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Document ID (ISN)38387
CIS number 82-1609
ISSN - Serial title 0144-557X - Analytical Proceedings
Year 1981
Convention or series no.
Author(s) Purnell C.J., Walker R.F.
Title Methods for the determination of atmospheric isocyanates
Bibliographic information Nov. 1981, p.472-478. 35 ref.
Abstract Reported methods for the determination of aliphatic and aromatic isocyanates are discussed. Spectrophotometric methods provide a total isocyanate figure, but for mixtures of the monomer and prepolymer a calibration graph using similar standard mixtures is required. These methods are simple and inexpensive. Chromatographic methods are necessary to resolve the concentrations of individual isocyanates present in a mixture. High-performance thin-layer chromatography and high-performance liquid chromatography are the preferred techniques.
Descriptors (primary) isocyanates; determination in air; plastics industry
Descriptors (secondary) literature survey; polyurethanes; high performance chromatography; methylenebis(4-cyclohexyl isocyanate); methylene diisocyanate; hexamethylene diisocyanate; spectrophotometry; 2,6-tolylene diisocyanate; 2,4-tolylene diisocyanate; sampling and analysis; description of technique; thin-layer chromatography; isophorone diisocyanate
Document type D - Periodical articles
Subject(s) Toxic and dangerous substances
Broad subject area(s)
Browse category(ies) Chemical industry
Isocyanates
Cyano compounds
Plastics industry