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Document ID (ISN)47435
CIS number 87-237
ISSN - Serial title 0016-9900 - Gigiena i sanitarija
Year 1985
Convention or series no.
Author(s) Dmitriev M.T., Kuleš T.A., Rastjannikov E.G.
Title Study of the toxic substances formed in the oxo process
Original title Izučenie toksičnyh veščestv, obrazujuščihsja v processe oksosinteza [in Russian]
Bibliographic information Aug. 1985, No.8, p.51-54. 12 ref.
Abstract In the oxo process, olefins are reacted with carbon monoxide and hydrogen to yield alcohols; aldehydes are intermediate reaction products. Various volatile by-products may also be formed, so that workplace air can be contaminated by a wide range of substances. To identify and quantitate these contaminants, air was sampled by being drawn through a glass tube packed with Tenax sorbent. The material collected was desorbed onto a glass capillary gas-chromatography column coated with SE30. The gas chromatograph was coupled to a mass spectrometer. 165 organic compounds were identified. They included saturated, unsaturated and aromatic hydrocarbons, terpenes, halogenated hydrocarbons, nitriles, thiocyanates, sulfides, alcohols, ethers, aldehydes and ketones.
Descriptors (primary) chemical industry; aldehydes; determination in air; atmospheric pollution; alcohols
Descriptors (secondary) sulfides; ketones; halogenated hydrocarbons; hydrocarbons; ethers; gas-liquid chromatography; aromatic hydrocarbons; thiocyanates; nitriles; chemical processes; terpenes
Document type D - Periodical articles
Subject(s) Toxic and dangerous substances
Broad subject area(s) Chemical safety
Browse category(ies) Air pollution
Environmental pollution
Chemical industry