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Page No. 1 \wp51\stt\ipcs\18 November 1996
Classification using Risk- and Safety Phrases
Substance CAS number Symbol Risk-phrases Safety phrases
ACEPHATE 30560-19-1 Xn 22 (2)-36
ACETAL 105-57-7 F,Xi 11-36/38 (2-)9-16-33
ACETALDEHYDE 75-07-0 F+,Xn 12-36/37-40 (2-)16-33-36/37
ACETAMIDE 60-35-5 Xn 40 (2-)36/37
ACETIC ACID, conc.>90% 64-19-7 C 10-35 (1/2-)23-26-45 Note B
ACETIC ACID, conc. 25%-90% C 34 (1/2-)23-26-45 Note B
ACETIC ANHYDRIDE 108-24-7 C 10-34 (1/2-)26-45
ACETONE 67-64-1 F 11 (2-)9-16-23-33
ACETONE CYANOHYDRIN 75-86-5 T+,N 26/27/28-50 (1/2-)7/9-27-45-61
ACETONITRILE 75-05-8 F,T 11-23/24/25 (1/2-)16-27-45
ACETOPHENONE 98-86-2 Xn 22-36 (2-)26
ACETYLACETONE 123-54-3 Xn 10-22 (2-)21-23-24/25
ACETYL CHLORIDE 75-36-5 F,C 11-14-34 (1/2-)9-16-26-45
ACETYLENE 74-86-2 F+ 5-6-12 (2-)9-16-33
3-ACETYL-6-METHYL-2H-PYRAN-2,4(3H)-DIONE 520-45-6 Xn 22 (2)
ACLONIFEN 74070-46-5 N 50/53 60-61
ACONITINE 302-27-2 T+ 26/28 (1/2-)24-45
ACONITINE, SALTS T+ 26/28 (1/2-)24-45 Note A
ACROLEIN 107-02-8 F,T+ 11-25-26-34 (1/2-)3/9/14-26-36/37/39-38-45
ACRYLALDEHYDE 107-02-8 F,T+ 11-25-26-34 (1/2-)3/9/14-26-36/37/39-38-45
ACRYLAMIDE 79-06-1 T 45-46-24/25-48/23/24/25 53-45 Note D, E
ACRYLATES, with the exception of those Xi 36/37/38 (2-)26-28
specified elsewhere in this Annex, conc.³10%
ACRYLIC ACID 79-10-7 C 10-34 (1/2-)26-36-45 Note D
ACRYLONITRILE 107-13-1 F,T 45-11-23/24/25-38 53-45 Note D, E
ADIPIC ACID 124-04-9 Xi 36 (2)
ADZN 78-67-1 E,Xn 2-11-20/22 (2-)39-41-47
ALACHLOR 15972-60-8 Xn 22-40-43 (2-)36/37/39
ALDICARB 116-06-3 T+ 27/28 (1/2-)22-36/37-45
ALDRIN 309-00-2 T,N 24/25-40-48/24/25-50/53 (1/2-)22-36/37-45-60-61
ALLETHRIN 584-79-2 Xn 22 (2-)36
ALLIDOCHLOR 93-71-0 Xn 21/22-36/38 (2-)26-28-36/37/39
ALLYL ALCOHOL 107-18-6 T,N 10-23/24/25-36/37/38-50 (1/2-)36/37/39-38-45-61
ALLYLAMINE 107-11-9 F,T,N 11-23/24/25-51/53 (1/2-)9-16-24/25-45-61
5-ALLYL-1,3-BENZODIOXOLE 94-59-7 T 45-22-40 53-45 Note E
ALLYL CHLORIDE 107-05-1 F,T+,N 11-26-50 (1/2-)16-29-33-45-61 Note D
ALLYL 2,3-EPOXYPROPYL ETHER 106-92-3 Xn 20-43 (2-)24/25
ALLYL GLYCIDYL ETHER 106-92-3 Xn 20-43 (2-)24/25
ALLYL IODIDE 556-56-9 C 10-34 (1/2-)7-26-45
ALUMINIUM, ALKYLS F,C 14-17-34 (1/2-)16-43-45 Note A
ALUMINIUM CHLORIDE, anhydrous 7446-70-0 C 34 (1/2-)7/8-28-45
ALUMINIUM LITHIUM HYDRIDE 16853-85-3 F 15 (2-)7/8-24/25-43
ALUMINIUM PHOSPHIDE 20859-73-8 F,T+ 15/29-28-32 (1/2-)3/9/14-30-36/37-45
ALUMINIUM POWDER, PYROPHORIC 7429-90-5 F 15-17 (2-)7/8-43
ALUMINIUM POWDER, STABILIZED - 10-15 (2-)7/8-43
ALUMINIUM-TRI-ISOPROPOXIDE 555-31-7 F 11 (2-)8-16
AMETRYN 834-12-8 Xn 22 (2-)36
AMIDITHION 919-76-6 Xn 22 (2-)24-36
AMINES, POLYETHYLENEPOLY- 68131-73-7 C,N 21/22-34-43-50/53 (1/2-)26-36/37/39-45-60-61
4-AMINOAZOBENZENE 60-09-3 T 45 53-45
o-AMINOAZOTOLUENE 97-56-3 T 45-43 53-45
3-AMINOBENZENE SULPHONIC ACID 121-47-1 Xn 20/21/22 (2-)25-28
4-AMINOBENZENE SULPHONIC ACID 121-57-3 Xi 36/38-43 (2-)24-37
4-AMINOBIPHENYL 92-67-1 T 45-22 53-45 Note E
4-AMINOBIPHENYL, SALTS T 45-22 53-45 Note A, E
1-AMINOBUTANE 109-73-9 F,C 11-20/21/22-35 (1/2-)3-16-26-29-36/37/39-45
2-AMINOBUTANE 13952-84-6 F,C,N 11-20/22-35-50 (1/2-)9-16-26-28-36/37/39-45-61
AMINOCARB 2032-59-9 T 24/25 (1/2-)28-36/37-45
5-AMINO-4-CHLORO-2-PHENYLPYRIDAZIN-3(2H)-ONE 1698-60-8 Xi 43 (2-)24-37
4-AMINO-N,N-DIETHYLANILINE 93-05-0 T 25-34 (1/2-)26-36-45
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Substance CAS number Symbol Risk-phrases Safety phrases
3-AMINO-N,N'-DIMETHYLANILINE 2836-04-6 T 23/24/25 (1/2-)28-45 Note C
4-AMINO-N,N-DIMETHYLANILINE 99-98-9 T 23/24/25 (1/2-)28-45 Note C
4-AMINO-2',3-DIMETHYLAZOBENZENE 97-56-3 T 45-43 53-45
2-AMINO-4,6-DINITROPHENOL 96-91-3 E,Xn 1-20/21/22-52/53 (2-)35-61
2-AMINOETHANOL 141-43-5 Xn 20-36/37/38 (2)
2-AMINOETHYLDIMETHYLAMINE 108-00-9 F,C 11-21/22-35 (1/2-)16-23-26-28-36-45
4-AMINO-3-FLUOROPHENOL 399-95-1 T,N 45-22-43-51/53 53-45-61 Note E
2-AMINO-2-METHYLPROPANOL 124-68-5 Xi 36/38 (2)
3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE 2855-13-2 C 21/22-34-43-52/53 (1/2-)26-36/37/39-45-61
2-AMINOPHENOL 95-55-6 Xn 20/22-40 (2-)28-36/37
5-AMINO-PHENYL-1,2,4-TRIAZOL-1-YL-N,N,N',N'- 1031-47-6 T+ 27/28 (1/2-)22-28-36/37-45
TETRAMETHYL PHOSPHONIC DIAMIDE
2-AMINOPROPANE 75-31-0 F+,Xi 12-36/37/38 (2-)16-26-29
1-AMINOPROPAN-2-OL 78-96-6 C 34 (1/2-)23-26-36-45
3-AMINOPROPYLDIETHYLAMINE 104-78-9 C 10-21/22-34-43 (1/2-)26-36/37/39-45
3-AMINOPROPYLDIMETHYLAMINE 109-55-7 C 10-22-34-43 (1/2-)26-36/37/39-45
3-AMINOPROPYLTRIETHOXYSILANE 919-30-2 C 22-34 (1/2-)26-36/37/39-45
2-AMINOTOLUENE 95-53-4 T,N 45-23/25-36-50 53-45-61 Note E
AMITRAZ 33089-61-1 Xn 22 (2-)22
AMITROLE 61-82-5 Xn,N 40-48/22-51/53 (2-)36-37-61
AMMONIA, anhydrous 7664-41-7 T,N 10-23-34-50 (1/2-)9-16-26-36/37/39-45-61
AMMONIA SOLUTION conc.³25% 1336-21-6 C,N 34-50 (1/2-)26-36/37/39-45-61 Note B
AMMONIA SOLUTION 5%£conc.<10% 1336-21-6 Xi 36/37/38 (2-)7-26 Note B
AMMONIUM BIFLUORIDE 1341-49-7 T,C 25-34 (1/2-)22-26-37-45
AMMONIUM BIS(2,4,6-TRINITROPHENYL)AMINE 2844-92-0 E,T+,N 1-26/27/28-33-51/53 (1/2-)28-36/37-45-61
AMMONIUM CHLORIDE 12125-02-9 Xn 22-36 (2-)22
AMMONIUM DICHROMATE 7789-09-5 E,T+,N 49-46-1-8-21-25-26- 53-45-60-61 Note E
37/38-41-43-50/53
AMMONIUM FLUORIDE 12125-01-8 T 23/24/25 (1/2-)26-45
AMMONIUM HEXAFLUOROSILICATE 16919-19-0 T 23/24/25 (1/2-)26-45 Note A
AMMONIUM HYDROGEN DIFLUORIDE 1341-49-7 T,C 25-34 (1/2-)22-26-37-45
AMMONIUM PERCHLORATE 7790-98-9 O 9-44 (2-)14-16-27-36/37 Note G
AMMONIUM POLYSULPHIDES 9080-17-5 C 31-34 (1/2-)26-45
AMYL ACETATE 628-63-7 - 10 (2-)23 Note C
AMYLALCOHOL, except tert-PENTANOL 30899-19-5 Xn 10-20 (2-)24/25 Note C
AMYLASE, I- 9000-90-2 Xn 42 (2-)22-24-36/37
AMYLASES with exception of those specified Xn 42 (2-)22-24-36/37
elsewhere in this Annex
AMYL FORMATE 638-49-3 - 10 (2) Note C
AMYL PROPIONATE 624-54-4 - 10 (2-)23 Note C
ANILAZINE 101-05-3 Xi 36/38 (2-)22
ANILINE 62-53-3 T,N 20/21/22-40- (1/2-)28-36/37-45-61
48/23/24/25-50
ANILINE, SALTS T,N 20/21/22-40- (1/2-)28-36/37-45-61 Note A
48/23/24/25-50
o-ANISIDINE 90-04-0 T+,N 45-26/27/28-33-51/53 53-45-61 Note E
p-ANISIDINE 104-94-9 T+,N 26/27/28-33-50 (1/2-)28-36/37-45-61
ANTIMONY COMPOUNDS except TETROXIDE and Xn 20/22 (2-)22* Note A
PENTOXIDE, TRISULPHIDE, PENTASULPHIDE and
those specified elsewhere in this Annex *If appropriate
ANTIMONY PENTACHLORIDE 7647-18-9 C 34-37 (1/2-)26-45
ANTIMONY TRICHLORIDE 10025-91-9 C 34-37 (1/2-)26-45
ANTIMONY TRIFLUORIDE 7783-56-4 T 23/24/25 (1/2-)7-26-45
ANTIMONY TRIOXIDE 1309-64-4 Xn 40 (2-)22-36/37
ANTU 86-88-4 T+ 28-40 (1/2-)25-36/37-45
ARSENIC 7440-38-2 T 23/25 (1/2-)20/21-28-45
ARSENIC ACID and its SALTS T 45-23/25 53-45 Note A, E
ARSENIC COMPOUNDS, conc.³0.2%, with the T 23/25 (1/2-)20/21-28-45 Note A
exception of those specified elsewhere in this Annex
ARSENIC OXIDE 1303-28-2 T 45-23/25 53-45 Note E
ARSENIC PENTOXIDE 1303-28-2 T 45-23/25 53-45 Note E
ARSENIC TRIOXIDE 1327-53-3 T+ 45-28-34 53-45 Note E
ARSINE 7784-42-1 F+,T+,N 12-26-48/20-50/53 (1/2-)9-16-28-33-36/37-45-60-61
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Substance CAS number Symbol Risk-phrases Safety phrases
ASBESTOS T 45-48/23 53-45 Note E
ATRAZINE 1912-24-9 Xn 20/22-36-40-43 (2-)36/37-46
ATROPINE 51-55-8 T+ 26/28 (1/2-)25-45
ATROPINE, SALTS T+ 26/28 (1/2-)25-45 Note A
AURAMINE 492-80-8 Xn,N 22-36-40-51/53 (2-)36/37-61
AURAMINE, SALTS Xn,N 22-36-40-51/53 (2-)36/37-61 Note A
AZACONAZOLE 60207-31-0 Xn 22-44 (2-)24
AZINPHOS-ETHYL 2642-71-9 T+ 24-28 (1/2-)28-36/37-45
AZINPHOS-METHYL 86-50-0 T+ 24-28 (1/2-)28-36/37-45
AZIRIDINE 151-56-4 F,T+,N 45-46-11-26/27/28-34- 53-45-61 Note D, E
51/53
AZOBENZENE 103-33-3 Xn 20/22 (2-)28
AZOTHOATE 5834-96-8 Xn 20/22 (2-)13
AZOXYBENZENE 495-48-7 Xn 20/22 (2-)28
BARBAN 101-27-9 Xn 22-43 (2-)24-36/37
BARIUM CARBONATE 513-77-9 Xn 22 (2-)24/25
BARIUM CHLORATE 13477-00-4 O,Xn 9-20/22 (1/2-)13-27
BARIUM CHLORIDE 10361-39-4 T 20-25 (1/2-)45
BARIUM SALTS, conc.³1%, with the exception Xn 20/22 (2-)28 Note A
of BARIUM SULPHATE, salts of 1-AZO-2-HYDROXUNAPHTHALENYL ARYL SULPHONIC ACID
and salts specified elsewhere in this Annex
BARIUM PERCHLORATE 13465-95-7 O,Xn 9-20/22 (2-)27
BARIUM PEROXIDE 1304-29-6 O,Xn 8-20/22 (2-)13-27
BARIUM POLYSULPHIDES 50864-67-0 Xi 31-36/37/38 (2-)28
BARIUM SULPHIDE 21109-95-5 Xn 20/22-31 (2-)28
BENAZOLIN 3813-05-6 Xi 36/38 (2-)22
BENDIOCARB 22781-23-2 T 21-25 (1/2-)22-36/37-45
BENOMYL 17804-35-2 Xn 40 (2-)36/37
BENQUINOX 495-73-8 T 21-25 (1/2-)36/37-45
BENSULIDE 741-58-2 Xn 22 (2-)24-36
BENTAZONE 25057-89-0 Xn 22-36 (2-)26
BENZAL CHLORIDE 98-87-3 T 22-23-37/38-40-41 (1/2-)36/37-38-45
BENZALDEHYDE 100-52-7 Xn 22 (2-)24
BENZENE 71-43-2 F,T 45-11-48/23/24/25 53-45 Note E
BENZENE-1,3-DIAMINE DIHYDROCHLORIDE 541-69-5 T,N 23/24/25-43-50/53 (1/2-)28-36/37-45-60-61 Note C
BENZENE-1,4-DIAMINE DIHYDROCHLORIDE 624-18-0 T,N 23/24/25-43-50/53 (1/2-)28-36/37-45-60-61 Note C
1,3-BENZENEDIOL 108-46-3 Xn,N 22-36/38-50 (2-)26-61
BENZENE-1,2:3,4-TETRACARBOXYLIC DIANHYDRIDE 89-32-7 Xi 36/37/38 (2-)25
BENZENE-1,2,4-TRICARBOXYLIC-1,2-ANHYDRIDE 552-30-7 Xn 36/37/38-42 (2-)22-28
BENZIDINE 92-87-5 T,N 45-22-50/53 53-45-60-61 Note E
BENZIDINE, SALTS T,N 45-22-50/53 53-45-60-61 Note A, E
BENZIDINE BASED AZO DYES; T 45 53-45 Note A
4,4'-DIARYLAZOBIPHENYL DYES, with exception
of those specified elsewhere in this Annex
1,2-BENZISOTHIAZOL-3(2H)-ONE 2634-33-5 Xn 22-38-43 (2-)24-37
BENZO[e]ACEPHENANTHRYLENE 205-99-2 T 45 53-45
BENZO[a]ANTHRACENE 56-55-3 T 45 53-45
BENZO[d,e,f]CHRYSENE 50-32-8 T 45-46-60-61 53-45
BENZO[b]FLUORANTHENE 205-99-2 T 45 53-45
BENZO[j]FLUORANTHENE 205-82-3 T 45 53-45
BENZO[k]FLUORANTHENE 207-08-9 T 45 53-45
BENZOGUANAMINE 91-76-9 Xn 22 (2)
BENZONITRILE 100-47-0 Xn 21/22 (2-)23
BENZOPHENONE-3,3',4,4'-TETRACARBOXYLIC 2421-28-5 Xi 36/37 (2-)25
DIANHYDRIDE
BENZO[a]PYRENE 50-32-8 T 45-46-60-61 53-45
p-BENZOQUINONE 106-51-4 T 23/25-36/37/38 (1/2-)26-28-45
p-BENZOQUINONE 1-BENZOYLHYDRAZONE 4-OXIME 495-73-8 T 21-25 (1/2-)36/37-45
BENZOTHIAZOLE-2-THIOL 149-30-4 Xi,N 43-50/53 (2-)24-37-60-61
1-(2-BENZOTHIAZOLYL)-3-METHYLUREA 1929-88-0 Xn 22 (2-)24/25
(BENZOTHIAZOL-2-YLTHIO)SUCCINIC ACID 95154-01-1 Xi 43 (2-)24-37
Page No. 4
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Substance CAS number Symbol Risk-phrases Safety phrases
I-3-(3-(2H-BENZOTRIAZOL-2-YL)-5-tert- Xn,N 43-48/22-51/53 (2-)36/37-61
BUTYL-4-HYDROXYPHENYL)PROPIONYL-
omega-HYDROXYPOLY(OXYETHYLENE) and
I-3-(3-(2H-BENZOTRIAZOL-2-YL)-5-tert-BUTYL-4-HYDROXYPHENYL)PROPIONYL-
omega-3(3-(2H-BENZOTRIAZOL-2-YL)-5-tert-BUTYL-4-HYDROXYPHENYL)PROPIONYL-
HYDROXYPOLY(OXYETHYLENE)
BENZOTRICHLORIDE 98-07-7 T 45-22-23-37/38-41 53-45 Note E
BENZOTRIFLUORIDE 98-08-8 F,N 11-51/53 (2-)16-23-61
BENZOYL CHLORIDE 98-88-4 C 34 (1/2-)26-45
BENZOYL PEROXIDE 94-36-0 E,Xi 2-7-36-43 (2-)3/7-14-36/37/39
BENZOYLPROP-ETHYL 33878-50-1 Xn 22 (2-)24
BENZTHIAZURON 1929-88-0 Xn 22 (2-)24/25
BENZYL ALCOHOL 100-51-6 Xn 20/22 (2-)26
BENZYLAMINE 100-46-9 C 21/22-34 (1/2-)26-36/37/39-45
BENZYL BENZOATE 120-51-4 Xn 22 (2-)25
BENZYL BROMIDE 100-39-0 Xi 36/37/38 (2-)39
BENZYL CHLORIDE 100-44-7 T 22-23-37/38-40-41 (1/2-)36/37-38-45
