
Ministry of the Quality of Life (Ministère de la qualité de la vie), Paris.
Circular of 17 April 1975 concerning underground storage tanks for flammable liquids (scheduled undertakings)
Circulaire du 17 avril 1975 relative aux réservoirs enterrés dans lesquels sont emmagasinés des liquides inflammables (établissements classés). [in French]
This circular repeals and replaces the instructions of 17 July 1973. Contents: scope; provisions applying to new installations (definitions; construction of trench, tank, pipes, etc.); installations and fittings (buried tanks, entrenched tanks, etc.; unearthing of tanks (prior ventilation); earthing (electric hazard); gauging of contents; pipes; vents; leakage detection, etc.); location of storage tanks (safe distances); provisions applying to installations already officially approved or notified (compliance with specifications, etc.). Schedules: list of other types of fuel storage tanks to which the circular also applies; periodic inspection and testing (form of certificate).
Journal officiel de la République française, 19 June 1975, Vol.107, No.141, p.6096-6102.

CIS 76-777 Wiessner K.
Consideration of the particular physiological properties of PTFE in the transformation of PTFE semi-finished and finished products
Berücksichtigung der besonderen physiologischen Eigenschaften von PTFE bei Verarbeitung von PTFE-Halbzeugen und -Fertigteilen [in German]
Semi-finished products of polytetrafluoroethylene (PTFE) are processed by machining or hot moulding. PTFE presents no health hazards between -190 and +260°C; at higher temperatures toxic decomposition products occur (mainly perfluoroisobutene and fluorophosgenes above 380°C). The hazards of work with PTFE are: inhalation of pyrolysis products through smoking contaminated tobacco (prohibition of smoking during machining); uncontrolled heating of PTFE products (measures: good ventilation, temperature controls: colour change of PTFE at 327°C; local exhaust ventilation; prohibition of work with naked flame). Respiratory protective masks must be worn in the event of PTFE fires.
Maschinenbautechnik, Apr. 1975, Vol.24, No.4, p.188-189. Illus. 12 ref.

CIS 76-621 Reichel H.
Determination of the ignition temperature of combustible solids
Zur Ermittlung der Entflammungstemperatur brennbarer Feststoffe [in German]
An apparatus similar to that recommended by ASTM (American Society for Testing Materials) D 1969-62-T for determination of the ignition temperature of solids is described. Ignition temperature was determined as a function of the quantity of air. Results are compared with those of other testing methods.
Unser Brandschutz, wissenschaftlich-technische Beilage 2/1975, p.20-22. Illus. 4 ref.

CIS 76-620 Fire prevention - Principal legislative texts
Prévention des incendies - Principaux textes réglementaires. [in French]
List of relevant legislative texts drawn up by the legal department of the French National Research and Safety Institute (INRS). They are classified under the following heads: fire-extinguishing equipment; protection of workers (general provisions applicable to all establishments, electricity, lifting equipment, flammable liquids, paints and varnishes, explosive substances and dust); legislation and regulations concerning dangerous, harmful or offensive establishments (refineries, storehouses, underground tanks); establishments open to the public; high-rise buildings; residential buildings; explosive atmospheres. Brief notes on content of each text.
Travail et sécurité, June 1975, No.6, p.331-334. 26 ref.

CIS 76-618 Denisenko G.F., Fajnštejn V.I.
Safe working methods in oxygen production
Tehnika bezopasnosti pri proizvodstve kisloroda [in Russian]
Contents: description of explosions which have occurred in plants for the fractional distillation of air; dangerous substances mixed with air (hydrocarbons, etc.); measures for preventing explosions (air purification by adsorption, catalytic oxidation, etc.); flammability and explosibility of substances which can mix with oxygen; recommendations concerning materials used in fractional distillation plant (lubricants, insulating materials, metals used for valves and fittings, safe working methods to be observed in operating, etc.); compressors and pressure-reducing devices, in maintenance and repair work, in filling and transporting oxygen containers and in handling liquefied gases; degreasing of surfaces in contact with oxygen.
Izdatel'stvo "Metallurgija", 2-j Obydenskij per. 14, 119034 Moskva G-34, USSR, 2nd edition 1975. 272p. Illus. 105 ref. Price: Rbl.0.86.

