Document ID (ISN) | 53228 |
CIS number |
90-190 |
ISSN - Serial title |
0016-9900 - Gigiena i sanitarija |
Year |
1988 |
Convention or series no. |
|
Author(s) |
Javorskij A.P., Manza I.A., Petrov N.A., Timofeeva T.N. |
Title |
Comprehensive study of the composition of the volatile products of epoxy resins by proton magnetic resonance and gas-liquid chromatography |
Original title |
Kompleksnoe izučenie sostava letučih produktov ėpoksidnyh smol s primeneniem metoda protonno-magnitnogo rezonansa i gazožidkostnoj hromatografii [in Russian] |
Bibliographic information |
May 1988, No.5, p.86-88. 5 ref. |
Abstract |
The composition of volatile products of cycloaliphatic epoxy resins UP-640 and UP-650 T, polyoxypropylene epoxides DE-1000, DE-2000, TE-750, TE-1500 and epoxy-diane ED-6 was determined. The cycloaliphatic epoxy resins and polyoxypropylene epoxides (POPE) differ from earlier epoxy resins in both component composition and content. Such highly toxic components as allyl chloride and styrene can volatilise along with epichlorohydrin and toluene from UP-640 and UP-650 T, in contrast to epoxy resins. Volatile products of POPE include acetone, allyl chloride, ethanol and dioxane equally with the usual components of diane resins. The main component taken into account for standardisation cannot be only epichlorohydrin. In the case of hygienic standardisation of POPE, in particular, acetone is chosen as the volatile component because of its proportion, boiling point and volatilising proportion in comparison with other volatile products. |
Descriptors (primary) |
epoxy resins; USSR; dioxane; acetone; allyl chloride; standardization; styrene; ethanol; epichlorohydrin; volatile substances; toluene |
Descriptors (secondary) |
nuclear magnetic resonance spectroscopy; gas-liquid chromatography |
Document type |
D - Periodical articles |
Subject(s) |
Toxic and dangerous substances
|
Broad subject area(s) |
Chemical safety
|
Browse category(ies) |
Alcohols Ethylene oxide Ketones Halogenated hydrocarbons Aromatic hydrocarbons Ethers
|