BENZYL CHLOROFORMATE 501-53-1 C 34-37 (1/2-)26-45
S-BENZYL DIISOPROPYL PHOSPHOROTHIOATE 26087-47-8 Xn 22 (2)
BENZYLDIMETHYLAMINE 103-83-3 C 10-20/21/22-34-52/53 (1/2-)26-36-45-61
S-BENZYL N,N-DIPROPYLTHIOCARBAMATE 52888-80-9 Xn,N 22-48/22-51/53 (2-)37-61
(N-BENZYL-N-ETHYL)AMINO-3'- 55845-90-4 Xi,N 41-51/53 (2-)26-39-61
HYDROXYACETOPHENONE HYDROCHLORIDE
BENZYL-2-HYDROXYDECYLDIAMMONIUM BENZOATE 113694-52-3 C,N 22-34-50/53 (1/2-)26-28-36/37/39-45-60-61
BENZYLIDENE CHLORIDE 98-87-3 T 22-23-37/38-40-41 (1/2-)36/37-38-45
BENZYLTRIBUTYLAMMONIUM 4-HYDROXYNAPHTHALENE- 102561-46-6 Xn,N 20-51/53 (2-)22-61
1-SULPHONATE
BENZYL VIOLET 4B 1694-09-3 Xn 40 (2-)36/37
BERYLLIUM 7440-41-7 T+ 49-25-26-36/37/38-
43-48/23 53-45, Note E
BERYLLIUM COMPOUNDS T+ 49-25-26-36/37/38-
43-48/23 53-45 Note A, E
BHC 608-73-1 T,N 21-25-40-50/53 (1/2-)22-36/37-45-60-61 Note C
BINAPACRYL 485-31-4 T 61-21/22 53-45 Note E
BIOALLETHRIN 584-79-2 Xn 22 (2-)24
S-BIOALLETHRIN 28434-00-6 Xn,N 21/22-50/53 (2-)36/37-60-61
BIPHENYL 92-52-4 Xi,N 36/37/38-50/53 (2-)23-60-61
BIPHENYL-4-YLAMINE 92-67-1 T 45-22 53-45 Note E
BIPHENYL-4-YLAMINE, SALTS T 45-22 53-45 Note A, E
BIPHENYL-4,4'-YLENEDIAMINE 92-87-5 T,N 45-22-50/53 53-45-60-61 Note E
BIPHENYL-4,4'-YLENEDIAMINE, SALTS T,N 45-22-50/53 53-45-60-61 Note A, E
2,2-BIS(ACRYLOYLOXYMETHYL)BUTYL ACRYLATE 15625-89-5 Xi 36/38-43 (2-)39 Note D
N,N-BIS(3-AMINOPROPYL)METHYLAMINE 105-83-9 T 22-23/24-34 (1/2-)26-36/37/39-45
BIS(2-CHLOROETHYL) ETHER 111-44-4 T+ 10-26/27/28-40 (1/2-)7/9-27-38-45
BIS(CHLOROMETHYL) ETHER 542-88-1 T+ 45-10-22-24-26 53-45 Note E
O,O-BIS(4-CHLOROPHENYL) 4104-14-7 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
N-ACETIMIDOYLPHOSPHOROAMIDOTHIOATE
1,1-BIS(4-CHLOROPHENYL)ETHANOL 80-06-8 Xn 22 (2-)36
BIS(2-DIMETHYLAMINOETHYL)(METHYL)AMINE 3030-47-5 T 22-24-34 (1/2-)26-36/37/39-45
BIS(I,I-DIMETHYLBENZYL) PEROXIDE 80-43-3 O,Xi 7-36/38 (2-)3/7-14-36/37/39
2,5-BIS(1,1-DIMETHYLBUTYL)HYDROQUINONE N 51/53 61
1,1'-BIS(3,5-DIMETHYLMORPHOLINOCARBONYL- Xn 22-36/37/38 (2-)22-36
METHYL)-4,4'-BIPYRIDYLIUM ION
1,3-BIS(2,3-EPOXYPROPOXY)BENZENE 101-90-6 T 23/24/25-40-43 (1/2-)23-24-45
1,4-BIS(2,3-EPOXYPROPOXY)BUTANE 2425-79-8 Xn 20/21-36/38-43 (2-)26-28-37/39
1,3-BIS(2,3-EPOXYPROPOXY)-2,2-DIMETHYLPROPANE 17557-23-2 Xi 38-43 (2-)24-37
BIS[4-(2,3-EPOXYPROPOXY)PHENYL]PROPANE 1675-54-3 Xi 36/38-43 (2-)28-37/39
1,2-BIS(ETHOXYCARBONYL)ETHYL O,O-DIMETHYL 121-75-5 Xn 22 (2-)24
PHOSPHORODITHIOATE
3-[BIS(2-ETHYLHEXYL)AMINOMETHYL] 105254-85-1 C,N 34-43-50/53 (1/2-)26-28-36/37/39-45-60-61
BENZOTHIAZOLE-2(3H)-THIONE
N,N-BIS(2-ETHYLHEXYL)-((1,2,4-TRIAZOL- 91273-04-0 C,N 34-43-51/53 (1/2-)26-28-36/37/39-45-61
1-YL)METHYL)AMINE
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Substance CAS number Symbol Risk-phrases Safety phrases
BIS(4-FLUOROPHENYL)-METHYL-(1,2,4-TRIAZOL- Xi,N 36-51/53 (2-)26-61
4-YLMETHYL)SILANE HYDROCHLORIDE
BIS(HYDROXYLAMMONIUM) SULPHATE 10039-54-0 Xn,N 22-36/38-43-48/22-50 (2-)22-24-37-61
2,5-BIS-(HYDROXYMETHYL)OXOLANE 104-80-3 Xi 36/37/38 (2-)39
BIS(8-HYDROXYQUINOLINE) SULPHATE 134-31-6 Xn 22 (2-)36
BIS(2-METHOXYETHYL) PHTHALATE 117-82-8 T 61-62 53-45
BIS(METHOXYTHIOCARBONOYL) DISULPHIDE 1468-37-7 Xn 22 (2)
BISPHENOL-A-DIGLYCIDYL ETHER 1675-54-3 Xi 36/38-43 (2-)28-37/39
BIS(PIPERIDINOTHIOCARBONYL) DISULPHIDE 94-37-1 Xi 36/37/38-43 (2-)24-26-37
BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDYL)SUCCINATE 62782-03-0 Xi 36-52/53 (2-)26-61
BIS(2,4,6-TRINITROPHENYL)AMINE 131-73-7 E,T+,N 2-26/27/28-33-51/53 (1/2-)35-36-45-61
4,4'-BI-o-TOLUIDINE 119-93-7 T,N 45-22-51/53 53-45-61 Note E
BLASTICIDIN-S 2079-00-7 T+ 28 (1/2-)24/25-36/37-45
BORON TRIBROMIDE 10294-33-4 T+,C 14-26/28-35 (1/2-)9-26-28-36/37/39-45
BORON TRICHLORIDE 10294-34-5 T+ 14-26/28-34 (1/2-)9-26-28-36/37/39-45
BORON TRIFLUORIDE 7637-07-2 T+,C 14-26-35 (1/2-)9-26-28-36/37/39-45
BRODIFACOUM 56073-10-0 T+ 27/28-48/24/25 (1/2-)36/37-45
BROMELAIN, juice 9001-00-7 Xn 36/37/38-42 (2-)22-24-26-36/37
BROMINE 7726-95-6 T+,C 26-35 (1/2-)7/9-26-45
BROMOACETIC ACID 79-08-3 T,C 23/24/25-35 (1/2-)36/37/39-45
BROMOBENZENE 108-86-1 Xi,N 10-38-51/53 (2-)61
BROMOBENZYLBROMOTOLUENE, mixture of isomers 99688-47-8 Xn,N 43-48/22-50/53 (2-)24-37-41-60-61
0-4-BROMO-2,5-DICHLOROPHENYL O,O-DIETHYL 4824-78-6 T,N 21-25-50/53 (1/2-)28-36/37-45-60-61
PHOSPHOROTHIOATE
O-4-BROMO-2,5-DICHLOROPHENYL O-METHYL 21609-90-5 T,N 21-25-39/25-50/53 (1/2-)25-36/37/39-45-60-61
PHENYLPHOSPHONOTHIOATE
BROMOETHANE 74-96-4 Xn 20/21/22 (2-)28
2-(2-BROMOETHOXY)ANISOLE 4463-59-6 Xn 22-52/53 (2-)22-61
BROMOETHYLENE 593-60-2 F+,T 45-12 53-45
BROMOFENOXIM 13181-17-4 Xn 22 (2-)25
BROMOFORM 75-25-2 T,N 23-36/38-51/53 (1/2-)28-45-61
BROMOMETHANE 74-83-9 T,N 23-36/37/38-50/53-59 (1/2-)15-27-36/37/39-38-
45-59-61
BROMOPHOS 2104-96-3 Xn 22 (2-)36
BROMOPHOS-ETHYL 4824-78-6 T,N 21-25-50/53 (1/2-)28-36/37-45-60-61
1-BROMOPROPANE 106-94-5 Xn 10-20 (2-)9-24
I-BROMOTOLUENE 100-39-0 Xi 36/37/38 (2-)39
BROMOXYNIL 1689-84-5 T 25-63 (1/2-)36/37-45
BROMOXYNIL OCTANOATE 1689-99-2 Xn 21/22-63 (2-)36/37
BRONOPOL 52-51-7 Xn,N 21/22-37/38-41-50/53 (2-)26-37/39-60-61
BRUCINE 357-57-3 T+ 26/28 (1/2-)13-45
BRUCINE, SALTS T+ 26/28 (1/2-)13-45 Note A
BUFENCARB 8065-36-9 T 24/25 (1/2-)28-36/37-45
BUTANAL 123-72-8 F 11 (2-)9-29-33
1,3-BUTADIENE 106-99-0 F+,T 45-12 53-45 Note D
BUTADIENE DIEPOXIDE 1464-53-5 T 23/24/25-36/37/38-40-
42/43 (1/2-)23-24-45
BUTANEDIOLDIGLYCIDYL ETHER 2425-79-8 Xn 20/21-36/38-43 (2-)26-28-37/39
BUTANE 106-97-8 F+ 12 (2-)9-16 Note C
BUTANOL, except tert-BUTYL ALCOHOL 71-36-3(n) Xn 10-20 (2-)16 Note C
tert-BUTANOL 75-65-0 F,Xn 11-20 (2-)9-16
2-BUTANONE 78-93-3 F,Xi 11-36/37 (2-)9-16-25-33
2-BUTANONE OXIME 96-29-7 Xi 36-43 (2-)23-24
2-BUTENAL 123-73-9 F,T 11-23-36/37/38 (1/2-)29-33-45
BUTENE, all isomers F+ 12 (2-)9-16-33 Note C
2-BUTOXYETHANOL 111-76-2 Xn 20/21/22-37 (2-)24/25
2-(2-BUTOXYETHOXY)ETHANOL 112-34-5 Xi 36 (2-)26
2-(2-BUTOXYETHOXY)ETHYL THIOCYANATE 112-56-1 T 10-24/25 (1/2-)13-36/37-45
2-BUTOXYETHYL ACETATE 112-07-2 Xn 20/21 (2-)24
3-BUTOXY-2-PROPANOL 5131-66-8 Xi 36/38 (2)
1-(2-BUTOXYPROPOXY)PROPAN-2-OL 24083-03-2 Xn 21/22 (2)
n-BUTYL ACETATE 123-86-4 - 10 (2)
sec-BUTYL ACETATE 105-46-4 F 11 (2-)16-23-29-33 Note C
Page No. 6
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Substance CAS number Symbol Risk-phrases Safety phrases
tert-BUTYL ACETATE 540-88-5 F 11 (2-)16-23-29-33 Note C
ISOBUTYL ACETATE 110-19-0 F 11 (2-)16-23-29-33 Note C
n-BUTYL ACRYLATE 141-32-2 Xi 10-36/37/38-43 (2-)9 Note D
tert-BUTYL ALCOHOL 75-65-0 F,Xn 11-20 (2-)9-16
BUTYL ALCOHOL, except tert-BUTYL ALCOHOL 71-36-3 (n) Xn 10-20 (2-)16 Note C
BUTYLAMINE 109-73-9 F,C 11-20/21/22-35 (1/2-)3-16-26-29-36/37/39-45
sec-BUTYLAMINE 13952-84-6 F,C,N 11-20/22-35-50 (1/2-)9-16-26-28-36/37/39-
45-61
2-tert-BUTYLAMINOETHYL METHACRYLATE 3775-90-4 Xi 36/38-43 (2-)26 Note D
BUTYL BUTYRATE 109-21-7 - 10 (2) Note C
BUTYL CHLORIDE 109-69-3 F 11 (2-)9-16-29
BUTYL CHLOROFORMATE 592-34-7 T 10-23-34 (1/2-)26-36-45
4-tert-BUTYL-2-CHLOROPHENYL METHYL 299-86-5 Xn,N 21/22-50/53 (2-)36/37-60-61
METHYLPHOSPHORAMIDATE
tert-BUTYL CUMYL PEROXIDE 3457-61-2 O,Xi 7-38 (2-)3/7-14-36/37/39
BUTYL (DIALKYLOXY(DIBUTOXYPHOSPHORYLOXY))- F,Xi,N 11-36-51/53 (2-)7/9-16-26-43-61
TITANIUM (TRIALKYLOXY)TITANIUM PHOSPHATE
tert-BUTYL-I,I-DIMETHYL- 3457-61-2 O,Xi 7-38 (2-)3/7-14-36/37/39
BENZYL PEROXIDE
6-sec-BUTYL-2,4-DINITROPHENOL 88-85-7 T,N 61-62-24/25-36-44-50/53 53-45-60-61 Note E
2-tert-BUTYL-4,6-DINITROPHENOL 1420-07-1 T 61-24/25-36-44 53-45 Note E
2-sec-BUTYL-4,6-DINITROPHENYL 973-21-7 T 25 (1/2-)37-45
ISOPROPYL CARBONATE
2-sec-BUTYL-4,6-DINITROPHENYL-3-METHYL- 485-31-4 T 61-21/22 53-45 Note E
CROTONATE
1,3-BUTYLENEGLYCOL DIACRYLATE 19485-03-1 C 21-34-43 (1/2-)26-36/37/39-45 Note D
1,4-BUTYLENEGLYCOL DIACRYLATE 1070-70-8 C 21-34-43 (1/2-)26-36/37/39-45 Note D
BUTYL-2,3-EPOXYPROPYL ETHER 2426-08-6 Xn 20-43 (2-)24/25
BUTYL ETHYL KETONE 106-35-4 Xn 10-20-36 (2-)24
BUTYL FORMATE, all isomers 592-84-7(n) F 11 (2-)9-16-33 Note C
BUTYL GLYCIDYL ETHER 2426-08-6 Xn 20-43 (2-)24/25
BUTYLGLYCOL ACETATE 112-07-2 Xn 20/21 (2-)24
n-BUTYL METHACRYLATE 97-88-1 Xi 10-36/37/38-43 (2) Note D
BUTYL METHYL KETONE 591-78-6 F,T 11-48/23 (1/2-)9-16-29-45-51
1-BUTYL-2-METHYLPYRIDIUM BROMIDE 26576-84-1 Xn 22-52/53 (2-)61
sec-BUTYL NITRITE 924-43-6 F,Xn 11-20/22 (2-)16-24-46
tert-BUTYL NITRITE 540-80-7 F,Xn 11-20/22 (2-)16-24-46
BUTYL PROPIONATE, all isomers 591-01-2(n) - 10 (2) Note C
2-BUTYNE-1,4-DIOL 110-65-6 T 25-34 (1/2-)22-36-45
BUTYRALDEHYDE 123-72-8 F 11 (2-)9-29-33
BUTYRALDEHYDE OXIME 110-69-0 T 22-24-36 (1/2-)23-36-45
BUTYRIC ACID 107-92-6 C 34 (1/2-)26-36-45
n-BUTYRONITRILE 109-74-0 T 10-23/24/25 (1/2-)45
BUTYRYL CHLORIDE 141-75-3 F,C 11-34 (1/2-)16-23-26-36-45
CADMIUM CHLORIDE 10108-64-2 T 45-48/23/25 53-45 Note E
CADMIUM COMPOUNDS, except CADMIUM Xn 20/21/22 (2-)22* Note A
SULPHOSELENIDE, mixture of CADMIUM
SULPHIDE with ZINC- or MERCURY SULPHIDE *If appropriate
CADMIUMCYANIDE 542-83-6 T+ 26/27/28-32-33-40 (1/2-)7-28-29-45
CADMIUM FLUORIDE 7790-79-6 T 23/25-33-40 (1/2-)22-45
CADMIUM FLUOROSILICATE 17010-21-8 T 23/25-33-40 (1/2-)22-45
CADMIUMFORMATE 4464-23-7 T 23/25-33-40 (1/2-)22-45
CADMIUM HEXAFLUOROSILICATE 17010-21-8 T 23/25-33-40 (1/2-)22-45
CADMIUM IODIDE 7790-80-9 T 23/25-33-40 (1/2-)22-45
CADMIUM OXIDE 1306-19-0 T 49-22-48/23/25 53-45 Note E
CADMIUM SULPHATE 10124-36-4 T 49-22-48/23/25 53-45 Note E
CADMIUM SULPHIDE 1306-23-6 T 22-40-48/23/25 (1/2-)22-36/37-45
CAFFEINE 58-08-2 Xn 22 (2)
CALCIUM 7440-70-2 F 15 (2-)8-24/25-43
CALCIUM CARBIDE 75-20-7 F 15 (2-)8-43
CALCIUM CHLORIDE 10043-52-4 Xi 36 (2-)22-24
CALCIUM CHROMATE 13765-19-0 T,N 45-22-50/53 53-45-60-61 Note E
CALCIUM CYANAMIDE 156-62-7 Xn 22-37-41 (2-)22-26-36/37/39
Page No. 7
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Substance CAS number Symbol Risk-phrases Safety phrases
CALCIUM CYANIDE 592-01-8 T+ 28-32 (1/2-)7/8-23-36/37-45
CALCIUM HYDRIDE 7789-78-8 F 15 (2-)7/8-24/25-43
CALCIUM HYPOCHLORITE, active Chlorine>39% 7778-54-3 O,C 8-31-34 (1/2-)26-43-45
CALCIUM IODOXYBENZOATE, all isomers E 1 (2-)35 Note C
CALCIUM OCTADECYLXYLENESULPHONATE C,N 34-51/53 (1/2-)26-28-36/37/39-45-61
CALCIUM PHOSPHIDE 1305-99-3 F,T+ 15/29-28 (1/2-)22-43-45
CALCIUM POLYSULPHIDES 1344-81-6 Xi 31-36/37/38 (2-)28
CALCIUM SULPHIDE 20548-54-3 Xi 31-36/37/38 (2-)28
CALOMEL 10112-91-1 Xn 22-36/37/38 (2-)13-24/25-46
CAMPHECHLOR 8001-35-2 T,N 21-25-37/38-40-50/53 (1/2-)36/37-45-60-61
epsilon-CAPROLACTAM 105-60-2 Xn 20/22-36/37/38 (2)
CAPTAFOL 2425-06-1 T 45-43 53-45
CAPTAN 133-06-2 Xn 36-40-43 (2-)36/37
CARBADOX 6804-07-5 F,T 45-11-22 53-45 Note E
CARBANONITRIL 420-04-2 T 21-25-36/38-43 (1/2-)3-22-36/37-45
CARBARYL 63-25-2 Xn 22 (2-)22-24
CARBENDAZIM 10605-21-7 Xn 40 (2-)36/37
CARBOFURAN 1563-66-2 T+ 26/28 (1/2-)36/37-45
4,4'CARBONIMIDOYLBIS[N,N-DIMETHYLANILINE] 492-80-8 Xn,N 22-36-40-51/53 (2-)36/37-61
4,4'CARBONIMIDOYLBIS[N,N-DIMETHYLANILINE], SALTS Xn,N 22-36-40-51/53 (2-)36/37-61 Note A
CARBON DISULPHIDE 75-15-0 F,T 11-36/38-48/23-62-63 (1/2-)16-33-36/37-45
CARBON MONOXIDE 630-08-0 F+,T 61-12-23-48/23 53-45, Note E