CIS 76-616 Suter T.
Floating-roof tanks - Greater safety in petrol storage
Membrantanks - Erhöhte Sicherheit bei der Lagerung von Benzin [in German]
This report presents the arguments in favour of the construction of a floating roof inside storage tanks and deals with safety problems associated with the use of upright tanks. It describes gas concentration measurements undertaken in a specific case, the results obtained and the conclusions drawn. Ventilation slots under the edge of the fixed roof and the ventilation system at its centre were found sufficient to prevent any hazardous concentration of petrol vapours between the floating and the fixed roof.
Wasser-Boden-Luft-Umweltschutz, Autumn 1975, Vol.11, No.2, p.20-26. Illus.

CIS 76-615 Sibilev M.S., Svistunov N.P., Aksenov M.S.
Reference manual for fire safety and fire protection in the chemical industry, the petroleum processing industry and petrochemical industries
Spravočnik po požarnoj bezopasnosti i protivopožarnoj zaščite na predprijatijah himičeskoj, neftepererabatyvajuščej i neftehimičeskoj promyšlennosti [in Russian]
Contents: general fire safety rules (extracts from the Soviet regulations on the organisation of fire fighting); fire safety in research, planning and operation of plants and premises for the processing and storage of flammable liquids; rules, standards and recommendations concerning fire fighting.
Izdatel'stvo "Himija", Stromynka 13, 107076 Moskva, USSR, 1975. 455p. Illus. Price: Rbl.2.04.

CIS 76-826 Baumgärtel I.
Accident hazards in the use of combustible mould facings in foundries
Unfallgefahren beim Einsatz brennbarer Formstoffüberzüge in Giessereibetrieben [in German]
The risks of an accident during the use of mould facings (blacking, mould varnish) depend on the type of solvent employed. In view of the fire, explosion and intoxication risks, the author concentrates on paints based on alcohol and petrol: physical characteristics and hazards; storage of facings and solvents; limits imposed on quantities stored on site; receptacles for storage and transportation of facings; fire prevention; layout of the workplace for application of facings (elimination of potential ignition sources, ventilation, respiratory protection, etc.); skin protection; behaviour of workers. He warns against replacing flammable solvents by non-flammable but toxic chlorinated hydrocarbons. General use of rapid-drying, non-flammable mould facings based on non-toxic materials would be desirable.
Die Berufsgenossenschaft, Aug. 1975, Vol.27, No.8, p.304-309. Illus. 5 ref.

CIS 76-612 Fire safety training in health care institutions.
This manual stresses organisation and procedure in training employees of these institutions in preventing fire and in handling fire until professional firefighters arrive; in safeguarding patients, visitors and staff. It enjoins the executive officer and fire marshal first to organise; second, to set up a procedure and put it in writing; and third, to train and drill staff, obtaining help from local professional firefighters in these endeavours. Appendices: fire hazard inspection report; extinguishers; available motion pictures.
American Hospital Association, 840 North Lake Shore Drive, Chicago, Illinois 60611, USA, 1975. 51p. Illus. 19 ref. Price: US-$2.25.

CIS 76-733 Frant R.
Decomposition products released during welding
Ontledingsprodukten gedurende het lassen [in Dutch]
Literature survey of the questions of phosgene formation by electric arc heat and radiation (particularly at wavelengths >2,200Å) in welding metal parts cleaned with solvents in air and of the toxic effects of phosgene in lungs. Importance of alerting workers to recognise the warning odours of chlorine compounds which are formed simultaneously with phosgene. Safety recommendations (cleaning shops to be separate from welding shops, neutralisation of phosgene by blowing steam or ammoniac) and recommendations for medical supervision.
De veiligheid, July-Aug. 1975, Vol.51, No.7-8, p.337-338. 4 ref.

CIS 76-726 Van Stee E.W., Harris A.M., Horton M.L., Back K.C.
Effects of three vaporizable fire extinguishing agents on myocardial metabolism and cardiovascular dynamics in the anesthetized dog.
34 mongrel dogs were divided into 5 groups: (1) 6 served as O₂ controls; (2) 8 exposed to 27-75% bromotrifluoromethane (CBrF₃) in O₂; (3) 4 exposed to 27-75% N₂ in O₂; (4) 9 exposed to 4-12% bromochlorodifluoromethane (CBrClF₂) in O₂; and (5) 7 exposed to 0.3-1.0% chlorobromomethane (CH₂BrCl) in O₂. 38 variables reflecting cardiovascular dynamics and myocardial metabolism were monitored before, during and after 45-min exposures to the respective compounds. The most significant observation was the elevation of the coronary sinus blood PO₂ and O₂ content during exposure to CBrClF₂ or CH₂BrCl. Both of these variables increased in magnitude progressively during the exposures. The persistence of the effect after exposure was greater for CBrClF₂ than for CH₂BrCl. Exposure to CBrF₃, CBrClF₂ or CH₂BrCl may result in disturbances of myocardial energy metabolism that are connected to myocardial performance. Based on the concentration to which dogs must be exposed to elicit such responses, CBrF₃ was least effective and CH₂BrCl was most effective. The CBrClF₂ was intermediate between the two but closer to the CH₂BrCl than to the CBrF₃.
Toxicology and Applied Pharmacology, Oct. 1975, Vol.34, No.1, p.62-71. 23 ref.

CIS 76-532
Anvisningar nr. 19:4, National Board of Occupational Safety and Health (Kungliga Arbetarskyddsstyrelsen), Stockholm, Mar. 1975.
Carbon dioxide fire extinguishing plant - Directives for shipyards
Kolsyresläckningsanläggningar - Varvsanvisningar [in Swedish]
These directives apply to shipbuilding, repair, maintenance and alteration work and testing of vessels equipped with carbon dioxide fire extinguishing plant. Leakages of this gas may cause asphyxiation by displacing oxygen in confined spaces. Safety rules for shipbuilding, alterations, design and layout, ship repairs in dockyards and sea trials (safety locking of CO₂ plant during all structural work, display of notices of locking for safety, custody of keys, responsibility, etc.). A model certificate of locking for safety and unlocking is appended.
Liber Förlag, Fack, 16289 Vällingby, Sweden, 1975. 11p. Price: Swe-cr.5.25.

CIS 76-315 Stevens A.M.
Safe storage and handling - Flammable liquids.
Practical advice on working methods and precautions to prevent fire and explosion hazards, under the following major areas of concern: solvent room storage and dispensing; in-plant storage and transfer; point of final use; and waste disposal. 3 checklists are appended: storage room safety; in-plant storage and transfer; production line and point-of-use safety.
National Safety News, June 1975, Vol.111, No.6, p.78-82. Illus.

CIS 76-313 Fire protection guide on hazardous materials.
This volume includes the National Fire Protection Association's 5 basic guides: a list of flash-point indexes of approximately 8,800 trade name liquids; the fire hazard index for 1,300 flammable liquids, gases and volatile solids; data on fire, explosion and toxicity hazards of 416 chemicals; an alphabetical list of hazardous chemical reactions covering 3,440 mixtures of 2 or more chemicals; and a system for the identification of fire and related hazards of materials.
NFPA No.SPP-1C, National Fire Protection Association, 470 Atlantic Avenue, Boston, Massachusetts 02210, USA, 6th edition 1975. 1248p. 400 ref. Price: US-$10.50.

CIS 76-312 King R.
Major fire and explosion hazards in hydrocarbon processing plants.
Reference is made to a number of disasters caused by unconfined vapour cloud explosions involving large quantities of hydrocarbon gas or vapour mixed with air. The author considers in turn the factors which constitute the hazard inherent in hydrocarbon handling and processing plants and units (the hazard rating scale developed by the Dow Chemical Co. is discussed) and the special but not uncommon hazard presented by the sudden mixture of water with hot hydrocarbon liquid (or vice versa) resulting in the generation of steam and the development of considerable pressure surge.
Protection, Nov. 1975, Vol.12, No.9, p.11-14. 6 ref.