CARBON TETRACHLORIDE 56-23-5 T,N 23/24/25-40-48/23- (1/2-)23-36/37-45-59-61
52/53-59
CARBONYL CHLORIDE 75-44-5 T+ 26-34 (1/2-)9-26-36/37/39-45
4,4'-CARBONYLDI(PHTHALIC ANHYDRIDE) 2421-28-5 Xi 36/37 (2-)25
CARBOPHENOTHION 786-19-6 T,N 24/25-50/53 (1/2-)28-36/37-45-60-61
CARTAP HYDROCHLORIDE 15263-52-2 Xn 21/22 (2-)36/37
CAUSTIC POTASH 1310-58-3 C 35 (1/2-)26-37/39-45
CAUSTIC SODA 1310-73-2 C 35 (1/2-)26-37/39-45
CELLOBIOHYDROLASE, exo- 37329-65-0 Xn 42 (2-)22-24-36/37
CELLULASE 9012-54-8 Xn 42 (2-)22-24-36/37
CELLULASES with exception of those specified 9012-54-8 Xn 42 (2-)22-24-36/37
elsewhere in this Annex
CELLULOSE NITRATE, containing a maximum of F 11 (2-)16-33-37/39
12.6% NITROGEN
CELLULOSE NITRATE, containing more than 12,6% 9004-70-0 E 1-3 (2-)35
NITROGEN
CHLORAL HYDRATE 302-17-0 T 25-36/38 (1/2-)25-45
2-CHLORALLYL (DIETHYL)DITHIOCARBAMATE 95-06-7 T 45-22 53-45, Note E
CHLORALOSE 15879-93-3 Xn 20/22 (2-)16-24/25-28
CHLORAMINE-T, SODIUM SALT 127-65-1 Xi 36/37/38 (2-)7-15
CHLORANIL 118-75-2 Xi,N 36/38-50/53 (2)37-60-61
CHLORDANE 57-74-9 Xn,N 21/22-40-50/53 (2-)36/37-60-61
CHLORDECONE 143-50-0 T 24/25-40 (1/2-)22-36/37-45
CHLORDIMEFORM 6164-98-3 Xn 21/22-40 (2-)22-36/37
CHLORDIMEFORM HYDROCHLORIDE 19750-95-9 Xn 22-40 (2-)22-36/37
CHLORENDIC ANHYDRIDE 115-27-5 Xi 36/37/38 (2-)25
CHLORFENAC 85-34-7 Xn 22 (2-)36
CHLORFENETHOL 80-06-8 Xn 22 (2-)36
CHLORFENPROP-METHYL 14437-17-3 Xn 21/22 (2-)36/37
CHLORFENSON 80-33-1 Xn 22-38 (2-)37
CHLORFENVINPHOS 470-90-6 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
CHLORINE 7782-50-5 T,N 23-36/37/38-50 (1/2-)9-45-61
CHLORMEPHOS 24934-91-6 T+ 27/28 (1/2-)28-36/37-45
CHLORMEQUAT CHLORIDE 999-81-5 Xn 21/22 (2-)36/37
CHLOROACETIC ACID 79-11-8 T,N 25-34-50 (1/2-)23-37-45-61
CHLOROACETONITRILE 107-14-2 T 23/24/25 (1/2-)45
CHLOROACETYL CHLORIDE 79-04-9 C 34-37 (1/2-)9-26-45
S-2-CHLOROALLYL (DIETHYL)DITHIOCARBAMATE 95-06-7 T 45-22 53-45, Note E
CHLOROANILINE mono-, di-, tri- T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61 Note C
CHLOROANILINES with exception of those T+,N 26/27/28-33-51/53 (1/2-)28-36/37-45-61 Note C
specified elsewhere in this Annex
Page No. 8
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Substance CAS number Symbol Risk-phrases Safety phrases
2-CHLOROBENZALDEHYDE 89-98-5 C 34 (1/2-)26-45
o-CHLOROBENZALDEHYDE 89-98-5 C 34 (1/2-)26-45
CHLOROBENZENE 108-90-7 Xn,N 10-20-51/53 (2-)24/25-61
CHLOROBENZILATE 510-15-6 Xn 22 (2)
2-CHLOROBENZONITRILE 873-32-5 Xn 21/22-36 (2-)23
2-CHLOROBUTA-1,3-DIENE 126-99-8 F,Xn 11-20/22-36 (2-)16 Note D
1-CHLOROBUTANE 109-69-3 F 11 (2-)9-16-29
4-CHLOROBUT-2-YNYL 3-CHLOROPHENYLCARBAMATE 101-27-9 Xn 22-43 (2-)24-36/37
CHLOROCRESOL 59-50-7 Xn,N 21/22-41-43-50 (2-)26-36/37/39-61
4-CHLORO-m-CRESOL 59-50-7 Xn,N 21/22-41-43-50 (2-)26-36/37/39-61
3-CHLORO-6-CYANO-BICYCLO(2.2.1)HEPTAN-2-ONE- 15271-41-7 T+ 24-28 (1/2-)28-36/37-45
O(N-METHYLCARBAMOYL)OXIME
2-(4-CHLORO-6-ETHYLAMINO-1,3,5-TRIAZINE-2- 21725-46-2 Xn 22 (2-)37
YLAMINO)-2-METHYLPROPIONITRILE
2-CHLORO-1-(2,4-DICHLOROPHENYL)VINYL DIETHYL 470-90-6 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
PHOSPHATE
2-CHLORO-2-DIETHYLCARBAMOYL-1-METHYLVINYL 13171-21-6 T+,N 24-28-40-50/53 (1/2-)23-36/37-45-60-61
DIMETHYL PHOSPHATE
2-CHLORO-4-DIMETHYLAMINO-6-METHYLPYRIMIDINE 535-89-7 T+ 28 (1/2-)36/37-45
CHLORODIMETHYL ETHER 107-30-2 F,T 45-11-20/21/22 53-45 Note E
CHLORODINITROBENZENE T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61 Note C
1-CHLORO-2,3-EPOXYPROPANE 106-89-8 T 45-10-23/24/25-34-43 53-45 Note E
CHLOROETHANE 75-00-3 F+,Xn 12-40-52/53 (2-)9-16-33-36/37-61
2-CHLOROETHANOL 107-07-3 T+ 26/27/28 (1/2-)7/9-28-45
2-CHLOROETHYL CHLOROPROPYL 2-CHLOROETHYL- Xn 22 (2)
PHOSPHONATE and 2-CHLOROETHYL CHLOROPROPYL
2-CHLOROPROPYLPHOSPHONATE, mixture of isomers
CHLOROETHYLENE 75-01-4 F+,T 45-12 53-45 Note D
2-CHLOROETHYLTRIMETHYL AMMONIUM CHLORIDE 999-81-5 Xn 21/22 (2-)36/37
CHLOROFORM 67-66-3 Xn 22-38-40-48/20/22 (2-)36/37
CHLOROFORMIC ACID BUTYL ESTER 592-34-7 T 10-23-34 (1/2-)26-36-45
CHLOROFORMIC ACID PROPYL ESTER 109-61-5 T 10-23-34 (1/2-)26-36-45
2-CHLORO-N-ISOPROPYLACETANILIDE 1918-16-7 Xn 22-36-43 (2-)24-37
CHLOROMETHANE 74-87-3 F+,Xn 12-40-48/20 (2-)9-16-33
(CHLOROMETHYL)BIS(4-FLUOROPHENYL)METHYLSILANE 85491-26-5 N 51/53 61
O-(3-CHLORO-4-METHYLCOUMARIN-7-YL) O,O- 56-72-4 T+,N 21-28-50/53 (1/2-)28-36/37-45-60-61
DIETHYL PHOSPHOROTHIOATE
CHLOROMETHYL METHYL ETHER 107-30-2 F,T 45-11-20/21/22 53-45 Note E
4-CHLORO-3-METHYLPHENOL 59-50-7 Xn,N 21/22-41-43-50 (2-)26-36/37/39-61
4-(4-CHLORO-o-TOLYLOXY) BUTYRIC ACID 94-81-5 Xn 22 (2-)24/25
2-(4-CHLORO-O-TOLYLOXY) PROPIONIC ACID 93-65-2 Xn 22-38-41 (2-)26-37/39
3-CHLORO-2-METHYLPROPENE 563-47-3 F,C,N 11-20/22-34-43-51/53 (2-)9-16-26-29-36/37/39-45-61
CHLORONITROANILINES with exception of those T+,N 26/27/28-33-51/53 (1/2-)28-36/37-45-61 Note C
specified elsewhere in this Annex
2-CHLORO-4-NITROANILINE 121-87-9 Xn,N 22-51/53 (2-)22-24-61
1-CHLORO-4-NITROBENZENE 100-00-5 T 23/24/25-33 (1/2-)28-37-45
p-CHLORONITROBENZENE 100-00-5 T 23/24/25-33 (1/2-)28-37-45
2-CHLORO-6-NITRO-3-PHENOXYANILINE 74070-46-5 N 50/53 60-61
O-(3-CHLORO-4-NITROPHENYL) O,O-DIMETHYL 500-28-7 Xn 20/21/22 (2-)13
PHOSPHOROTHIOATE
O-4-CHLORO-3-NITROPHENYL O,O-DIMETHYL 5826-76-6 Xn 20/21/22 (2-)13
PHOSPHOROTHIOATE
1-CHLORO-1-NITROPROPANE 600-25-9 Xn 20/22 (2)
S-(6-CHLORO-2-OXOBENZOXAZOLIN-3-YLMETHYL) 2310-17-0 T,N 21-25-50/53 (1/2-)36/37-45-60-61
O,O-DIETHYL PHOSPHORODITHIOATE
1-CHLOROPENTANE 543-59-9 F,Xn 11-20/21/22 (2-)9-29 Note C
2-CHLOROPENTANE 625-29-6 F,Xn 11-20/21/22 (2-)9-29 Note C
3-CHLOROPENTANE 616-20-6 F,Xn 11-20/21/22 (2-)9-29 Note C
3-CHLORO-4,5,I,I,I-PENTAFLUOROTOLUENE 77227-99-7 Xn,N 10-20/22-50-58 (2-)51-60-61
CHLOROPHACINONE 3691-35-8 T+ 23-27/28-48/24/25 (1/2-)36/37-45
CHLOROPHENOL, all isomers Xn 20/21/22 (2-)28 Note C
4-CHLOROPHENOXYACETIC ACID 122-88-3 Xn 22 (2)
O-4-(4-CHLOROPHENYLAZO)PHENYL O,O-DIMETHYL 5834-96-8 Xn 20/22 (2-)13
PHOSPHOROTHIOATE
Page No. 9
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Substance CAS number Symbol Risk-phrases Safety phrases
4-CHLOROPHENYL BENZENESULPHONATE 80-38-6 Xn 22-36 (2-)24-26
(CHLOROPHENYL)(CHLOROTOLYL)METHANE N 50/53 60-61
2-(4-(3-(4-CHLOROPHENYL)-4,5- 106359-93-7 Xi,N 36-50/53 (2-)26-60-61
DIHYDROPYRAZOLYL)PHENYLSULPHONYL)ETHYL-
DIMETHYLAMMONIUM HYDROGEN PHOSPHONATE
3-(4-CHLOROPHENYL)-1,1-DIMETHYLUREA 150-68-5 Xn 22-40 (2-)36/37
4-(2-CHLOROPHENYLHYDRAZONO)-3-METHYL-5- 5707-69-7 T 25 (1/2-)22-24-36/37-45
ISOXAZOLONE
3-(4-CHLOROPHENYL)-1-METHOXY-1-METHYLUREA 1746-81-2 Xn 22 (2-)22
2-[2-(4-CHLOROPHENYL)-2-PHENYLACETYL]INDAN- 3691-35-8 T+ 23-27/28-48/24/25 (1/2-)36/37-45
1,3-DIONE
2-(4-(3-(4-CHLOROPHENYL)-2-PYRAZOLIN-1-YL) C,N 34-43-48/22-50/53 (1/2-)24-26-28-37/39-45-60-61
PHENYLSULPHONYL)ETHYLDIMETHYLAMMONIUM FORMATE
S-(4-CHLOROPHENYLTHIOMETHYL) O,O-DIETHYL 786-19-6 T,N 24/25-50/53 (1/2-)28-36/37-45-60-61
PHOSPHORODITHIOATE
2-CHLORO-1-PHTHALIMIDOETHYL O,O-DIETHYL 10311-84-9 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
PHOSPHORODITHIOATE
CHLOROPICRIN 76-06-2 T+ 22-26-36/37/38 (1/2-)36/37-38-45
CHLOROPRENE 126-99-8 F,Xn 11-20/22-36 (2-)16 Note D
1-CHLOROPROPANE 540-54-5 F,Xn 11-20/21/22 (2-)9-29 Note C
2-CHLOROPROPANE 75-29-6 F,Xn 11-20/21/22 (2-)9-29 Note C
3-CHLOROPROPENE 107-05-1 F,T+,N 11-26-50 (1/2-)16-29-33-45-61 Note D
2-CHLOROPROPIONIC ACID 598-78-7 C 22-35 (1/2-)23-26-28-36-45
CHLOROSULPHONIC ACID 7790-94-5 C 14-35-37 (1/2-)26-45
CHLOROSULPHURIC ACID 7790-94-5 C 14-35-37 (1/2-)26-45
CHLOROTHALONIL 1897-45-6 Xn 40 (2-)36/37
2-CHLOROTOLUENE 95-49-8 Xn,N 20-51/53 (2-)24/25-61 Note C
3-CHLOROTOLUENE 108-41-8 Xn,N 20-51/53 (2-)24/25-61 Note C
4-CHLOROTOLUENE 106-43-3 Xn,N 20-51/53 (2-)24/25-61 Note C
CHLOROTOLUENE 25168-05-2 Xn,N 20-51/53 (2-)24/25-61 Note C
I-CHLOROTOLUENE 100-44-7 T 22-23-37/38-40-41 (1/2-)36/37-38-45
N2-(4-CHLORO-o-TOLYL)-N1,N1-DIMETHYL- 6164-98-3 Xn 21/22-40 (2-)22-36/37
FORMAMIDINE
N2-(4-CHLORO-o-TOLYL)-N1,N1-DIMETHYL- 19750-95-9 Xn 20-40 (2-)22-36/37
FORMAMIDINE HYDROCHLORIDE
4-CHLORO-o-TOLYLOXYACETIC ACID 94-74-6 Xn 22-38-41 (2-)26-37-39
4-(2-CHLORO-4-TRIFLUOROMETHYL)PHENOXY-2- T,N 22-41-43-48/25-50/53 (1/2-)26-36/37/39-45-60-61
FLUOROANILINE HYDROCHLORIDE
3-CHLORO-5-TRIFLUOROMETHYL-2-PYRIDYLAMINE 79456-26-1 Xn 22-52/53 (2-)61
CHLOROTRINITROBENZENE (mix) 28260-61-9 E,T+ 2-26/27/28 (1/2-)35-45 Note C
CHLORPHONIUM CHLORIDE 115-78-6 T 21-25-36/38 (1/2-)36/37/39-45
CHLORPYRIFOS 2921-88-2 T,N 24/25-50/53 (1/2-)28-36/37-45-60-61
CHLORTHIAMID 1918-13-4 Xn 22 (2-)36
CHLORTHION 500-28-7 Xn 20/21/22 (2-)13
CHLORTHIOPHOS 21923-23-9 T+ 24-28 (1/2-)28-36/37-45
CHOLCHICINE 64-86-8 T+ 26/28 (1/2-)13-45
CHROMIC CHROMATE 24613-89-6 O,T,C,N 45-8-35-43-50/53 53-45-60-61
CHROMIC OXYCHLORIDE 14977-61-8 O,T,C,N 49-46-8-35-43-50/53 53-45-60-61 Note E
CHROMIUM III CHROMATE 24613-89-6 O,T,C,N 45-8-35-43-50/53 53-45-60-61
CHROMIUM VI COMPOUNDS with exception of T,N 49-43-50/53 53-45-60-61 Note A, E
BARIUM CHROMATE and compounds specified
elsewhere in this Annex
CHROMIUM TRIOXIDE 1333-82-0 O,T,C,N 49-8-25-35-43-50/53 53-45-60-61 Note E
CHROMYL DICHLORIDE 14977-61-8 O,T,C,N 49-46-8-35-43-50/53 53-45-60-61 Note E
C.I. DIRECT BLACK 38 1937-37-7 T 45-63 53-45
C.I. DIRECT BLUE 6 2602-46-2 T 45-63 53-45
C.I. DIRECT BROWN 95 16071-86-6 T 45 53-45
C.I. DIRECT RED 28 573-58-0 T 45-63 53-45
C.I. SOLVENT YELLOW 34 492-80-8 Xn,N 22-36-40-51/53 (2-)36/37-61
CINERIN I 25402-06-6 Xn 22 (2)
CINERIN II 121-20-0 Xn 22 (2)
CITRAL 5392-40-5 Xi 38-43 (2-)24/25-37
CLOFOP-ISOBUTYL 51337-71-4 Xn 22 (2)
Page No. 10
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Substance CAS number Symbol Risk-phrases Safety phrases
CLOPYRALID 1702-17-6 Xi,N 41-51/53 (2-)26-39-61
COBALT 7440-48-4 Xn 42/43 (2-)22-24-37
COBALT OXIDE 1307-96-6 Xn 22-43 (2-)24-37
COBALT SULPHIDE 1317-42-6 Xi 43 (2-)24-37
COLCHICINE 64-86-8 T+ 26/28 (1/2-)13-45
COLOPHONY 8050-09-7 Xn 43 (2-)24-37
COPPER CHLORIDE 7758-89-6 Xn 22 (2-)22
COPPER(I) O,O-DIISOPROPYL PHOSPHORODITHIOATE N 50/53 60-61
and COPPER(I) O-ISOPROPYL O-(4-METHYLPENT-
2-YL) PHOSPHORODITHIOATE and COPPER(I)
O,O-BIS(4-METHYLPENT-2-YL) PHOSPHORODITHIOATE
COPPER NAPHTHENATE 1338-02-9 Xn 10-22 (2)
COPPER (I) OXIDE 1317-39-1 Xn 22 (2-)22
COPPER SULPHATE 7758-98-7 Xn 22-36/38 (2-)22
COUMACHLOR 81-82-3 Xn 48/22 (2-)37
COUMAFURYL 117-52-2 T 25-48/25 (1/2-)37-45
COUMAPHOS 56-72-4 T+,N 21-28-50/53 (1/2-)28-36/37-45-60-61
COUMATETRALYL 5836-29-3 T+ 27/28-48/24/25 (1/2-)36/37-45
COUMITHOATE 572-48-5 T 25 (1/2-)28-36/37-45
4-CPA 122-88-3 Xn 22 (2)
CRESOL, all isomers T 24/25-34 (1/2-)36/37/39-45 Note C
CRESYL GLYCIDYL ETHER 26447-14-3 Xi 38 (2-)26-28 Note C
CRIMIDINE 535-89-7 T+ 28 (1/2-)36/37-45
CROTONALDEHYDE 123-73-9 F,T 11-23-36/37/38 (1/2-)29-33-45
CROTOXYPHOS 7700-17-6 T 24/25 (1/2-)28-36/37-45
CRUFOMATE 299-86-5 Xn,N 21/22-50-53 (2-)36/37-60-61
CRYOLITE 15096-52-3 T 20/22-48/23/25 (1/2-)22-37-45
CUMENE 98-82-8 Xi 10-37 (2) Note C
CUMENE HYDROPEROXIDE 80-15-9 O,C 7-20/22-34 (1/2-)3/7-14-36/37/39-45-50
CUMITHOATE 572-48-5 T 25 (1/2-)28-36/37-45
CYANAMIDE 420-04-2 T 21-25-36/38-43 (1/2-)3-22-36/37-45
CYANAZINE 21725-46-2 Xn 22 (2-)37