CIS 76-311 Scholl E.W.
Fire and explosion hazards with movable equipment for the removal of sawdust and wood shavings by exhaust draught
Brand- und Explosionsgefahren an fahrbaren Einzelabsauggeräten für Hobelspäne und Holzstaub [in German]
An introduction summarising the results of explosion experiments performed with sawdust and wood shavings of various dimensions in a specially designed recipient is followed by a description of experiments carried out with various types of local exhaust ventilation systems used in industry. The results obtained show that there is a fire hazard where there is a high proportion of fine dust and if the source of ignition has sufficient energy. These conditions are rarely encountered in practice.
Die Berufsgenossenschaft, Apr. 1975, Vol.27, No.4, p.129-135. Illus. 1 ref.

CIS 76-336 Hofer R.
Technical requirements for spray painting installations
Technische Anforderungen an Spritzlackierereien [in German]
Summary of requirements for spray painting stations satisfying occupational safety and health criteria: fire protection; ventilation; respiratory protection; explosion protection; storage of flammable liquids.
Betriebssicherheit, 1975, No.2, p.4-6. Illus.

CIS 76-27 High flash-point liquids and low melting point solids.
Liquides à point d'éclair élevé et solides à bas point de fusion [in French]
Although classified as poorly flammable substances, high-flash-point liquids and low-melting-point solids play a substantial role in the initiation and spread of fire. This article draws attention to the fire properties of 3 categories of these products: hydrocarbons (bitumen, oil quenches and cutting oils, hydraulic fluids, heat transfer fluids, etc.); animal or vegetable oils and fats; and some solids such as sugar, sulfur and waxes. Illustrated examples of recent fires due to these products. A French version of this note is published in Cahiers de notes documentaires - Sécurité et hygiène du travail, Paris, France, 4th quarter 1975, No.81, Note No.985-81-75, p.479-485. Illus.
Fire Prevention, Feb. 1975, No.107, p.31-35. Illus.

CIS 76-196 Abaseev V.K., Lebedev M.A., Kvasov A.A., Andreeva G.S., Šapošnikov Ju.K.
Catalytic cleaning of gaseous pyrolysis products of coal tar
Katalitičeskaja očistka gazoobraznyh produktov termičeskogo razloženija kamennougol'nogo peka [in Russian]
In laying wooden blocks for flooring in factories considerable quantities of smoke are given off from the heated coal tar used to fill the spaces between the blocks. These pyrolysis products contain aromatic polynuclear hydrocarbons which are carcinogenic (especially benzopyrenes). Laboratory tests with various catalysers resulted in the development of a prototype combustion catalyser containing platinum- and aluminium-coated balls. This device, mounted on the machine for filling the spaces between the blocks in the flooring and smoothing the floor surface, removes by exhaust draught the smoke given off and rids it of all carcinogens.
Gigiena truda i professional'nye zabolevanija, Jan. 1975, No.1, p.12-14.

CIS 76-26 Clancey V.J.
Fire hazards of calcium hypochlorite.
About a dozen fires and explosions of calcium hypochlorite occurred aboard British ships during the 5-year period 1969-73. This led to investigation of the accidents and of the composition and properties of the commercial material. Impurities in the product, contaminants introduced later, and heat due to storage or reaction may contribute to the instability. The material appears to be more hazardous than indicated by its classification in the IMCO Code as oxidising agent in Class 5.1. Storage on deck is recommended. Further study of the cause of the instability is required.
Journal of Hazardous Materials, Sep. 1975, Vol.1, No.1, p.83-94.

CIS 76-194 Leleu J.
Hazardous chemical reactions - 36. Aluminium
Réactions chimiques dangereuses - 36. Alumimium. [in French]
Enumeration and description of the possible reactions of aluminium with 37 organic or inorganic substances or groups of substances. The references used are listed for each reaction.
Cahiers de notes documentaires - Sécurité et hygiène du travail, 4th quarter 1975, No.81, Note No.987-81-75, p.493-497.