CYANIDES, with the exception of COMPLEX T+ 26/27/28-32 (1/2-)7-28-29-45 Note A
CYANIDES as FERROCYANIDES, FERRICYANIDES
and MERCURIC OXOCYANIDE
S-[N-(1-CYANO-1-METHYLETHYL)CARBAMOYLMETHYL] 3734-95-0 T+ 24-28 (1/2-)36/37-45
O,O-DIETHYL PHOSPHOROTHIOATE
CYANOFENPHOS 13067-93-1 T 21-25-36-39/25 (1/2-)36/37-45
CYANOGEN 460-19-5 F,T 11-23 (1/2-)23-45
O-4-CYANOPHENYL O,O-DIMETHYL PHOSPHOROTHIOATE 2636-26-2 Xn,N 21/22-50/53 (2-)36/37-60-61
CYANOPHOS 2636-26-2 Xn,N 21/22-50/53 (2-)36/37-60-61
2-CYANOPROPAN-2-OL 75-86-5 T+,N 26/27/28-50 (1/2-)7/9-27-45-61
CYANTHOATE 3734-95-0 T+ 24-28 (1/2-)36/37-45
CYANURIC CHLORIDE 108-77-0 Xi 36/37/38 (2-)28
CYCLOBUTANE-1,3-DIONE 15506-53-3 F 11 (2-)9-16-33
CYCLOHEXANE 110-82-7 F 11 (2-)9-16-33
CYCLOHEXANE-1,2-DICARBOXYLIC ANHYDRIDE 85-42-7 Xi 36/37/38 (2-)23-39CYCLOHEXANOL 108-93-0 Xn 20/22-37/38 (2-)24/25
CYCLOHEXANONE 108-94-1 Xn 10-20 (2-)25
CYCLOHEXANONE PEROXIDE, mixture 12262-58-7 E,C 2-7-22-34 (1/2-)3/7-14-36/37/39-45 Note C
CYCLOHEX-4-ENE-1,2-DICARBOXYLIC ANHYDRIDE 85-43-8 Xi 36/37 (2-)25
CYCLOHEXYL ACRYLATE 3066-71-5 Xi 37/38 (2) Note D
CYCLOHEXYLAMINE 108-91-8 C 10-21/22-34 (1/2-)36/37/39-45
2-CYCLOHEXYL-4,6-DINITROPHENOL 131-89-5 T 23/24/25 (1/2-)13-45
CYCLOOCT-4-EN-1-YL METHYL CARBONATE 87731-18-8 Xi 43 (2-)24-37
CYCLOPENTANE 287-92-3 F 11 (2-)9-16-29-33
CYCLOPENTANE-1,2,3,4-TETRACARBOXYLIC 6053-68-5 Xi 36/37 (2-)25
DIANHYDRIDE
CYCLOPENTANONE 120-92-3 Xi 10-36/38 (2-)23
CYCLOPROPANE 75-19-4 F+ 12 (2-)9-16-33
CYHEXATIN 13121-70-5 Xn 20/21/22 (2-)13
CHYMOTRYPSIN 9004-07-3 Xn 36/37/38-42 (2-)22-24-26-36/37
2,4-D 94-75-7 Xn 22-36/37/38 (2-)36/37
Page No. 11
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Substance CAS number Symbol Risk-phrases Safety phrases
2,4-D, SALTS and ESTERS Xn 20/21/22 (2-)13 Note A
DALAPON 75-99-0 Xn 22-38-41 (2-)26-39
DAMINOZIDE 1596-84-5 Xn 40 (2-)36/37
DAPSONE 80-08-0 Xn 22 (2-)22
DAZOMET 533-74-4 Xn 22-36 (2-)15-22-24
2,4-DB 94-82-6 Xn 21/22 (2-)36/37
2,4-DB, SALTS Xn 20/21/22 (2-)13 Note A
DDT 50-29-3 T,N 25-40-48/25-50/53 (1/2-)22-36/37-45-60-61
DECACHLOROPENTACYCLO 143-50-0 T 24/25-40 (1/2-)22-36/37-45
(5.2.1.02,6.03,9.05,8) DECAN-4-ONE
DECARBOFURAN 1563-67-3 T 23/24/25 (1/2-)13-36/37-45
DEHYDRACETIC ACID 520-45-6 Xn 22 (2)
DEMEPHION-O 682-80-4 T+ 24-28 (1/2-)28-36/37-45
DEMEPHION-S 2587-90-8 T+ 24-28 (1/2-)28-36/37-45
DEMETON 8065-48-3 T+,N 27/28-50 (1/2-)28-36/37-45-61
DEMETON-O 298-03-3 T+,N 27/28-50 (1/2-)28-36/37-45-60-61
DEMETON-O-METHYL 867-27-6 T 25 (1/2-)24-36/37-45
DEMETON-S 126-75-0 T+ 27/28 (1/2-)28-36/37-45
DEMETON-S-METHYL 919-86-8 T,N 24/25-51/53 (1/2-)28-36/37-45-61
DEMETON-S-METHYL SULPHONE 17040-19-6 T 21-25 (1/2-)22-28-36/37-45
2,4-DES 149-26-7 Xn 22-38-41 (2-)26
DESMETRYNE 1014-69-3 Xn 21/22 (2-)36/37
DIACETONE ALCOHOL 123-42-2 F,Xi 11-36 (2-)7-16-24/25
DIACETONE ALCOHOL, TECHNICAL 123-42-2 F,Xi 11-36 (2-)7-16-24/25
N,N'-DIACETYLBENZIDINE 613-35-4 Xn 20/21/22 (2-)22-36
DIALIFOS 10311-84-9 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
DI-ALLATE 2303-16-4 Xn 22-40 (2-)25-36/37
N,N-DIALLYLCHLOROACETAMIDE 93-71-0 Xn 21/22-36/38 (2-)26-28-36/37/39
DIALLYL PHTHALATE 131-17-9 Xn 22 (2-)24/25
4,4'-DIAMINOBIPHENYL 92-87-5 T,N 45-22-50/53 53-45-60-61 Note E
4,4'-DIAMINODIPHENYLMETHANE 101-77-9 T,N 45-20/21/22-43- 53-45-61 Note E
48/20/21-51/53
4,4'-DIAMINO DIPHENYL SULPHONE 80-08-0 Xn 22 (2-)22
1,2-DIAMINOETHANE 107-15-3 C 10-21/22-34-42/43 (1/2-)23-26-36/37/39-45
2,5-DIAMINOTOLUENE SULPHATE 6369-59-1 T,N 20/21-25-43-50/53 (1/2-)24-37-45-60-61
S-(4,6-DIAMINO-1,3,5-TRIAZIN-2-YLMETHYL) 78-57-9 Xn 22-52/53 (2-)61
O,O-DIMETHYL PHOSPHORODITHIOATE
DIAMMINEDIISOCYANATOZINC Xn,N 22-41-42/43-50 (2-)22-26-36/37/39-41-61
o-DIANISIDINE 119-90-4 T 45-22 53-45 Note E
o-DIANISIDINE, SALTS T 45-22 53-45 Note A, E
3,6-DIAZAOCTANE-1,8-DIAMINE 112-24-3 C 21-34-43-52/53 (1/2-)26-36/37/39-45-61
DIAZINON 333-41-5 Xn,N 22-50/53 (2-)24/25-60-61
DIAZOMETHANE 334-88-3 T 45 53-45
DIBENZ[a,h]ANTHRACENE 53-70-3 T 45 53-45
DIBENZOYL PEROXIDE 94-36-0 E,Xi 2-7-36-43 (2-)3/7-14-36/37/39
1,2-DIBROMO-3-CHLOROPROPANE 96-12-8 T 45-46-60-25-48/20/22- 53-45-61 Note E
52/53
O-1,2-DIBROMO-2,2-DICHLOROETHYL 300-76-5 Xn 21/22-36/38 (2-)36/37
DIMETHYL PHOSPHATE
1,2-DIBROMOETHANE 106-93-4 T,N 45-23/24/25-36/37/38- 53-45-61 Note E
51/53
3,5-DIBROMO-4-HYDROXYBENZALDEHYDE 13181-17-4 Xn 22 (2-)25
O-(2,4-DINITROPHENYL) OXIME
3,5-DIBROMO-4-HYDROXYBENZONITRILE 1689-84-5 T 25-63 (1/2-)36/37-45
DIBROMOMETHANE 74-95-3 Xn 20-52/53 (2-)24-61
DI-n-BUTYLAMINE 111-92-2 Xn 10-20/21/22 (2)
DI-sec-BUTYLAMINE 626-23-3 Xn 10-20/21/22 (2)
DIBUTYL ETHER 142-96-1 Xi 10-36/37/38 (2)
DI-n-BUTYL ETHER 142-96-1 Xi 10-36/37/38 (2)
DI-tert-BUTYL PEROXIDE 110-05-4 O,F 7-11 (2-)3/7-14-16-36/37/39
DIBUTYLTIN HYDROGEN BORATE 75113-37-0 T,N 21/22-41-43-48/25-50/53 (1/2-)22-26-36/37-45-60-61
DICHLOBENIL 1194-65-6 Xn 21 (2-)36/37
DICHLOFENTHION 97-17-6 Xn,N 22-50/53 (2)-60-61
Page No. 12
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Substance CAS number Symbol Risk-phrases Safety phrases
DICHLOFLUANID 1085-98-9 Xi,N 36-43-50/53 (2-)22-24-60-61
DICHLONE 117-80-6 Xn 22-36/38 (2-)26
DICHLOROACETIC ACID 79-43-6 C 35 (1/2-)26-45
DICHLOROACETYL CHLORIDE 79-36-7 C 35 (1/2-)9-26-45
DICHLOROACETYLENE 7572-29-4 E,Xn 2-40-48/20 (2-)36/37
S-2,3-DICHLOROALLYL DIISOPROPYLTHIOCARBAMATE 2303-16-4 Xn 22-40 (2-)25-36/37
DICHLOROANILINE T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61 Note C
1,2-DICHLOROBENZENE 95-50-1 Xn,N 22-36/37/38-50/53 (2-)23-60-61
1,3-DICHLOROBENZENE 541-73-1 Xn,N 22-51/53 (2-)61
1,4-DICHLOROBENZENE 106-46-7 Xn 22-36/38 (2-)22-24/25-46
o-DICHLOROBENZENE 95-50-1 Xn,N 22-36/37/38-50/53 (2-)23-60-61
p-DICHLOROBENZENE 106-46-7 Xn 22-36/38 (2-)22-24/25-46
3,3'-DICHLOROBENZIDINE 91-94-1 T,N 45-21-43-50/53 53-45-60-61 Note E
3,3'-DICHLOROBENZIDINE, SALTS T,N 45-21-43-50/53 53-45-60-61 Note A, E
2,6-DICHLOROBENZONITRILE 1194-65-6 Xn 21 (2-)36/37
3,3'-DICHLOROBIPHENYL-4,4'-YLENEDIAMINE 91-94-1 T,N 45-21-43-50/53 53-45-60-61 Note E
3,3'-DICHLOROBIPHENYL-4,4'-YLENEDIAMINE, SALTS T,N 45-21-43-50/53 53-45-60-61 Note A, E
1,4-DICHLOROBUT-2-ENE 764-41-0 T+,N 45-24/25-26-34-50/53 53-45-60-61 Note E
DICHLORO 76253-60-6 N 50/53 60-61
[(DICHLOROPHENYL)METHYL]METHYLBENZENE
2,2'-DICHLORODIETHYL ETHER 111-44-4 T+ 10-26/27/28-40 (1/2-)7/9-27-38-45
3,5-DICHLORO-2,4-DIFLUOROBENZOYL FLUORIDE 101513-70-6 T,C 22-23-29-34-43-52/53 (1/2-)26-36/37/39-45-61
1,1-DICHLOROETHANE 75-34-3 F,Xn 11-22-36/37-52/53 (2-)16-23-61
1,2-DICHLOROETHANE 107-06-2 F,T 45-11-22-36/37/38 53-45 Note E
1,1-DICHLOROETHYLENE 75-35-4 F+,Xn 12-20-40 (2-)7-16-29 Note D
1,2-DICHLOROETHYLENE 540-59-0 F,Xn 11-20-52/53 (2-)7-16-29-61 Note C
cis-DICHLOROETHYLENE 156-59-2 F,Xn 11-20-52/53 (2-)7-16-29-61 Note C
trans-DICHLOROETHYLENE 156-60-5 F,Xn 11-20-52/53 (2-)7-16-29-61 Note C
1,3-DICHLORO-5-ETHYL-5-METHYLIMIDAZOLIDINE- 89415-87-2 O,T+,N 8-22-26-34-43-50 (1/2-)8-26-36/39-45-61
2,4-DIONE
2,4-DICHLORO-3-ETHYLPHENOL C,N 34-50/53 (1/2-)26-36/39-45-60-61
N'-DICHLOROFLUOROMETHYLTHIO-N,N-DIMETHYL-N'- 1085-98-9 Xi,N 36-43-50/53 (2-)22-24-60-61
PHENYLSULPHAMIDE
N-(DICHLOROFLUOROMETHYLTHIO)PHTHALIMIDE 719-96-0 Xi 38 (2-)28
DICHLOROISOCYANURIC ACID 2782-57-2 O,Xn 8-22-31-36/37 (2-)8-26-41
DICHLOROISOCYANURIC ACID, SODIUM SALT, 2893-78-9 O,Xn 8-22-31-36/37 (2-)8-26-41
and POTASSIUM SALT 2244-21-5
DICHLOROMETHANE 75-09-2 Xn 40 (2-)23-24/25-36/37
2,2'-DICHLORO-4,4'-METHYLENEDIANILINE 101-14-4 T,N 45-22-50/53 53-45-60-61 Note E
2,2'-DICHLORO-4,4'-METHYLENEDIANILINE, SALTS T,N 45-22-50/53 53-45-60-61 Note A, E
2,3-DICHLORO-1,4-NAPHTHOQUINONE 117-80-6 Xn 22-36/38 (2-)26
1,1-DICHLORO-1-NITROETHANE 594-72-9 T 23/24/25 (1/2-)26-45
DICHLOROPHEN 97-23-4 Xn 22-36 (2-)26
2,4-DICHLOROPHENOL 120-83-2 C,N 21/22-34-51/53 (1/2-)26-36/37/39-45-61
2,4-DICHLOROPHENOXYACETIC ACID 94-75-7 Xn 22-36/37/38 (2-)36/37
4-(2,4-DICHLOROPHENOXY) BUTYRIC ACID 94-82-6 Xn 21/22 (2-)36/37
2-(2,4-DICHLOROPHENOXY)ETHYL HYDROGENSULPHATE 149-26-8 Xn 22-38-41 (2-)26
2-(2,4-DICHLOROPHENOXY) PROPIONIC ACID 120-36-5 Xn 21/22-38-41 (2-)26-36/37
O-(2,4-DICHLOROPHENYL) O,O-DIETHYL 97-17-6 Xn,N 22-50/53 (2)-60-61
PHOSPHOROTHIOATE
3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA 330-54-1 Xn 48/22 (2-)22-37
1-(3,4-DICHLOROPHENYLIMINO) THIOSEMICARBAZIDE 5836-73-7 T+ 28 (1/2-)22-36/37-45
3-(3,4-DICHLOROPHENYL)-1-METHOXY-1-METHYLUREA 330-55-2 Xn 40 (2-)36/37
S-(2,5-DICHLOROPHENYLTHIOMETHYL) O,O-DIETHYL 2275-14-1 T,N 23/24/25-50/53 (1/2-)13-45-60-61
PHOSPHORODITHIOATE
1,2-DICHLOROPROPANE 78-87-5 F,Xn 11-20/22 (2-)16-24
1,3-DICHLORO-2-PROPANOL 96-23-1 T 45-21-25 53-45 Note E
1,1-DICHLOROPROPENE 563-58-6 F,T 11-25-52/53 (1/2-)16-29-33-45-61
1,3-DICHLOROPROPENE 542-75-6 T,N 10-20/21-25-36/37/38- (1/2-)36/37-45-60-61 Note D, C
43-50/53
(Z)-1,3-DICHLOROPROPENE 10061-01-5 T,N 10-20/21-25-36/37/38- (1/2-)36/37-45-60-61 Note D, C
43-50/53
3',4'-DICHLOROPROPIONANILIDE 709-98-8 Xn 22 (2-)22
Page No. 13
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Substance CAS number Symbol Risk-phrases Safety phrases
2,2-DICHLOROPROPIONIC ACID 75-99-0 Xn 22-38-41 (2-)26-39
3,6-DICHLOROPYRIDINE-2-CARBOXYLIC ACID 1702-17-6 Xi,N 41-51/53 (2-)26-39-61
2,4-DICHLORO-I-(PYRIMIDIN-5-YL) 26766-27-8 Xn 22 (2)
BENZHYDRYL ALCOHOL
3,7-DICHLOROQUINOLINE-8-CARBOXYLIC ACID 84-087-01-4 Xi 43 (2-)24-37
3,5-DICHLORO-4-(1,1,2,2-TETRAFLUOROETHOXY) 104147-32-2 Xn,N 22-50/53 (2-)24/25-26-57-60-61
ANILINE
2,6-DICHLORO (THIOBENZAMIDE) 1918-13-4 Xn 22 (2-)36
I,I-DICHLOROTOLUENE 98-87-3 T 22-23-36/37-38-40-41 (1/2-)36/37-38-45
DICHLORO-1,3,5-TRIAZINETRIONE 2782-57-2 O,Xn 8-22-31-36/37 (2-)8-26-41
DICHLORO-1,3,5-TRIAZINETRIONE, SODIUM SALT, 2893-78-9 O,Xn 8-22-31-36/37 (2-)8-26-41
POTASSIUM SALT 2244-21-5
2,2-DICHLOROVINYL DIMETHYL PHOSPHATE 62-73-7 T 24/25 (1/2-)23-36/37-45
2,2-DICHLOROVINYL-2-ETHYLSULPHINYLETHYL 7076-53-1 T 23/24/25 (1/2-)13-45
METHYL PHOSPHATE
DICHLORPROP 120-36-5 Xn 21/22-38-41 (2-)26-36/37
DICHLORPROP, SALTS Xn 20/21/22 (2-)13 Note A
DICHLORVOS 62-73-7 T 24/25 (1/2-)23-36/37-45
DICHROMIUM TRIS(CHROMATE) 24613-89-6 O,T,C,N 45-8-35-43-50/53 53-45-60-61
DICLOFOP-METHYL 51338-27-3 Xn 22 (2)
DICOFOL 115-32-2 Xn 21/22-38-43 (2-)36/37
DICOUMARIN 66-76-2 T 22-48/25 (1/2-)37-45
DICROTOPHOS 141-66-2 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
DICUMYL PEROXIDE 80-43-3 O,Xi 7-36/38 (2-)3/7-14-36/37/39
5,10-DIHYDRO-5,10-DIOXONAPHTHO(2,3-b)(1,4)- 3347-22-6 Xn 22 (2-)24
DITHIAZINE-2,3-DICARBONITRILE
DICYCLOHEXYLAMINE 101-83-7 C,N 22-34-50/53 (1/2-)26-36/37/39-45-60-61
DICYCLOHEXYLAMMONIUM NITRITE 3129-91-7 Xn 20/22 (2-)15-41
DICYCLOHEXYLCARBODIIMIDE 538-75-0 T 22-24-41-43 (1/2-)24-26-37/39-45
DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE 5124-30-1 T 23-36/37/38-42/43 (1/2-)26-28-38-45
DIELDRIN 60-57-1 T+,N 25-27-40-48/25-50/53 (1/2-)22-36/37-45-60-61
1,2,3,4-DIEPOXYBUTANE 1464-53-5 T 23/24/25-36/37/38-40-
42/43 (1/2-)23-24-45
DIETHANOLAMINE 111-42-2 Xi 36/38 (2-)26
DIETHANOLAMINE SALT of 4-CPA Xn 22 (2)
1,1-DIETHOXYETHANE 105-57-7 F,Xi 11-36/38 (2-)9-16-33
I-(DIETHOXYPHOSPHINOTHIOYLIMINO) 14816-18-3 Xn 22 (2-)36
PHENYL ACETONITRILE