CIS 76-193 Leleu J.
Hazardous chemical reactions - 35. Calcium, strontium and barium
Réactions chimiques dangereuses - 35. Calcium, strontium et baryum. [in French]
Enumeration and description of the possible reactions of calcium, strontium and barium with various substances. The references used are listed for each reaction.
Cahiers de notes documentaires - Sécurité et hygiène du travail, 4th quarter 1975, No.81, Note No.986-81-75, p.489-491.

CIS 76-25 Manual of hazardous chemical reactions - A compilation of chemical reactions reported to be potentially hazardous.
This edition presents approximately 1,200 new reactions added to the 2,350 in the last edition. The reactions range in hazard from those causing incandescence or flames at moderate or slightly elevated temperatures to those having potential for detonation. The entries are arranged alphabetically under the name of one of the reactants with cross-references to or from each of the other reactants. The reactions are briefly described with references to the source of the information. Explosive fuel-air mixtures are not included, but pyrophoric or hypergolic mixtures are listed. Some entries are grouped by chemical class name.
NFPA No.491M-1975, National Fire Protection Association, 470 Atlantic Avenue, Boston, Massachusetts 02210, USA, 5th edition, 1975. 470p. Bibl. Price: US-$5.00.

CIS 76-177 Polakoff P.L., Lapp N.L., Reger R.
Polyvinyl chloride pyrolysis products - A potential cause for respiratory impairment.
Pulmonary function tests were undertaken in 17 meat wrappers, who showed a higher prevalence of cough phlegm, hay fever and asthma than a control group. Relative decreases in one-second forced expiratory volume and 50% forced expiratory flow after one work shift were found, while controls showed an opposite tendency. The groups were not however ideally matched for age and other factors, including smoking status.
Archives of Environmental Health, June 1975, Vol.30, No.6, p.269-271. 5 ref.

CIS 76-24 Hazardous chemicals data 1975.
This edition contains information on 29 substances listed for the first time and revised data for 21 chemicals in the 330 substances listed. There is new explanatory material on spill control, water pollution, flash point test methods, and the Hazard Identification System (NFPA No.704M). The substances are arranged alphabetically with many cross-references and citations to data sheets and codes. For each substance there are a description, fire and explosion hazards, health or life hazard, fire fighting advice, usual shipping containers, storage recommendations, and hazard rating number. Explosives are not included unless they are used for other purposes also.
NFPA No.49-1975, National Fire Protection Association, 470 Atlantic Avenue, Boston, Massachusetts 02210, USA, 1975. 310p. 30 ref. Price: US-$4.50.

CIS 76-19 Kuiper J.P., Buschmann C.H., Van Daatselaar C.J., Verberk M.M., Balemans A.W.M., Zuidema J.W., Mouwen C.D.A., Lamme N., Oosterbaan J.W., De Jong J.P., Vossenaar B.
Hazardous substances, variations on a topical theme
Gevaarlijke stoffen, variaties op een actueel thema [in Dutch]
Special issue devoted to the risks of fire and explosion and health hazards in the production, transport, storage and use of dangerous or harmful substances. Contents: assessment of hazard; radioactive substances; emergency exposure limits; check-list for the chemical industry; transport of, and operations with, explosive substances; road transport; rail transport; shipment by sea or inland waterway, dock handling; local emergency services; plant fire protection and fire fighting services.
Noodzaak, Alphen aan den Rijn, Netherlands, Oct.-Nov. 1975, Vol.24, No.7, p.137-176. Illus. 16 ref.

CIS 76-166 Leleu J.
Hazardous chemical reactions - 34. Magnesium
Réactions chimiques dangereuses - 34. Magnésium. [in French]
Enumeration and description of the possible reactions of magnesium with 25 substances or groups of substances (organic and inorganic). The references are quoted for each reaction.
Cahiers de notes documentaires - Sécurité et hygiène du travail, 3rd quarter 1975, No.80, Note No.977-80-75, p.397-399.