DIETHYLAMINE 109-89-7 F,C 11-20/21/22-35 (1/2-)3-16-26-29-36/37/39-45
2-DIETHYLAMINOETHANOL 100-37-8 Xi 36/37/38 (2-)28
2-DIETHYLAMINOETHYL METHACRYLATE 105-16-8 Xn 20-36/38-43 (2-)26 Note D
2,6-DIETHYLANILINE 579-66-8 Xn 22 (2-)23-34
N,N-DIETHYLANILINE 91-66-7 T,N 23/24/25-33-51/53 (1/2-)28-37-45-61
DIETHYLCARBAMOYL CHLORIDE 88-10-8 Xn 20/22-36/37/38-40 (2-)26-36/37
N,N-DIETHYL-1,3-DIAMINOPROPANE 104-78-9 C 10-21/22-34-43 (1/2-)26-36/37/39-45
O,O-DIETHYL O-2-DIETHYLAMINO-6- 23505-41-1 T,N 21-25-50/53 (1/2-)23-36/37-45-60-61
METHYLPYRIMIDIN-4-YL PHOSPHOROTHIOATE
DIETHYLENE GLYCOL DIACRYLATE 4074-88-8 T 24-36/38-43 (1/2-)28-39-45 Note D
DIETHYLENE GLYCOL DINITRATE 693-21-0 E,T+ 3-26/27/28-33 (1/2-)33-35-36/37-45
DIETHYLENETRIAMINE 111-40-0 C 21/22-34-43 (1/2-)26-36/37/39-45
DIETHYL ETHER 60-29-7 F+ 12-19 (2-)9-16-29-33
DIETHYL(ETHYLDIMETHYLSILANOLATO)ALUMINIUM 55426-95-4 F,C 14/15-17-35 (1/2-)6-16-30-36/39-43-45
O,O-DIETHYL S-[2-(ETHYLSULPHINYL)ETHYL] 2497-07-6 T+ 24-28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
O,O-DIETHYL-O-[2-(ETHYLTHIO)ETHYL] PHOSPHORO- 298-03-3 T+,N 27/28-50 (1/2-)28-36/37-45-61
THIOATE
O,O-DIETHYL-S-[2-(ETHYLTHIO)ETHYL] PHOSPHORO- 298-04-4 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
DITHIOATE
DIETHYL-S-[2-(ETHYLTHIO)ETHYL] PHOSPHORO- 126-75-0 T+ 27/28 (1/2-)28-36/37-45
THIOATE
O,O-DIETHYL ETHYLTHIOMETHYL 298-02-2 T+ 27/28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
O,O-DIETHYL ISOPROPYLCARBAMOYLMETHYL 2275-18-5 T+ 27/28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
Page No. 14
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Substance CAS number Symbol Risk-phrases Safety phrases
O,O-DIETHYL-O-2-ISOPROPYL-6-METHYL- 333-41-5 Xn,N 22-50/53 (2-)24/25-60-61
PYRIMIDIN-4-YL PHOSPHOROTHIOATE
DIETHYL KETONE 96-22-0 F 11 (2-)9-16-33
O,O-DIETHYL-O-(4-METHYLCOUMARIN-7-YL) 299-45-6 T+ 26/27/28 (1/2-)13-28-45
PHOSPHOROTHIOATE
DIETHYL 4-METHYL-1,3-DITHIOLAN- 950-10-7 T+,N 27/28-51/53 (1/2-)36/37/39-45-61
2-YLIDENEPHOSPHOROAMIDATE
DIETHYL 3-METHYLPYRAZOL-5-YL PHOSPHATE 108-34-9 T+ 26/27/28 (1/2-)13-28-45
O,O-DIETHYL O-[4-(METHYLSULPHINYL)PHENYL] 115-90-2 T+,N 27/28-50/53 (1/2-)23-28-36/37-45-60-61
PHOSPHOROTHIOATE
O,O-DIETHYL O-4-NITROPHENYL PHOSPHOROTHIOATE 56-38-2 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
DIETHYL OXALATE 95-92-1 Xn 22-36 (2-)23
S-(O,O-DIETHYL 4-OXOBENZOTRIAZIN-3-YLMETHYL 2642-71-9 T+ 24-28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
N,N-DIETHYL-p-PHENYLENDIAMINE 93-05-0 T 25-34 (1/2-)26-36-45
DIETHYL SULPHATE 64-67-5 T 45-46-20/21/22-34 53-45 Note E
O,O-DIETHYL O-7,8,9,10-TETRAHYDRO-6- 572-48-5 T 25 (1/2-)28-36/37-45
OXOBENZO[c]CHROMEN-3-YL PHOSPHOROTHIOATE
N,N-DIETHYL-m-TOLUAMIDE 134-62-3 Xn 22-36/38 (2)
O,O-DIETHYL O-3,5,6-TRICHLORO-2-PYRIDYL 2921-88-2 T,N 24/25-50/53 (1/2-)28-36/37-45-60-61
PHOSPHOROTHIOATE
DIFENACOUM 56073-07-5 T+ 28-48/25 (1/2-)36/37-45
DIFENZOQUAT-METHYLSULPHATE 43222-48-6 Xn 22 (2)
DIGITOXIN 71-63-6 T 23/25-33 (1/2-)-45
DIGOL DINITRATE 693-21-0 E,T+ 3-26/27/28-33 (1/2-)33-35-36/37-45
9,10-DIHYDRO-8a,10a-DIAZONIAPHENANTHRENE ION 2764-72-9 T 24/25-36/37/38 (1/2-)22-36/37/39-45
2,3-DIHYDRO-2,2-DIMETHYLBENZOFURAN-7-YL 1563-66-2 T+ 26/28 (1/2-)36/37-45
METHYLCARBAMATE
2,3-DIHYDRO-5-METHOXY-2-OXO-1,3,4-THIADIAZOL- 950-37-8 T+,N 21-28-50/53 (1/2-)22-28-36/37-45-60-61
3-YLMETHYL-O,O-DIMETHYL PHOSPHORODITHIOATE
2,3-DIHYDRO-2-METHYLBENZOFURAN-7-YL 1563-67-3 T 23/24/25 (1/2-)13-36/37-45
METHYLCARBAMATE
1,2-DIHYDROXYBENZENE 120-80-9 Xn 21/22-36/38 (2-)22-26-37
1,4-DIHYDROXYBENZENE 123-31-9 Xn 20/22 (2-)24/25-39
DI-ISOBUTYLENE 107-39-1 F 11 (2-)9-16-29-33
DI-ISOBUTYL KETONE 108-83-8 Xi 10-37 (2-)24
2,6-DI-ISOCYANATE TOLUENE 91-08-7 T 23-36/37/38-42 (1/2-)23-26-28-38-45 Note C
DI-ISOPROPANOLAMINE 110-97-4 Xi 36 (2-)26
DI-ISOPROPYL ETHER 108-20-3 F 11-19 (2-)9-16-33
DI-ISOPROPYL KETONE 565-80-0 F 11 (2-)16-23
O,O-DIISOPROPYL 2-PHENYLSULPHONYL- 741-58-2 Xn 22 (2-)24-36
AMINOETHYL PHOSPHORODITHIOATE
N,N'-DIISOPROPYLPHOSPHORODIAMINIC FLUORIDE 371-86-8 T+ 39/26/27/28 (1/2-)13-45
DIKETENE 674-82-8 Xn 10-20 (2-)3 Note D
DILAUROYL PEROXIDE 105-74-8 O 7 (2-)3/7-14-36/37/39
DILITHIUM 6-ACETAMIDO-4-HYDROXY-3-(4-((2- Xi 43 (2-)24-37
SULPHONATOOXY)ETHYLSULPHONYL)PHENYLAZO)
NAPHTHALENE-2-SULPHONATE
DIMEFOX 115-26-4 T+ 27/28 (1/2-)23-28-36/37-38-45
DIMEPRANOL 108-16-7 C 10-22-34 (1/2-)23-26-36-45
DIMERCURY DICHLORIDE 10112-91-1 Xn 22-36/37/38 (2-)13-24/25-46
DIMETAN 122-15-6 T 25 (1/2-)36/37-45
DIMETHOATE 60-51-5 Xn 21/22 (2-)36/37
3,3'-DIMETHOXYBENZIDINE 119-90-4 T 45-22 53-45 Note E
3,3'-DIMETHOXYBENZIDINE, SALTS T 45-22 53-45 Note A, E
1,1-DIMETHOXYETHANE 534-15-6 F 11 (2-)9-16-33
1,2-DIMETHOXYETHANE 110-71-4 Xn 10-19-20 (2-)24/25
DIMETHYL ACETAL 534-15-6 F 11 (2-)9-16-33
N,N-DIMETHYLACETAMIDE 127-19-5 Xn 20/21-36 (2-)26-28-36
O,S-DIMETHYL ACETYLPHOSPHORAMIDOTHIOATE 30560-19-1 Xn 22 (2-)36
2-DIMETHYLAMINO-5,6-DIMETHYLPYRIMIDIN-4-YL 23103-98-2 T 25 (1/2-)22-37-45
DIMETHYLCARBAMATE
2-DIMETHYLAMINOETHANOL 108-01-0 Xi 10-36/37/38 (2-)28
Page No. 15
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Substance CAS number Symbol Risk-phrases Safety phrases
2-DIMETHYLAMINOETHYLAMINE 108-00-9 F,C 11-21/22-35 (1/2-)16-23-26-28-36-45
3-DIMETHYLAMINOMETHYLENEAMINOPHENYL 22259-30-9 T+ 28 (1/2-)22-36/37-45
METHYLCARBAMATE
2-DIMETHYLAMINOETHYL METHACRYLATE 2867-47-2 Xn 21/22-36/38-43 (2-)26-28 Note D
3-(DIMETHYLAMINO)PROPYLUREA 31506-43-1 Xi 41 (2-)26-39
N-DIMETHYLAMINOSUCCINAMIC ACID 1596-84-5 Xn 40 (2-)36/37
4-DIMETHYLAMINO-3-TOLYL METHYLCARBAMATE 2032-59-9 T 24/25 (1/2-)28-36/37-45
4-DIMETHYLAMINO-3,5-XYLYL METHYLCARBAMATE 315-18-4 T+ 21-28 (1/2-)36/37-45
N,N-DIMETHYLANILINE 121-69-7 T,N 23/24/25-40-51/53 (1/2-)28-36/37-45-61
2,2'-DIMETHYL-2,2'AZODIPROPIONITRILE 78-67-1 E,Xn 2-11-20/22 (2-)39-41-47
N,N-DIMETHYLBENZENE-1,3-DIAMINE 2836-04-6 T 23/24/25 (1/2-)28-45 Note C
N,N'-DIMETHYLBENZENE-1,4-DIAMINE 99-98-9 T 23/24/25 (1/2-)28-45 Note C
3,3'-DIMETHYLBENZIDINE 119-93-7 T,N 45-22-51/53 53-45-61 Note E
3,3'-DIMETHYLBENZIDINE, SALTS T,N 45-22-51/53 53-45-61 Note A, E
N,N'-DIMETHYLBENZIDINE 2810-74-4 Xn 20/21/22 (2-)22-36
2,2-DIMETHYL-1,3-BENZODIOXOL-4-OL 22961-82-6 Xi 41 (2-)24-26-39
I,I-DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 O,C 7-20/22-34 (1/2-)3/7-14-36/37/39-45-50
1,1'-DIMETHYL-4,4'-BIPYRIDINIUM ION 4685-14-7 T 24/25-36/37/38 (1/2-)22-36/37/39-45
DIMETHYLCARBAMOYL CHLORIDE 79-44-7 T 45-22-23-36/37/38 53-45 Note E
1-DIMETHYLCARBAMOYL-5-METHYLPYRAZOL-3-YL 644-64-4 T 21-25 (1/2-)36/37-45
DIMETHYLCARBAMATE
DIMETHYL CARBONATE 616-38-6 F 11 (2-)9-16
N,N-DIMETHYL-2-(3-(4-CHLOROPHENYL)-4,5- 10357-99-0 Xn,N 43-48/22-51/53 (2-)24-37-61
DIHYDROPYAZOL-1-YLPHENYLSULPHONYL)ETHYLAMINE
1,4-DIMETHYLCYCLOHEXANE 589-90-2 F 11 (2-)9-16-33
N,N-DIMETHYL-1,3-DIAMINOPROPANE 109-55-7 C 10-22-34-43 (1/2-)26-36/37/39-45
DIMETHYLDICHLOROSILANE 75-78-5 F,Xi 11-36/37/38 (2)
DIMETHYL cis-2-DIMETHYLCARBAMOYL-1- 141-66-2 T+,N 22-28-50/53 (1/2-)28-36/37-45-60-61
METHYLVINYL PHOSPHATE
N,N-DIMETHYL-2,2-DIPHENYLACETAMIDE 957-51-7 Xn 22 (2)
DIMETHYL ETHER 115-10-6 F+ 12 (2-)9-16-33
DIMETHYL FORMAMIDE 68-12-2 T 61-20/21-36 53-45 Note E
N,N-DIMETHYLFORMAMIDE 68-12-2 T 61-20/21-36 53-45 Note E
2,6-DIMETHYLHEPTAN-4-ONE 108-83-8 Xi 10-37 (2-)24
1,2-DIMETHYLHYDRAZINE 540-73-8 T 45-23/24/25 53-45 Note E
N,N-DIMETHYLHYDRAZINE 57-14-7 F,T 45-11-23/25-34 53-45 Note E
1,2-DIMETHYLIMIDAZOLE 1739-84-0 Xn 22-38-41 (2-)24-26
O,O-DIMETHYL-S-2-(1-METHYLCARBAMOYLETHYL- 2275-23-2 T,N 21-25-50 (1/2-)36/37-45-61
THIO)ETHYL PHOSPHOROTHIOATE
O,O-DIMETHYL METHYLCARBAMOYLMETHYL 60-51-5 Xn 21/22 (2-)36/37
PHOSPHORODITHIOATE
O,O-DIMETHYL-S-METHYLCARBAMOYLMETHYL 1113-02-6 T,N 21-25-50 (1/2-)23-36/37-45-61
PHOSPHOROTHIOATE
DIMETHYL-1-METHYL-2-(METHYLCARBAMOYL)VINYL 6923-22-4 T+,N 24-28-50/53 (1/2-)23-36/37-45-60-61
PHOSPHATE
2,2'-DIMETHYL-4,4'- 6864-37-5 T,C,N 22-23/24-35-51/53 (1/2-)26-36/37/39-45-61
METHYLENEBIS(CYCLOHEXYLAMINE)
O,O-DIMETHYL-O-(4-METHYLTHION-m-TOLYL) 55-38-9 T,N 21-25-50/53 (1/2-)36/37-45-60-61
PHOSPHOROTHIOATE
DIMETHYL 4-(METHYLTHIO)PHENYL PHOSPHATE 3254-63-5 T+ 27/28 (1/2-)28-36/37-45
O,O-DIMETHYL-O-4-NITRO-m-TOLYL 122-14-5 Xn,N 22-50/53 (2-)60-61
PHOSPHOROTHIOATE
O,O-DIMETHYL-S-(MORPHOLINOCARBONYLMETHYL) 144-41-2 T,N 23/24/25-50/53 (1/2-)13-45-60-61
PHOSPHORODITHIOATE
O,O-DIMETHYL O-4-NITROPHENYL PHOSPHOROTHIOATE 298-00-0 T+ 24-28 (1/2-)28-36/37-45
DIMETHYLNITROSOAMINE 62-75-9 T+,N 45-25-26-48/25-51/53 53-45-61 Note E
7,7-DIMETHYL-3-OXA-6-AZAOCTAN-1-OL C 22-35 (1/2-)26-28-36/37/39-45
O,O-DIMETHYL 4-OXOBENZOTRIAZIN-3-YLMETHYL 86-50-0 T+ 24-28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
5,5-DIMETHYL-3-OXOCYCLOHEX-1-ENYL 122-15-6 T 25 (1/2-)36/37-45
DIMETHYLCARBAMATE
2,4-DIMETHYLPENTAN-3-ONE 565-80-0 F 11 (2-)16-23
O,S-DIMETHYL PHOSPHOROAMIDOTHIOATE 10265-92-6 T+,N 24-28-36-50 (1/2-)22-28-36/37-45-61
Page No. 16
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Substance CAS number Symbol Risk-phrases Safety phrases
O,O-DIMETHYL S-PHTHALIMIDOMETHYL 732-11-6 Xn 21/22 (2-)22-36/37
PHOSPHORODITHIOATE
2,2-DIMETHYL PROPANE 463-82-1 F+ 12 (2-)9-16-33
N,N'-(2,2-DIMETHYLPROPYLIDENE)HEXAMETHYLENE 1000-78-8 Xi 38-43 (2-)24-37
DIAMINE
DIMETHYLSULFAMOYLCHLORIDE 13360-57-1 T+ 45-21/22-26-34 53-45 Note E
DIMETHYL SULPHATE 77-78-1 T+ 45-25-26-34 53-45 Note E
N,N-DIMETHYLTOLUIDINE, all isomers T 23/24/25-33-52/53 (1/2-)28-36/37-45-61 Note C
DIMETHYL 2,2,2-TRICHLORO-1-HYDROXY- 52-68-6 Xn 22-43 (2-)24-37
ETHYLPHOSPHONATE
O,O-DIMETHYL-O-2,4,5-TRICHLOROPHENYL 299-84-3 Xn 21/22 (2-)25-36/37
PHOSPHOROTHIOATE
2,6-DIMETHYL-4-TRIDECYLMORPHOLINE 24602-86-6 Xn 21/22 (2-)25-36/37
2,2-DIMETHYLTRIMETHYLENE DIACRYLATE 2223-82-7 T 24-36/38-43 (1/2-)28-39-45 Note D
DIMETILAN 644-64-4 T 21-25 (1/2-)36/37-45
DIMEXANO 1468-37-7 Xn 22 (2)
DINEX 131-89-5 T 23/24/25 (1/2-)13-45
DINEX, SALTS and ESTERS T 23/24/25 (1/2-)13-45 Note A
DINICKEL TRIOXIDE 1314-06-3 T 49-43 53-45
2,4-DINITROANILINE 97-02-9 T+,N 26/27/28-33-51/53 (1/2-)28-36/37-45-61
DINITROBENZENE, all isomers 25154-54-5 T+,N 26/27/28-33-50/53 (1/2-)28-36/37-45-60-61 Note C
4,6-DINITRO-o-CRESOL, AMMONIUM SALT 2980-64-5 T+ 26/27/28-33 (1/2-)13-28-45
4,6-DINITRO-o-CRESOL, POTASSIUM SALT 5787-96-2 T 23/24/25-33 (1/2-)13-45
4,6-DINITRO-o-CRESOL, SODIUM SALT 2312-76-7 T 23/24/25-33 (1/2-)13-45
DINITROGEN TETROXIDE 10544-72-6 T+ 26-34 (1/2-)9-26-28-36/37/39-45
2,6-DINITRO-4-OCTYLPHENYL and 39300-45-3 Xn 22-38 (2-)37
2,4-DINITRO-6-OCTYLPHENYL CROTONATES
DINITROPHENOL 25550-58-7 T 23/24/25-33 (1/2-)28-37-45 Note C
DINITROPHENOL, SALTS T 23/24/25-33 (1/2-)28-37-45 Note A
DINITROTOLUENE 25321-14-6 T 23/24/25-33 (1/2-)28-37-45 Note C
DINOBUTON 973-21-7 T 25 (1/2-)37-45
DINOCAP 39300-45-3 Xn 22-38 (2-)37
DINOCTON 63919-26-6 Xn 22 (2)
DINOCTON-6 8069-76-9 Xn 22 (2)
8,9-DINORBORN-5-ENE-2,3-DICARBOXYLIC 123748-85-6 Xn 22-36/37/38-42 (2-)39 Note C
ANHYDRIDE
DINOSAM 4097-36-3 T 23/24/25 (1/2-)13-45
DINOSAM, SALTS and ESTERS T 23/24/25 (1/2-)13-45 Note A
DINOSEB 88-85-7 T,N 61-62-24/25-36-44-50/53 53-45-60-61 Note E
DINOSEB, SALTS and ESTERS T 61-62-24/25-36-44 53-45 Note A, E