CIS 76-165 Leleu J.
Hazardous chemical reactions - 33. Beryllium
Réactions chimiques dangereuses - 33. Béryllium. [in French]
Enumeration and description of the possible reactions of beryllium with chlorine, fluorine, phosphorus, selenium, sulfur and tellurium. The references are quoted for each reaction.
Cahiers de notes documentaires - Sécurité et hygiène du travail, 3rd quarter 1975, No.80, Note No.976-80-75, p.395.

CIS 76-164 Leleu J.
Hazardous chemical reactions - 32. Rubidium - Cesium
Réactions chimiques dangereuses - 32. Rubidium - Césium. [in French]
Enumeration and description of the possible reactions of rubidium with water, halogens and mercury, and of cesium with acids, water, halogens, phosphorus and sulfur. The references are quoted for each reaction.
Cahiers de notes documentaires - Sécurité et hygiène du travail, 3rd quarter 1975, No.80, Note No. 975-80-75, p.393-394.

CIS 76-163 Leleu J.
Hazardous chemical reactions - 31. Potassium
Réactions chimiques dangereuses - 31. Potassium. [in French]
Enumeration and description of the possible reactions of potassium with 29 substances or groups of substances (organic and inorganic). The references are quoted for each reaction.
Cahiers de notes documentaires - Sécurité et hygiène du travail, 3rd quarter 1975, No.80, Note No.974-80-75, p.389-392.

CIS 76-16 Fire tests - Flame resistant textiles, films.
The introduction to this standard lists applications of flame-resistant fabrics and gives treatments and physical properties of the treated fabrics. The tests described determine the ignition and flame propagation capabilities of the textiles and films. Test apparatus and materials, test procedures, cleaning and weathering procedures, flame-resistance requirements, and a match flame field test are described. Appendices discuss field testing, effectiveness of flame-resistance treatments, specific formulas for agents, weathering, and non-combustible fabrics.
NFPA No.701-1975, National Fire Protection Association, 470 Atlantic Avenue, Boston, Massachusetts 02210, USA, 1975. 36p. 33 ref.

CIS 76-15 Safeguarding building construction and demolition operations.
This standard is intended to help prevent or minimise damage from fire. It is a complete editorial revision of the previous edition. Chapters describe temporary construction and equipment, construction processes and hazards, utilities, and fire protection. An appendix explains the principles of safeguarding construction and demolition operations.
NFPA No.241-1975, National Fire Protection Association, 470 Atlantic Avenue, Boston, Massachusetts 02210, USA, 1975. 20p. 9 ref.

CIS 76-14 Processing and finishing of aluminium.
This standard is intended to hep reduce fires and explosions in processing aluminium or its alloys when metallic dust or powder is liberated or handled. Discussed are dust collection and disposal during processing of the metal, fire safety practices, handling and storage of aluminium powder and paste, and fire protection. An appendix covers work clothing, fire extinguishing equipment, explosibility parameters, and non-sparking materials.
NFPA No.65-1975, National Fire Protection Association, 470 Atlantic Avenue, Boston, Massachusetts 02210, USA, 1975. 14p. 12 ref.

CIS 76-239 Magnesium.
This data sheet covers: characteristics of magnesium; storage; control and disposal of fine scrap; handling molten metal; machining; grinding, buffing, and wire brushing; welding; heat treating; chemical treatment; fire protection; first aid; respiratory protection; and spot tests for magnesium.
Data Sheet 426, Revision A, National Safety Council, 425 North Michigan Avenue, Chicago, Illinois 60611, USA, 1975. 8p. Illus. 1 ref.

CIS 76-140 Turpentine.
This data sheet covers: properties and uses of turpentine; shipping and storage; personnel hazards; personnel protection; ventilation; fire hazards; electrical equipment; first aid; toxicity; and threshold limit value.
Data Sheet 367, Revision A (extensive), National Safety Council, 425 North Michigan Avenue, Chicago, Illinois 60611, USA, 1975. 2p. Illus. 5 ref.