DINOTERB 1420-07-1 T 61-23/24/25-36-44 53-45 Note E
DINOTERB, SALTS and ESTERS T 61-23/24/25 53-45 Note A, E
DIOXACARB 6988-21-2 T 25 (1/2-)37-45
1,4-DIOXANE 123-91-1 F,Xn 11-19-36/37-40 (2-)16-36/37
1,4-DIOXAN-2,3-DIYL-O,O,O',O'-TETRAETHYL 78-34-2 T+ 24-26/28 (1/2-)28-36/37-45
DI(PHOSPHORODITHIOATE)
DIOXATHION 78-34-2 T+ 24-26/28 (1/2-)28-36/37-45
1,3-DIOXOLANE 646-06-0 F 11 (2-)16
2-(1,3-DIOXOLAN-2-YL)PHENYL METHYLCARBAMATE 6988-21-2 T 25 (1/2-)37-45
N-(4-(4-(2,5-DIOXOPYRROL- Xi,N 43-50/53 (2-)24-37-60-61
1-YL)BENZYL)PHENYL)ACETAMIDE
DIPENTENE 138-86-3 Xi 10-38 (2-)28
DIPHACINONE 82-66-6 T+ 28-48/23/24/25 (1/2-)36/37-45
DIPHENAMID 957-51-7 Xn 22 (2)
DIPHENYL 92-52-4 Xi,N 36/37/38-50/53 (2-)23-60-61
DIPHENYLAMINE 122-39-4 T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61
1,2-DIPHENYLHYDRAZINE 122-66-7 T 45-22 53-45 Note E
DIPHENYLMETHANEDIISOCYANATE, isomers 9016-87-9 Xn 20-36/37/38-42 (2-)26-28-38-45 Note C
and homologues
DIPHENYLMETHANE-2,2'-DIISOCYANATE 2536-05-2 Xn 20-36/37/38-42 (2-)26-28-38-45 Note C
DIPHENYLMETHANE-2,4'-DIISOCYANATE 5873-54-1 Xn 20-36/37/38-42 (2-)26-28-38-45 Note C
DIPHENYLMETHANE-4,4'-DIISOCYANATE 101-68-8 Xn 20-36/37/38-42 (2-)26-28-38-45 Note C
DIPICRYLAMINE, AMMONIUM SALT 2844-92-0 E,T+,N 1-26/27/28-33-51/53 (1/2-)28-36/37-45-61
Page No. 17
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Substance CAS number Symbol Risk-phrases Safety phrases
DIPROPYLAMINE 142-84-7 F,C 11-20/21/22-35 (1/2-)16-26-36/37/39-45
DIPROPYLENETRIAMINE 56-18-8 T+,C 22-24-26-35-43 (1/2-)26-28-36/37/39-45
DI-n-PROPYL ETHER 111-43-3 F 11-19 (2-)9-16-33
DIPROPYL KETONE 123-19-3 - 10 (2-)23
DIQUAT 2764-72-9 T 24/25-36/37/38 (1/2-)22-36/37/39-45
DIQUAT, SALTS T 24/25-36/37/38 (1/2-)22-36/37/39-45 Note A
DISODIUM N-CARBOXYMETHYL-N-(2- 92511-22-3 Xi 41 (2-)26-39
(2-HYDROXYETHOXY)ETHYL)GLYCINATE
DISODIUM ETHYLENEBISDITHIOCARBAMATE 142-59-6 Xn 22-37-43 (2-)8-24/25-46
DISODIUM S,S'-HEXANE-1,6-DIYLDI(THIOSULPHATE) Xi 43-52/53 (2-)22-24-37-61
DIHYDRATE
DISODIUM METASILICATE 6834-92-0 C 34-37 (1/2-)13-24/25-36/37/39-45
DISODIUM 7-OXABICYCLO(2,2,1)HEPTANE-2,3- 129-67-9 T 21-25-36/37/38 (1/2-)36/37/39-45
DICARBOXYLATE
DISULFOTON 298-04-4 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
DISULPHUR DICHLORIDE 10025-67-9 C 14-34-37 (1/2-)26-45
DITALIMFOS 5131-24-8 Xi 38-43 (2-)36/37
DITHALLIUM SULPHATE 7446-18-6 T+ 28-38-48/25 (1/2-)13-36/37-45
DITHIANON 3347-22-6 Xn 22 (2-)24
DIURON 330-54-1 Xn 48/22 (2-)22-37
DIXANTHOGEN 502-55-6 Xn 22 (2-)24
DNOC 534-52-1 T+ 27/28-33-36-40-44 (1/2-)36/37-45
DNOC, AMMONIUM SALT 2980-64-5 T+ 26/27/28-33 (1/2-)13-28-45
DNOC, POTASSIUM SALT 5787-96-2 T 23/24/25-33 (1/2-)13-45
DNOC, SODIUM SALT 2312-76-7 T 23/24/25-33 (1/2-)13-45
DODECYLQUANIDIUM ACETATE 2439-10-3 Xn 22-36/38 (2-)26
DODECYL 3,4,5-TRIHYDROXYBENZOATE 1166-52-5 Xi 43 (2-)24-37
DODEMORPH 1593-77-7 Xi 36/37/38 (2-)26
DODINE 2439-10-3 Xn 22-36/38 (2-)26
DRAZOXOLON 5707-69-7 T 25 (1/2-)22-24-36/37-45
EDIFENPHOS 17109-49-8 T 23/24/25 (1/2-)28-36/37-45
ENDOSULFAN 115-29-7 T,N 24/25-36-50/53 (1/2-)28-36/37-45-60-61
ENDOTHAL 145-73-3 T 21-25-36/37/38 (1/2-)36/37/39-45
ENDOTHAL-SODIUM 129-67-9 T 21-25-36/37/38 (1/2-)36/37/39-45
ENDOTHION 2778-04-3 T 24/25 (1/2-)36/37-45
ENDRIN 72-20-8 T+,N 24-28-50/53 (1/2-)22-36/37-45-60-61
EPHEDRINE 299-42-3 Xn 22 (2-)22-25
EPHEDRINE, SALTS Xn 22 (2-)22-25 Note A
EPICHLOROHYDRIN 106-89-8 T 45-10-23/24/25-34-43 53-45 Note E
EPN 2104-64-5 T+,N 27/28-50/53 (1/2-)22-36/37-45-60-61
(EPOXYETHYL)BENZENE 96-09-03 T 45-21-36 53-45 Note E
1,2-EPOXY-4-EPOXYETHYLCYCLOHEXANE 106-87-6 T 23/24/25-40 (1/2-)23-24-45
2,3-EPOXY-1,4,5,6,7,8,8-HEPTACHLORO- 1024-57-3 T,N 25-33-40-50/53 (1/2-)36/37-45-60-61
3a,4,7,7a-TETRAHYDRO-4,7-METHANOINDANE
1,2-EPOXY-3-PHENOXYPROPANE 122-60-1 Xn 21-43 (2-)24/25
1,2-EPOXYPROPANE 75-56-9 F+,T 45-12-20/21/22-36/37/38 53-45 Note E
2,3-EPOXY-1-PROPANOL 556-52-5 T 21/22-23-36/37/38-42/43 (1/2-)45
2,3-EPOXYPROPYL ACRYLATE 106-90-1 T 23/24/25-34-43 (1/2-)26-36/37/39-45 Note D
2,3-EPOXYPROPYL-2-ETHYLCYCLOHEXYL ETHER 130014-35-6 Xi 36/38-43 (2-)26-28-37/39
2,3-EPOXYPROPYL METHACRYLATE 106-91-2 Xn 20/21/22-36/38-43 (2-)26-28 Note D
EPOXYRESIN, reaction product: 25068-38-6 Xi 36/38-43 (2-)28-37/39
BISPHENOL-A(EPICHLOROHYDRIN), average
molecule weight <700
1,2-EPOXY-3-(TOLYLOXY)PROPANE 26447-14-3 Xi 38 (2-)26-28 Note C
EPTC 759-94-4 Xn 22 (2-)23
ERBON 136-25-4 Xn 22 (2)
ERIONITE 12510-42-8 T 45 53-45
ESERIN 57-47-6 T+ 26/28 (1/2-)25-45
ETHANAL 75-07-0 F+,Xn 12-36/37-40 (2-)16-33-36/37
ETHANE 74-84-0 F+ 12 (2-)9-16-33
ETHANEDIOL 107-21-1 Xn 22 (2)
ETHANE-1,2-DIONE 107-22-2 Xi 36/38 (2-)26-28 Note B
ETHANETHIOL 75-08-1 F,Xn 11-20 (2-)16-25
Page No. 18
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Substance CAS number Symbol Risk-phrases Safety phrases
ETHANOL 64-17-5 F 11 (2-)7-16
ETHANOLAMINE 141-43-5 Xn 20-36/37/38 (2)
ETHIOFENCARB 29973-13-5 Xn 22 (2)
ETHION 563-12-2 T 21-25 (1/2-)25-36/37-45
ETHIRIMOL 23947-60-6 Xn 21 (2-)36/37
ETHOATE-METHYL 116-01-8 Xn 21/22 (2-)36/37
ETHOPROPHOS 13194-48-4 T+ 25-27 (1/2-)36/37/39-45
ETHOXIDES, ALKALI F,C 11-14-34 (1/2-)8-16-26-43-45 Note A
2-ETHOXYANILINE 94-70-2 T 23/24/25-33 (1/2-)28-36/37-45 Note C
4-ETHOXYANILINE 156-43-4 T 23/24/25-33 (1/2-)28-36/37-45 Note C
N-ETHOXYCARBONYL-N-METHYLCARBAMOYLMETHYL 2595-54-2 T,N 24/25-50/53 (1/2-)36/37-45-60-61
O,O-DIETHYL PHOSPHORODITHIOATE
6-ETHOXY-1,2-DIHYDRO-2,2,4-TRIMETHYLQUINOLINE 91-53-2 Xn 22 (2-)24
2-ETHOXYETHANOL 110-80-5 T 60-61-10-20/21/22 53-45 Note E
2-ETHOXYETHYL ACETATE 111-15-9 T 60-61-20/21/22 53-45 Note E
ETHOXYQUIN 91-53-2 Xn 22 (2-)24
ETHYL ACETATE 141-78-6 F 11 (2-)16-23-29-33
ETHYL ACRYLATE 140-88-5 F,Xn 11-20/21/22-36/37/38-43 (2-)9-16-33-36/37 Note D
ETHYL ALCOHOL 64-17-5 F 11 (2-)7-16
ETHYLAMINE 75-04-7 F+,Xi 12-36/37 (2-)16-26-29
2-ETHYLAMINO-4-ISOPROPYLAMINO-6-METHYLTHIO- 834-12-8 Xn 22 (2-)36
1,3,5-TRIAZINE
N-ETHYLANILINE 103-69-5 T 23/24/25-33 (1/2-)28-37-45
ETHYLBENZENE 100-41-4 F,Xn 11-20 (2-)16-24/25-29
ETHYL BROMIDE 74-96-4 Xn 20/21/22 (2-)28
ETHYL BROMOACETATE 105-36-2 T+ 26/27/28 (1/2-)7/9-26-45
2-ETHYLBUTAN-1-OL 97-95-0 Xn 21/22 (2)
2-ETHYL BUTANOL 97-95-0 Xn 21/22 (2)
ETHYL CARBAMATE 51-79-6 T 45 53-45
S-(N-ETHYLCARBAMOYLMETHYL) O,O-DIMETHYL 116-01-8 Xn 21/22 (2-)36/37
PHOSPHORODITHIOATE
ETHYL CHLORIDE 75-00-3 F+,Xn 12-40-52/53 (2-)9-16-33-36/37-61
ETHYL CHLOROACETATE 105-39-5 T,N 23/24/25-50 (1/2-)7/9-45-61
ETHYL CHLOROFORMATE 541-41-3 F,T+ 11-22-26-34 (1/2-)9-16-26-28-33-36/37/39-45
ETHYL CYCLOHEXYL GLYCIDYL ETHER 130014-35-6 Xi 36/38-43 (2-)26-28-37/39
ETHYL 5-(1,2,3,5,6,7,8,9,10,10-DECACHLORO- 4234-79-1 T 22-24 (1/2-)36/37-45
-4-HYDROXYPENTACYCLO[5.2.1.02,6.03,9.05,8]
DEC-4-YL)OXOVALERATE
ETHYL 2-(DIMETHOXYPHOSPHINOTHIOYLTHIO)-2- 2597-03-7 Xn 21/22 (2-)22-36/37
PHENYLACETATE
ETHYLDIMETHYLAMINE 598-56-1 F+,C 12-20/22-34 (1/2-)3-16-26-36-45
ETHYL trans-3-DIMETHYLAMINOACRYLATE 924-99-2 Xi 43 (2-)24-37
S-ETHYL DIPROPYLTHIOCARBAMATE 759-94-4 Xn 22 (2-)23
ETHYLENE 74-85-1 F+ 12 (2-)9-16-33
ETHYLENE BIS(TRICHLOROACETATE) 2514-53-6 Xi 38 (2)
ETHYLENE CHLOROHYDRIN 107-07-3 T+ 26/27/28 (1/2-)7/9-28-45
ETHYLENEDIAMINE 107-15-3 C 10-21/22-34-42/43 (1/2-)23-26-36/37/39-45
ETHYLENE DIAMMONIUM O,O-BIS(OCTYL) C,N 22-34-50/53 (1/2-)24/25-26-28-39-45-60-61
PHOSPHORODITHIOATE, mixture of isomers
ETHYLENE DIBROMIDE 106-93-4 T,N 45-23/24/25-36/37/38- 53-45-61 Note E
51/53
ETHYLENE DICHLORIDE 107-06-2 F,T 45-11-22-36/37/38 53-45 Note E
ETHYLENE DIMETHACRYLATE 97-90-5 Xi 36/37 (2) Note D
ETHYLENE DINITRATE 628-96-6 E,T+ 2-26/27/28-33 (1/2-)33-35-36/37-45
2,2'-(ETHYLENEDIOXY)DIETHYL DIACRYLATE 1680-21-3 Xi 36/38-43 (2-)26-28 Note D
ETHYLENE GLYCOL 107-21-1 Xn 22 (2)
ETHYLENE GLYCOL DIMETHACRYLATE 97-90-5 Xi 36/37 (2) Note D
ETHYLENE GLYCOL DIMETHYL ETHER 110-71-4 Xn 10-19-20 (2-)24/25
ETHYLENE GLYCOL DINITRATE 628-96-6 E,T+ 2-26/27/28-33 (1/2-)33-35-36/37-45
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 Xn 20/21/22-37 (2-)24/25
ETHYLENE GLYCOL MONOETHYL ETHER 110-80-5 T 60-61-10-20/21/22 53-45 Note E
ETHYLENE GLYCOL MONOISOPROPYL ETHER 109-59-1 Xn 20/21-36 (2-)24/25
ETHYLENE GLYCOL MONOMETHYL ETHER 109-86-4 T 60-61-10-20/21/22 53-45 Note E
Page No. 19
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Substance CAS number Symbol Risk-phrases Safety phrases
2-ETHYLHEXYL 3,5-BIS(1,1-DIMETHYLETHYL)- 80387-97-9 T 61-43 53-45
4-HYDROXYPHENYL METHYL THIOACETATE
ETHYLENEIMINE 151-56-4 F,T+,N 45-46-11-26/27/28-34- 53-45-61 Note D, E
51/53
ETHYLENE OXIDE 75-21-8 F+,T 45-46-12-23-36/37/38 53-45 Note E
ETHYLENE THIOUREA 96-45-7 T 61-22 53-45 Note E
ETHYL FORMATE 109-94-4 F 11 (2-)9-16-33
ETHYL GLYCOL 110-80-5 T 60-61-10-20/21/22 53-45 Note E
ETHYLGLYCOL ACETATE 111-15-9 T 60-61-20/21/22 53-45 Note E
2-ETHYLHEXANE-1,3-DIOL 94-96-2 Xi 36 (2-)26
2-ETHYLHEXANOIC ACID 149-57-5 Xn 63 (2-)36/37
2-ETHYLHEXYL ACRYLATE 103-11-7 Xi 37/38-43 (2-)24-37 Note D
O-ETHYLHYDROXYLAMINE 624-86-2 F,T,N 11-23/24/25-36-43- (1/2-)16-26-36/37/39-38-
48/20-50 45-61
ETHYLIDENE DICHLORIDE 75-34-3 F,Xn 11-22-36/37-52/53 (2-)16-23-61
ETHYL LACTATE 97-64-3 - 10 (2-)23
ETHYL MERCAPTAN 75-08-1 F,Xn 11-20 (2-)16-25
ETHYL METHACRYLATE 97-63-2 F,Xi 11-36/37/38-43 (2-)9-16-29-33 Note D
ETHYL METHYL ETHER 540-67-0 F+ 12 (2-)9-16-33
ETHYL METHYL KETONE 78-93-3 F,Xi 11-36/37 (2-)9-16-25-33
ETHYL METHYL KETOXIME 96-29-7 Xi 36-43 (2-)23-24
ETHYL NITRATE 625-58-1 E 2 (2-)23-24/25
ETHYL NITRITE 109-95-5 E,Xn 2-20/21/22 (2)
O-ETHYL-O-4-NITROPHENYL 2104-64-5 T+,N 27/28-50/53 (1/2-)22-36/37-45-60-61
PHENYLPHOSPHONOTHIOATE
(ETHYL-3-OXOBUTANOATO-O'1,O'3)(2-DIMETHYL- Xi 10-41 (2-)26-39
AMINOETHANOLATO)(1-METHOXYPROPAN-2-
OLATO)ALUMINIUM(III), dimerised
O-ETHYL PHENYL ETHYLPHOSPHONODITHIOATE 944-22-9 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
ETHYL PROPIONATE 105-37-3 F 11 (2-)16-23-29-33
ETHYL SILICATE 78-10-4 Xn 10-20-36/37 (2)
S-[2-(ETHYLSULPHINYL)ETHYL]-O,O-DIMETHYL 2703-37-9 T+ 26/27/28 (1/2-)13-28-45
PHOSPHORODITHIOATE
S-[2-(ETHYLSULPHINYL)ETHYL]-O,O-DIMETHYL 301-12-2 T,N 24/25-50 (1/2-)23-36/37-45-61
PHOSPHOROTHIOATE
S-ETHYLSULPHINYLMETHYL 5827-05-4 T+ 25-27 (1/2-)28-36/37-45
O,O-DIISOPROPYLPHOSPHORODITHIOATE
S-[2-(ETHYLSULPHONYL)ETHYL]-O,O-DIMETHYL 17040-19-6 T 21-25 (1/2-)22-28-36/37-45
PHOSPHOROTHIOATE
O-[2-(ETHYLTHIO)ETHYL] O,O-DIMETHYL 867-27-6 T 25 (1/2-)24-36/37-45
PHOSPHOROTHIOATE
S-2-(ETHYLTHIO)ETHYL-O,O-DIMETHYL 640-15-3 T 21-25 (1/2-)36/37-45
PHOSPHORDITHIOATE
S-2-(ETHYLTHIO)ETHYL-O,O-DIMETHYL 919-86-8 T,N 24/25-51/53 (1/2-)28-36/37-45-61
PHOSPHOROTHIOATE
O-ETHYL-O-2,4,5-TRICHLOROPHENYL 327-98-0 T+,N 24-28-50/53 (1/2-)23-28-36/37-45-60-61
ETHYLPHOSPHONOTHIOATE
ETHYNE 74-86-2 F+ 5-6-12 (2-)9-16-33
ETRIMFOS 38260-54-7 Xn 22 (2)
FAST GARNET GBC BASE 97-56-3 T 45-43 53-45
FATTY ACIDS, TALL-OIL, reaction products Xi, N 38-51/53 (2-)28-37-61
with IMINOETHANOL and BORIC ACID
FENAMINOSULF 140-56-7 T 21-25 (1/2-)36/37-45
FENAMIPHOS 22224-92-6 T+ 24-28 (1/2-)23-28-36/37-45
FENAZAFLOR 14255-88-0 Xn 21/22 (2-)36/37
FENBUTATIN OXIDE 13356-0806 Xn 21-36/38 (2-)36/37
FENCHLORPHOS 299-84-3 Xn 21/22 (2-)25-36/37
FENITROTHION 122-14-5 Xn,N 22-50/53 (2-)60-61