CIS 76-139 Vallaud A.
Hygiene and safety in the use of benzene hydrocarbons
L'hygiène et la sécurité dans l'emploi des hydrocarbures benzéniques. [in French]
This booklet provides industrial technicians, above all safety engineers, hygienists, industrial physicians and analysts, with concise information to enable them to solve the technical, medical and legal problems involved in the industrial use of benzene and benzene hydrocarbons, as well as that of the analytical control of the environment. Contents: general remarks on benzene hydrocarbons (benzene and homologues, toluene and xylenes, solvent naphtha; toxicology of benzene hydrocarbons; occupational benzene poisoning, medical prevention and compensation; technical prevention; technical protection measures (detection of benzene hydrocarbons, collective and personal protection, fire and explosion prevention); use of substitutes; labelling of containers. A list of the relevant French regulations in force is appended.
Edition INRS No.85, Institut national de recherche et de sécurité, 30 rue Olivier-Noyer, 75680 Paris Cedex 14, France, 8th edition, 1975. 187p. Illus. 240 ref.

CIS 76-13 Woolley W.D., Ames S.A.
The explosion risk of stored foamed rubber.
A serious fire in a storeroom containing foam rubber mattresses prompted studies with the material used (density 65kg/m³). Description of the experiments: flaming and smouldering ignition tests; rate of smouldering; flammability and explosibility of products of smouldering. Conclusions: (1) when ignited with flaming ignition sources, foam rubber burns readily with flames and produces black smoke; (2) non-flaming ignition sources produce smouldering throughout the bulk of the rubber, with cool grey smoke, leading to flaming with time; (3) the grey smoke and vapours from smouldering are flammable and can produce an explosive atmosphere: flaming can then produce a serious explosion; (4) an explosive atmosphere can build up in a closed volume of 1.4m³ in some 30min, the rate of release of flammable products increasing with time.
Building Research Establishment, Garston, Watford WD2 7JR, United Kingdom, Apr. 1975. 7p. Illus. 1 ref. Gratis.

CIS 75-2002 Hartwig P.
Combustibility of protective clothing in hot workplaces
Die Brennbarkeit von Arbeitsschutzkleidung an wärmebelasteten Arbeitsplätzen [in German]
Study of the protection offered against flames and heat by different textiles of natural, artificial and synthetic fibres employed in flame-resistant clothing. Consideration of the flammability and flame resistance of flame-proof cotton, wool, cellulose, and synthetic fibres. The detrimental effect of radiant heat from melting furnaces, washing and mechanical action (wear and tear) on the flame-resistant properties of textiles is examined. The level of protection afforded by clothes must be checked regularly by means of standardised tests.
Die Berufsgenossenschaft, Feb. 1975, Vol.27, No.2, p.49-58. Illus. 7 ref.

CIS 75-1830 Types of building construction.
This standard classifies building types for committees of the USA National Fire Protection Association. Constructions described are: fire-resistive, non-combustible/limited-combustible, protected non-combustible/limited-combustible, heavy timber, ordinary, protected ordinary, wood frame, and protected wood frame. Definitions are also given. Appendices give physical properties of construction materials.
NFPA No.220-1975, National Fire Protection Association, 470 Atlantic Avenue, Boston, Massachusetts 02210, USA, 1975, 16p. 5 ref.

CIS 75-1828 Sharry J.A.
Foamed plastic fire - Fire spreads 430 feet in eight minutes.
A fire spread along the entire length of the rigid polyurethane insulation of a tunnel under construction, requiring 45min to bring under control. This fire points to the potential danger of urethane foam, the high rate of evolution of flammable gases and smoke and the rapidity of spread making a fire stop virtually impossible. Current testing and designation practices are inadequate, and the manufacturer's claim that the foam system was self-extinguishing was in contradiction with the fire hazard of the material. Better and more appropriate test methods and better identification of the fire hazard of new plastics are required.
Fire Journal, Jan. 1975, Vol.69, No.1, p.5-6, 56. Illus. 1 ref.

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