FENOPROP 93-72-1 Xn 22-38 (2-)37
FENOPROP, SALTS Xn 20/21/22 (2-)13 Note A
FENSON 80-38-6 Xn 22-36 (2-)24-26
FENSULFOTHION 115-90-2 T+,N 27/28-50/53 (1/2-)23-28-36/37-45-60-61
FENTHION 55-38-9 T,N 21-25-50/53 (1/2-)36/37-45-60-61
Page No. 20
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Substance CAS number Symbol Risk-phrases Safety phrases
FENTIN ACETATE 900-95-8 T+,N 24/25-26-36/38-43-50/53 (1/2-)36/37-45-60-61
FENTIN HYDROXIDE 76-87-9 T+,N 24/25-26-36/38-50/53 (1/2-)36/37-45-60-61
FENURON-TCA 4482-55-7 Xi 38 (2)
FERBAM 14484-64-1 Xi 36/37/38 (2)
FICIN 9001-33-6 Xn 36/37/38-42 (2-)22-24-26-36/37
FLUENETIL 4301-50-2 T+ 27/28 (1/2-)28-36/37-45
FLUORINE 7782-41-4 T+,C 7-26-35 (1/2-)9-26-36/37/39-45
2-FLUOROACETAMIDE 640-19-7 T+ 24-28 (1/2-)36/37-45
FLUOROACETATES, soluble T+ 28 (1/2-)20-22-26-45 Note A
FLUOROACETIC ACID 144-49-0 T+ 28 (1/2-)20-22-26-45
FLUOROBORIC ACID, conc.>25% 16872-11-0 C 34 (1/2-)26-27-45 Note B
N-(FLUORODICHLOROMETHYLTHIO)PHTHALIMIDE 719-96-0 Xi 38 (2-)28
2-FLUOROETHYL BIPHENYL-4-YLACETATE 4301-50-2 T+ 27/28 (1/2-)28-36/37-45
FLUOROSILICATES, with the exception of those Xn 22 (2-)13-24/25 Note A
specified elsewhere in this Annex
FLUOROSILICATES, ALKALINE (Na, K, NH4) T 23/24/25 (1/2-)26-45 Note A
FLUOROSILICIC ACID 16961-83-4 C 34 (1/2-)26-27-45 Note B
FLUOROSULPHONIC ACID 7789-21-1 C 20-35 (1/2-)26-45
FLUOROSULPHURIC ACID 7789-21-1 C 20-35 (1/2-)26-45
2-FLUORO-5-TRIFLUOROMETHYLPYRIDINE 69045-82-5 Xi 10-43-52/53 (2-)24-37-61
FOLPET 133-07-3 Xn 36-40-43 (2-)36/37
FONOFOS 944-22-9 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
FORMALDEHYDE, reaction products with 91673-30-2 Xi 43 (2-)24-37
BUTYLPHENOL
FORMALDEHYDE solution, 1%£conc.<5% 50-00-0 Xn 40-43 (1/2-)23-37 Note B, D
FORMALDEHYDE solution, 5%£conc.<25% 50-00-0 Xn 20/21/22-36/37/38-40-43 (1/2-)26-36/37-51 Note B, D
FORMALDEHYDE solution, conc.>25% 50-00-0 T 23/24/25-34-40-43 (1/2-)26-36/37/39-45-51
Note B, D
FORMETANATE 22259-30-9 T+ 28 (1/2-)22-36/37-45
FORMETANATE HYDROCHLORIDE 23422-53-9 T+ 28 (1/2-)22-36/37-45
FORMIC ACID, conc.>90% 64-18-6 C 35 (1/2-)23-26-45 Note B
FORMIC ACID, 10%40% C 34-37 (1/2-)7/9-26-45 Note B
HYDROCARBONS T 45 53-45
C26-C55 aromatic rich 97722-04-8
HYDROCHLORIC ACID, 10%£conc.<25% Xi 36/37/38 (1/2-)26 Note B
HYDROCHLORIC ACID, conc.³25% C 34-37 (1/2-)26-45 Note B
HYDROCYANIC ACID 74-90-8 F+,T+ 12-26 (1/2-)7/9-16-36/37-38-45
HYDROFLUORIC ACID 7664-39-3 T+,C 26/27/28-35 (1/2-)7/9-26-36/37-45 Note B
Page No. 22
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Substance CAS number Symbol Risk-phrases Safety phrases
HYDROGEN 1333-74-0 F+ 12 (2-)9-16-33
HYDROGEN BROMIDE 10035-10-6 C 35-37 (1/2-)7/9-26-45
HYDROGEN CHLORIDE, water solution C 34-37 (1/2-)26-45 Note B
HYDROGEN CHLORIDE, anhydrous 7647-01-0 T,C 23-35 (1/2-)9-26-36/37/39-45
HYDROGEN CYANIDE 74-90-8 F+,T+ 12-26 (1/2-)7/9-16-36/37-38-45
HYDROGEN CYANIDE, SALTS with the exception of T+ 26/27/28-32 (1/2-)7-28-29-45 Note A
complex cyanides as FERRO-, FERRICYANIDES,
MERCURIC OXOCYANIDE
HYDROGEN FLUORIDE 32057-09-3 T+,C 26/27/28-35 (1/2-)7/9-26-36/37/39-45
HYDROGEN IODIDE anhydrous 10034-85-2 C 35 (1/2-)9-26-36/37/39-45
HYDROGEN PEROXIDE, conc.³20% 7722-84-1 O,C 8-34 (1/2-)3-28-36/39-45 Note B
HYDROGEN PEROXIDE, 5%£conc.<20% Xi 36/38 (2-)28-39 Note B
HYDROGEN SODIUM N-CARBOXYLATOETHYL- Xi 43-52/53 (2-)24-37-61
N-OCTADEC-9-ENYLMALEATE
HYDROGEN SULPHIDE 7783-06-4 F+,T+,N 12-26-50 (1/2-)9-16-28-36/37-45-61
HYDROIODIC ACID, conc.>25% C 34 (1/2-)26-45 Note B
HYDROQUINONE 123-31-9 Xn 20/22 (2-)24/25-39
4-HYDROXY-3,5-DI-IODOBENZONITRILE 1689-83-4 T 21-25-63 (1/2-)36/37-45
2-HYDROXYETHYL ACRYLATE 818-61-1 T 24-34-43 (1/2-)26-36/39-45 Note D
2-HYDROXYETHYL METHACRYLATE 868-77-9 Xi 36/38-43 (2-)26-28 Note D
2-HYDROXYETHYL OCTYL SULPHIDE 3547-33-9 Xi 41 (2-)26
HYDROXYLAMINE 7803-49-8 Xn,C 5-22-37/38-41-43- (2-)22-26-36/37/39-61
48/22-50
HYDROXYLAMINE HYDROCHLORIDE 5470-11-1 Xn,N 22-36/38-43-48/22-50 (2-)22-24-37-61
HYDROXYLAMINE SULPHATE (1:1) 10046-00-1 Xn,N 22-36/38-43-48/22-50 (2-)22-24-37-61
HYDROXYLAMINE SULPHATE (2:1) 10039-54-0 Xn,N 22-36/38-43-48/22-50 (2-)22-24-37-61
HYDROXYLAMMONIUM CHLORIDE 5470-11-1 Xn,N 22-36/38-43-48/22-50 (2-)22-24-37-61
HYDROXYLAMMONIUM HYDROGENSULPHATE 10046-00-1 Xn,N 22-36/38-43-48/22-50 (2-)22-24-37-61
4-HYDROXY-4-METHYLPENTAN-2-ONE 123-42-2 F,Xi 11-36 (2-)7-16-24/25
4-HYDROXY-3-[3-OXO-1-(4-CHLOROPHENYL)BUTYL] 81-82-3 Xn 48/22 (2-)37
COUMARIN
4-HYDROXY-3-[3-OXO-1-(2-FURYL)BUTYL]COUMARIN 117-52-2 T 25-48/25 (1/2-)37-45
4-HYDROXY-3-(3-OXO-1-PHENYLBUTYL)COUMARIN 81-81-2 T 61-48/25 53-45 Note E
HYDROXYPROPYL ACRYLATE, mixture of isomers 25584-83-2 T 23/24/25-34-43 (1/2-)26-36/37/39-45 Note C, D
HYDROXYPROPYL METHACRYLATE, mixture of 923-26-2 Xi 36/38 (2-)26-28 Note D
isomers 2761-09-3
5-(I-HYDROXY-I-2-PYRIDYLBENZYL)-7- 991-42-4 Xn 22 (2)
(I-2-PYRIDYLBENZYLIDENE)BICYCLO [2.2.1]
HEPT-5-ENE-2,3-DICARBOXIMIDE
4-HYDROXY-3-(1,2,3,4-TETRAHYDRO-1-NAPHTHYL) 5836-29-3 T+ 27/28-48/24/25 (1/2-)36/37-45
COUMARIN
HYOSCINE 51-34-3 T+ 26/27/28 (1/2-)25-45
HYOSCINE, SALTS T+ 26/27/28 (1/2-)25-45 Note A
HYOSCYAMINE 101-31-5 T+ 26/28 (1/2-)24-45
HYOSCYAMINE, SALTS T+ 26/28 (1/2-)24-45 Note A
IMAZALIL 35554-44-0 Xn 22-36 (2)
IMAZALIL SULPHATE 58594-72-2 Xn 22-41 (2-)26
IMIDAZOLIDINE-2-THIONE 96-45-7 T 61-22 53-45 Note E
2-IMIDAZOLINE-2-THIOL 96-45-7 T 61-22 53-45 Note E
2,2'-IMINODIETHANOL 111-42-2 Xi 36/38 (2-)26
2,2'-IMINODIETHYLAMINE 111-40-0 C 21/22-34-43 (1/2-)26-36/37/39-45
1,1'-IMINODIPROPAN-2-OL 110-97-4 Xi 36 (2-)26
3,3'-IMINODI(PROPYLAMINE) 56-18-8 T+,C 22-24-26-35-43 (1/2-)26-28-36/37/39-45
IODINE 7553-56-2 Xn 20/21 (2-)23-25
IODOACETIC ACID 64-69-7 T,C 25-35 (1/2-)22-36/37/39-45
IODOMETHANE 74-88-4 T 21-23/25-37/38-40 (1/2-)36/37-38-45
IODOXYBENZENE 696-33-3 E 1 (2-)35
3-IODPROPENE 556-56-9 C 10-34 (1/2-)7-26-45
IOXYNIL 1689-83-4 T 21-25-63 (1/2-)36/37-45
IOXYNIL OCTANOATE 3861-47-0 Xn 22-63 (2-)36/37
IPROBENFOS 26087-47-8 Xn 22 (2)
ISOBENZAN 297-78-9 T+,N 27/28-50 (1/2-)28-36/37-45-61
ISOBORNYL THIOCYANOACETATE 115-31-1 Xn 22 (2-)24/25
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Substance CAS number Symbol Risk-phrases Safety phrases
ISOBUTYL ACRYLATE 106-63-8 Xn 10-20/21-38-43 (2-)9-24-37 Note D
ISOBUTYL 2-(4-(4-CHLOROPHENOXY) 51337-71-4 Xn 22 (2)
PHENOXY)PROPIONATE
ISOBUTYL 3,4-EPOXYBUTYRATE 100181-71-3 Xi,N 38-43-50/53 (2-)24-28-36/37-60-61
4,4'-ISOBUTYLETHYLIDENEDIPHENOL 6807-17-6 Xi,N 36-50/53 (2-)26-60-61
ISOBUTYLISOPROPYLDIMETHOXYSILANE 111439-76-0 Xn 10-20-38 (2-)25-26-36/37
ISOBUTYL METHACRYLATE 97-86-9 Xi 10-36/37/38-43 (2-)24-37 Note D
ISOBUTYRIC ACID 79-31-2 Xn 21/22 (2)
ISOBUTYRYL CHLORIDE 79-30-1 F,C 11-35 (1/2-)16-23-26-36-45
3-ISOCYANATOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYL- 4098-71-9 T 23-36/37/38-42/43 (1/2-)26-28-38-45
ISOCYANATE
4-ISOCYANATOSULPHONYLTOLUENE 4083-64-1 Xn 14-36/37/38-42 (2-)26-28-30
ISODRIN 465-73-6 T+,N 26/27/28-50/53 (1/2-)13-28-45-60-61
ISOFENPHOS 25311-71-1 T 24/25 (1/2-)36/37-45
ISOLAN 119-38-0 T+ 27/28 (1/2-)28-36/37/39-45
ISOPENTANE 78-78-4 F 11 (2-)9-16-29-33 Note C
ISOPHORONE 78-59-1 Xi 36/37/38 (2-)26
ISOPHORONE DIAMINE 2855-13-2 C 21/22-34-43-52/53 (1/2-)26-36/37/39-45-61
ISOPHORONE DI-ISOCYANATE 4098-71-9 T 23-36/37/38-42/43 (1/2-)26-28-38-45
ISOPRENE 78-79-5 F+ 12 (2-)9-16-29-33 Note D
ISOPROCARB 2631-40-5 Xn 22 (2)
ISOPROPANOLAMINE 78-96-6 C 34 (1/2-)23-26-36-45
ISOPROPENYL BENZENE 98-83-9 Xi 10-36/37 (2)
2-ISOPROPOXYETHANOL 109-59-1 Xn 20/21-36 (2-)24/25
2-ISOPROPOXYPHENYL METHYLCARBAMATE 114-26-1 T 25 (1/2-)37-45
ISOPROPYL ACETATE 108-21-4 F 11 (2-)16-23-29-33 Note C
ISOPROPYL ALCOHOL 67-63-0 F 11 (2-)7-16 Note C
ISOPROPYLAMINE 75-31-0 F+,Xi 12-36/37/38 (2-)16-26-29
6-ISOPROPYLAMINO-2-METHYLAMINO-4-METHYLTHIO- 1014-69-3 Xn 21/22 (2-)36/37
1,3,5-TRIAZINE
ISOPROPYLBENZENE 98-82-8 Xi 10-37 (2) Note C
3-ISOPROPYL-2,1,3-BENZOTHIADIAZIN-4-ONE- 25057-89-0 Xn 22-36 (2-)26
2,2-DIOXIDE
ISOPROPYL CHLOROACETATE 105-48-6 T 10-25-36/37/38 (1/2-)26-37/39-45
ISOPROPYL FORMATE 625-55-8 F 11 (2-)9-16-33 Note C
4,4'-ISOPROPYLIDENEDIPHENOL 80-05-7 Xi 36/37/38-43 (2-)24-26-37
exo-4-ISOPROPYL-1-METHYL-1,4- 87172-89-2 O,Xn 8-22-36 (2-)26
EPOXYCYCLOHEXAN-2-OL
5-ISOPROPYL-3-METHYLPHENYL METHYLCARBAMATE 2631-37-0 T 25 (1/2-)24-37-45
1-ISOPROPYL-3-METHYLPYRAZOL-5-YL 119-38-0 T+ 27/28 (1/2-)28-36/37/39-45
DIMETHYLCARBAMATE
S-[2-(ISOPROPYL SULPHINYL)-ETHYL] 2635-50-9 T 23/24/25 (1/2-)13-45
O,O-DIMETHYL PHOSPHOROTHIOATE
ISOPROTURON 34123-59-6 Xn 22-40 (2-)36/37
ISOTHIOATE 36614-38-7 T 24/25 (1/2-)28-36/37-45
ISOXATHION 18854-01-8 T 24/25 (1/2-)28-36/37-45
KELEVAN 4234-79-1 T 22-24 (1/2-)36/37-45
LEAD ACETATE 1335-32-6 T 61-62-33-40-48/22 53-45 Note E
LEAD ALKYLS T+,N 61-62-26/27/28-33-50/53 53-45-60-61 Note A, E
LEAD AZIDE 13424-46-9 E,T 61-62-3-20/22-33 53-45 Note E
LEAD CHROMATE 7758-97-6 T,N 61-62-33-40-50/53 53-45-60-61
LEAD COMPOUNDS with the exception of those T 61-62-20/22-33 53-45 Note A, E
specified elsewhere in this Annex
LEAD DIACETATE 301-04-2 T 61-62-33-48/22 53-45 Note E
LEAD HEXAFLUOROSILICATE 25808-74-6 T 61-62-20/22-33 53-45 Note E
LEAD(II) METHANESULPHONATE 17570-76-2 T,N 61-62-20/22-33-38- 53-45-57-61 Note E
41-48/20/22-58
LEADSTYPHNATE 15245-44-0 E,T 61-62-3-20/22-33 53-45 Note E
LEAD 2,4,6-TRINITRORESORCINOXIDE 15245-44-0 E,T 61-62-3-20/22-33 53-45 Note E
LEPTOPHOS 21609-90-5 T,N 21-25-39/25-50/53 (1/2-)25-36/37/39-45-60-61
LINDANE 58-89-9 T,N 23/24/25-36/38-50/53 (1/2-)13-45-60-61
LINURON 330-55-2 Xn 40 (2-)36/37
LITHIUM 7439-93-2 F,C 14/15-34 (1/2-)8-43-45
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Substance CAS number Symbol Risk-phrases Safety phrases
MAGNESIUM ALKYLS, C1-5 F,C 14-17-34 (1/2-)16-43-45 Note A
MAGNESIUM PHOSPHIDE 12057-74-8 F,T+ 15/29-28 (1/2-)22-43-45
MAGNESIUM POWDER, PYROPHORIC 7439-95-4 F 15-17 (2-)7/8-43
MAGNESIUM POWDER OR TURNINGS, stabilized 7439-95-4 F 11-15 (2-)7/8-43
MALATHION 121-75-5 Xn 22 (2-)24
MALEIC ACID 110-16-7 Xn 22-36/37/38 (2-)26-28-37
MALEIC ANHYDRIDE 108-31-6 Xn 22-36/37/38-42 (2-)22-28-39
MALONONITRILE 109-77-3 T 23/24/25 (1/2-)23-27-45
MANGANESE DIOXIDE 1313-13-9 Xn 20/22 (2-)25
MANGANESE SULPHATE 7785-87-7 Xn 48/20/22 (2-)22
MANNITOL HEXANITRATE 15825-0-4 E 3 (2-)35
MCPA 94-74-6 Xn 22-38-41 (2-)26-37-39
MCPA, SALTS and ESTERS Xn 20/21/22 (2-)13 Note A
MCPB 94-81-5 Xn 22 (2-)24/25
MCPB, SALTS and ESTERS Xn 22 (2-)24/25 Note A
MECARBAM 2595-54-2 T,N 24/25-50/53 (1/2-)36/37-45-60-61
MECOPROP 93-65-2 Xn 22-38-41 (2-)26-37/39
MECOPROP, SALTS Xn 20/21/22 (2-)13 Note A
MEDINOTERB ACETATE 2487-01-6 T 21-25 (1/2-)36/37-45
MENAZON 78-57-9 Xn 22-52/53 (2-)61
p-MENTHA-1,8,(9)-DIENE 138-86-3 Xi 10-38 (2-)28
p-MENTHANE HYDROPEROXIDE 80-47-7 O,C 7-20-34 (1/2-)3/7-14-36/37/39-45
8-p-MENTYL HYDROPEROXIDE 80-47-7 O,C 7-20-34 (1/2-)3/7-14-36/37/39-45
MEPHOSFOLAN 950-10-7 T+,N 27/28-51/53 (1/2-)36/37/39-45-61
MERCAPTODIMETUR 2032-65-7 T 25 (1/2-)22-37-45
MERCURIC CHLORIDE 7487-94-7 T+ 28-34-48/24/25 (1/2-)36/37/39-45
MERCURIC FULMINATE 628-86-4 E,T 3-23/24/25-33 (1/2-)3-35-45
MERCURIC OXYCYANIDE 1335-31-5 E,T 3-23/24/25-33 (1/2-)28-35-45
MERCURY 7439-97-6 T 23-33 (1/2-)7-45
MERCURY ALKYLS T+ 26/27/28-33 (1/2-)13-28-36-45 Note A
MERCURY DICHLORIDE 7487-94-7 T+ 28-34-48/24/25 (1/2-)36/37/39-45
MERCURY, INORGANIC COMPOUNDS with exception of T+ 26/27/28-33 (1/2-)13-28-45 Note A
MERCURIC SULPHIDE and those specified
elsewhere in this Annex
MERCURY, ORGANIC COMPOUNDS with exception of T+ 26/27/28-33 (1/2-)13-28-36-45 Note A
those specified elsewhere in this Annex
MESITYLENE 108-67-8 Xi 10-37 (2)
MESITYL OXIDE 141-79-7 Xn 10-20/21/22 (2-)25
METALDEHYDE 108-62-3 Xn 10-22 (2-)13-25-46
METANILIC ACID 121-47-1 Xn 20/21/22 (2-)25-28
METHACRYLATES with the exception of those Xi 36/37/38 (2-)26-28
specified elsewhere in this Annex, conc.³10%
METHACRYLIC ACID 79-41-4 C 34 (1/2-)15-26-45 Note D
METHACRYLONITRILE 126-98-7 F,T 11-23/24/25-43 (1/2-)9-16-18-29-45 Note D
METHALLYL CHLORIDE 563-47-3 F,C,N 11-20/22-34-43-51/53 (2-)9-16-26-29-36/37/39-45-61
METHAMIDOPHOS 10265-92-6 T+,N 24-28-36-50 (1/2-)22-28-36/37-45-61
METHANE 74-82-8 F+ 12 (2-)9-16-33
METHANESULPHONIC ACID 75-75-2 C 34 (1/2-)26-36-45
METHANETHIOL 74-93-1 F+,Xn 12-20 (2-)16-25
METHANOL 67-56-1 F,T 11-23/25 (1/2-)7-16-24-45
METHAZOLE 20354-26-1 Xn 21/22-36/38 (2-)36/37
METHENAMINE 100-97-0 F,Xn 11-42/43 (2-)16-22-24-37
METHIDATHION 950-37-8 T+,N 21-28-50/53 (1/2-)22-28-36/37-45-60-61
METHIOCARB 2032-65-7 T 25 (1/2-)22-37-45
METHOMYL 16752-77-5 T+ 28 (1/2-)22-36/37-45
METHOXIDES, ALKALI F,C 11-14-34 (1/2-)8-16-26-43-45 Note A
2-METHOXYANILINE 90-04-0 T+,N 45-26/27/28-33-51/53 53-45-61 Note E
4-METHOXYANILINE 104-94-9 T+,N 26/27/28-33-50 (1/2-)28-36/37-45-61
3-METHOXYBUTYL ACETATE 4435-53-4 Xi 36 (2-)25
2-METHOXYCARBONYL-1-METHYLVINYL DIMETHYL 7786-34-7 T+ 27/28 (1/2-)23-28-36/37-45
PHOSPHATE
2-METHOXYETHANOL 109-86-4 T 60-61-10-20/21/22 53-45 Note E
2-METHOXYETHYL ACETATE 110-49-6 T 60-61-20/21/22 53-45 Note E
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Substance CAS number Symbol Risk-phrases Safety phrases
2-METHOXYETHYLCARBAMOYLMETHYL 919-76-6 Xn 22 (2-)24-36
O,O-DIMETHYL PHOSPHORODITHIOATE
2-METHOXYETHYLMERCURY CHLORIDE 123-88-6 T 25-34-48/25 (1/2-)36/37/39-45
2-METHOXY-1-METHYLETHYL ACETATE 108-65-6 Xi 10-36 (2-)25
4-METHOXY-4-METHYLPENTAN-2-ONE 107-70-0 - 10 (2-)23
4-METHOXY-2-NITROANILINE 96-96-8 T+ 26/27/28-33-52/53 (1/2-)28-36/37-45-61
1-METHOXY-2-PROPANOL 107-98-2 - 10 (2-)24
S-(5-METHOXY-4-OXOPYRAN-2-YLMETHYL) DIMETHYL 2778-04-3 T 24/25 (1/2-)36/37-45
PHOSPHOROTHIOATE
METHYL ACETATE 79-20-9 F 11 (2-)16-23-29-33
METHYL ACETOACETATE 105-45-3 Xi 36 (2-)26
METHYL ACRYLAMIDOMETHOXYACETATE 77402-03-0 T 45-46-22-36 53-45 Note E
(containing ³0.1% ACRYLAMIDE)
METHYL ACRYLATE 96-33-3 F,Xn 11-20/22-36/37/38 (2-)9-16-33 Note D
METHYL ALCOHOL 67-56-1 F,T 11-23/25 (1/2-)7-16-24-45
METHYLAMINE, mono-, di-, tri F+,Xn 12-20-37/38-41 (2-)16-26-39
METHYLAMINE, mono-, solution 74-89-5 F+,C 12-20/22-34 (1/2-)3-16-26-29-36/37/39-45
Note B
METHYLAMINE, di-, solution 124-40-3 F+,C 12-20/22-34 (1/2-)3-16-26-29-36/37/39-45
Note B
METHYLAMINE, tri-, solution 75-50-3 F+,C 12-20/22-34 (1/2-)3-16-26-29-36/37/39-45
Note B
2-METHYLAMINOETHANOL 109-83-1 C 34 (1/2-)23-26-36-45
N-METHYL-2-AMINOETHANOL 109-83-1 C 34 (1/2-)23-26-36-45
N-METHYLANILINE 100-61-8 T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61
METHYLAZIRIDINE 75-55-8 F,T+ 45-11-26/27/28-41 53-45 Note E
METHYL-O,N,N-AZOXYMETHYL ACETATE 592-62-1 T 45-61 53-45
METHYL AZOXY METHYL ACETATE 592-62-1 T 45-61 53-45
DL-I-METHYLBENZYLAMINE 618-36-0 C 21/22-34 (1/2-)26-28-36/37/39-45
METHYL BROMIDE 74-83-9 T,N 23-36/37/38-50/53-59 (1/2-)15-27-36/37/39-38-
45-59-61
2-METHYLBUTA-1,3-DIENE 78-79-5 F+ 12 (2-)9-16-29-33 Note D
2-METHYLBUTAN-2-OL 75-85-4 F,Xn 11-20 (2-)9-16-24/25
3-METHYLBUTAN-2-ONE 563-80-4 F 11 (2-)9-16-33
2-(1-METHYLBUTYL)-4,6-DINITROPHENOL 4097-36-3 T 23/24/25 (1/2-)13-45
METHYL n-BUTYL KETONE 591-78-6 F,T 11-48/23 (1/2-)9-16-29-45-51
METHYLCARBOPHENOTHIONE 953-17-3 T 24/25 (1/2-)28-36/37-45
METHYL CHLORIDE 74-87-3 F+,Xn 12-40-48/20 (2-)9-16-33
METHYL CHLOROACETATE 96-34-4 T 10-23/25-37/38-41 (1/2-)26-37/39-45
METHYL 2-CHLORO-3-(4-CHLOROPHENYL) PROPIONATE 14437-17-3 Xn 21/22 (2-)36/37
METHYL CHLOROFORM 71-55-6 Xn,N 20-59 (2-)24/25-59-61 Note F
METHYL CHLOROFORMATE 79-22-1 F,T 11-23-36/37/38 (1/2-)9-16-33-45
METHYLCYCLOHEXANE 108-87-2 F 11 (2-)9-16-33
2-METHYLCYCLOHEXANOL 583-59-5 Xn 20 (2-)24/25
2-METHYLCYCLOHEXANONE 583-60-8 Xn 10-20 (2-)25
METHYL 3,4-DICHLOROPHENYLCARBANILATE 1918-18-9 Xn 22 (2)
N-METHYLDIETHANOLAMINE 105-59-9 Xi 36 (2-)24
METHYL I-((4,6-DIMETHOXYPYRIMIDIN-2-YL) 83055-99-6 Xi,N 43-51/53 (2-)24-37-61
UREIDOSULPHONYL)-o-TOLUATE
6-METHYL-1,3-DITHIOLO(4,5-b)QUINOXALIN-2-ONE 2439-01-2 Xi 36-43 (2-)24-37
4,4'-METHYLENEBIS(2-CHLOROANILINE) 101-14-4 T,N 45-22-50/53 53-45-60-61 Note E
4,4'-METHYLENEBIS(2-CHLOROANILINE), SALTS T,N 45-22-50/53 53-45-60-61 Note A, E
3,3'-METHYLENE BIS(4-HYDROXYCOUMARIN) 66-76-2 T 22-48/25 (1/2-)37-45
1,1'-[METHYLENEBIS(4,1-PHENYLENE)]DIPYRROLE- Xi,N 43-50/53 (2-)24-37-60-61
2,5-DIONE and 1-(4-(4-)5-OXO-2H-2-FURYLIDENEAMINO)BENZYL)
PHENYL)PYRROLE-2,5-DIONE
2,2'-METHYLENE BIS-(3,4,6-TRICHLOROPHENOL) 70-30-4 T,N 24/25-50/53 (1/2-)20-37-45-60-61
METHYLENE CHLORIDE 75-09-2 Xn 40 (2-)23-24/25-36/37
4,4'-METHYLENEDIANILINE 101-77-9 T,N 45-20/21/22-43- 53-45-61 Note E
48/20/21-51/53
METHYLENE DIBROMIDE 74-95-3 Xn 20-52/53 (2-)24-61
4,4'-METHYLENEDI(CYCLOHEXYL ISOCYANATE) 5124-30-1 T 23-36/37/38-42/43 (1/2-)26-28-38-45
METHYLENE DITHIOCYANATE 6317-18-6 Xi,N 43-50 (2-)24-37-61
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Substance CAS number Symbol Risk-phrases Safety phrases
4,4'-METHYLENEDI-o-TOLUIDINE 838-88-0 T,N 45-22-43-50/53 53-45-60-61 Note E
N-METHYL-2-ETHANOLAMINE 109-83-1 C 34 (1/2-)23-26-36-45
METHYL ETHYL KETONE 78-93-3 F,Xi 11-36/37 (2-)9-16-25-33
METHYL FORMATE 107-31-3 F+ 12 (2-)9-16-33
METHYLGLYCOL ACETATE 110-49-6 T 60-61-20/21/22 53-45 Note E
5-METHYLHEPTAN-3-ONE 541-85-5 Xi 10-36/37 (2-)23
5-METHYLHEXAN-2-ONE 110-12-3 - 10 (2-)23
1-METHYLIMIDAZOLE 616-47-7 C 21/22-34 (1/2-)26-36-45
2,2'-(METHYLIMINO)DIETHANOL 105-59-9 Xi 36 (2-)24
METHYL IODIDE 74-88-4 T 21-23/25-37/38-40 (1/2-)36/37-38-45
METHYL ISOAMYL KETONE 110-12-3 - 10 (2-)23
METHYL ISOBUTYL CARBINOL 108-11-2 Xi 10-37 (2-)24/25
METHYL ISOBUTYL KETONE 108-10-1 F 11 (2-)9-16-23-33
METHYL ISOCYANATE 624-83-9 F+,T 12-23/24/25-36/37/38 (1/2-)9-30-43-45
METHYL ISOPROPYL KETONE 563-80-4 F 11 (2-)9-16-33
METHYL ISOTHIOCYANATE 556-61-6 T 23/25-34-43 (1/2-)36/37-38-45
METHYL LACTATE 547-64-8 - 10 (2-)23
METHYL MERCAPTAN 74-93-1 F+,Xn 12-20 (2-)16-25
METHYL METHACRYLATE 80-62-6 F,Xi 11-36/37/38-43 (2-)9-16-29-33 Note D
exo-(+/-)-1-METHYL-2-(2-METHYLBENZYLOXY)- 89368-00-3 Xn,N 20-51/53 (2-)22-61
4-ISOPROPYL-7-OXABICYCLO(2.2.1)HEPTANE
2-METHYL-1-(4-METHYLTHIOPHENYL)- 71868-10-5 Xn,N 22-51/53 (2-)22-61
2-MORPHOLINOPROPAN-1-ONE
METHYL 2-(2-NITROBENZYLIDENE)ACETOACETATE 39562-27-1 Xi,N 43-51/53 (2-)24-37-61
METHYL 2-OCTYL-4,6-DINITROPHENYL CARBONATE 63919-26-6 Xn 22 (2)
and METHYL 4-OCTYL-2,6-DINITROPHENYL CARBONATE
1-METHYL-3-NITRO-1-NITROSOGUANIDINE 70-25-7 T,N 45-20-36/38-51/53 53-45-61 Note E
METHYLOXIRANE 75-56-9 F+,T 45-12-20/21/22-36/37/38 53-45 Note E
2-METHYLPENTANE-2,4-DIOL 107-41-5 Xi 36/38 (2)
4-METHYLPENTAN-2-OL 108-11-2 Xi 10-37 (2-)24/25
4-METHYLPENTAN-2-ONE 108-10-1 F 11 (2-)9-16-23-33
4-METHYLPENT-3-EN-2-ONE 141-79-7 Xn 10-20/21/22 (2-)25
3-(3-METHYLPENT-3-YL)ISOXAZOL-5-YLAMINE 82560-06-3 T 23/25-41-52/53 (1/2-)22-26-36/37/39-45-61
2-METHYL-1-PENTYLPYRIDINIUM BROMIDE Xn 21/22-52/53 (2-)36/37-61
METHYL PHENOL, all isomers T 24/25-34 (1/2-)36/37/39-45 Note C
2-METHYL-m-PHENYLENEDIAMINE 823-40-5 Xn,N 21/22-40-43-50/53 (2-)24-36/37-60-61
4-METHYL-m-PHENYLENEDIAMINE 95-80-7 T,N 45-21-25-36-43-50/53 53-45-60-61 Note E
2-METHYL-p-PHENYLENEDIAMINE 95-70-5 T,N 20/21-25-43-50/53 (1/2-)24-37-45-60-61
2-METHYL-p-PHENYLENEDIAMINE SULPHATE 615-50-9 T,N 20/21-25-43-50/53 (1/2-)24-37-45-60-61
4-METHYL-m-PHENYLENEDIAMINE SULPHATE 65321-67-7 T,N 45-21-25-36-43-50/53 53-45-60-61 Note E
S-(1-METHYL-1-PHENYLETHYL) PIPERIDINE-1- 61432-55-1 Xn,N 22-51/53 (2-)61
CARBOTHIOATE
2-METHYL-4-PHENYLPENTANOL 92585-24-5 Xi,N 43-51/53 (2-)24-37-61
2-METHYLPROPAN-2-OL 75-65-0 F,Xn 11-20 (2-)9-16
2-METHYL-2-PROPENE NITRILE 126-98-7 F,T 11-23/24/25-43 (1/2-)9-16-18-29-45 Note D
2-METHYLPROPENOIC ACID 79-41-4 C 34 (1/2-)15-26-45 Note D
METHYL PROPIONATE 554-12-1 F 11 (2-)16-23-29-33
2-METHYLPYRIDINE 109-06-8 Xn 10-20/21/22-36/37 (2-)26-36
4-METHYLPYRIDINE 108-89-4 T 10-20/22-24-36/37/38 (1/2-)26-36-45
N-METHYL-2-PYRROLIDONE 872-50-4 Xi 36/38 (2-)41
METHYL 3-SULPHAMOYL-2-THENOATE Xi 43 (2-)24-37
I-METHYLSTYRENE 98-83-9 Xi 10-36/37 (2)
o-METHYLSTYRENE 611-15-4 Xn 20 (2-)24
METHYL-2,3,5,6-TETRACHLORO-4-PYRIDYLSULPHONE 13108-52-6 Xn 21/22-36-43 (2-)26/28
2-METHYL-5-(1,1,3,3-TETRAMETHYLBUTYL) Xi,N 41-43-51/53 (2-)24/25-26-37-61
HYDROQUINONE
N-METHYL-N,2,4,6-TETRANITROANILINE 479-45-8 E,T 2-23/24/25-33 (1/2-)35-45
2-METHYL-2-METHYLTHIOPROPIONALDEHYDE 116-06-3 T+ 27/28 (1/2-)22-36/37-45
O-(METHYLCARBAMOYL)OXIME
4-METHYLTHIO-3,5-XYLYL METHYLCARBAMATE 2032-65-7 T 25 (1/2-)22-37-45
N-METHYL-m-TOLUIDINE 696-44-6 T 23/24/25-33-52/53 (1/2-)28-36/37-45-61 Note C
N-METHYL-o-TOLUIDINE 611-21-2 T 23/24/25-33-52/53 (1/2-)28-36/37-45-61 Note C
N-METHYL-p-TOLUIDINE 623-09-5 T 23/24/25-33-52/53 (1/2-)28-36/37-45-61 Note C
Page No. 27
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Substance CAS number Symbol Risk-phrases Safety phrases
5-METHYL-1,2,4-TRIAZOLO(3,4-b)BENZO- 41814-78-2 Xn 22 (2)
1,3-THIAZOLE
METHYLTRICHLOROSILANE 75-79-6 F,Xi 11-14-36/37/38 (2-)26-39
1-METHYLTRIMETHYLENE DIACRYLATE 19485-03-1 C 21-34-43 (1/2-)26-36/37/39-45 Note D
METHYL VINYL ETHER 107-25-5 F+ 12 (2-)9-16-33 Note D
METAM-SODIUM 137-42-8 Xn 21/22-31-41 (2-)26-36/37/39
METOLCARB 1129-41-5 Xn 22 (2)
METRIBUZIN 21087-64-9 Xn 22 (2)
MEVINPHOS 7786-34-7 T+ 27/28 (1/2-)23-28-36/37-45
MEXACARBATE 315-18-4 T+ 21-28 (1/2-)36/37-45
MIBK 108-10-1 F 11 (2-)9-16-23-33
MIPAFOX 371-86-8 T+ 39/26/27/28 (1/2-)13-45
MOLINATE 2212-67-1 Xn 22 (2-)24
MOLYBDEMUM TRIOXIDE 1313-27-5 Xn 36/37-48/20/22 (2-)22-25
MONOCHLOROANILINE T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61 Note C
MONOCHLOROBENZENE 108-90-7 Xn,N 10-20-51/53 (2-)24/25-61
MONOCROTOPHOS 6923-22-4 T+,N 24-28-50/53 (1/2-)23-36/37-45-60-61
MONOLINURON 1746-81-2 Xn 22 (2-)22
MONOMETILAN 2532-43-6 T 23/24/25 (1/2-)13-45
MONOPROPYLENE GLYCOL METHYL ETHER 107-98-2 - 10 (2-)24
MONURON 150-68-5 Xn 22-40 (2-)36/37
MORFAMQUAT Xn 22-36/37/38 (2-)22-36
MORFAMQUAT, SALTS Xn 22-36/37/38 (2-)22-36 Note A
MORPHOLINE 110-91-8 C 10-20/21/22-34 (1/2-)23-36-45
MORPHOLINE-4-CARBONYL CHLORIDE 15159-40-7 Xn 14-36/37-40 (2-)26-30-36-38
MORPHOTHION 144-41-2 T,N 23/24/25-50/53 (1/2-)13-45-60-61
NABAM 142-59-6 Xn 22-37-43 (2-)8-24/25-46
NALED 300-76-5 Xn 21/22-36/38 (2-)36/37
1-NAPHTHOL 90-15-3 Xn 21/22-37/38-41 (2-)22-26-37/39
2-NAPHTHOL 135-19-3 Xn 20/22 (2-)24/25
ß-NAPHTHOL 135-19-3 Xn 20/22 (2-)24/25
1-NAPHTHYLAMINE 134-32-7 Xn,N 22-51/53 (2-)24-61
2-NAPHTHYLAMINE 91-59-8 T,N 45-22-51/53 53-45-61 Note E
2-NAPHTHYLAMINE, SALTS T,N 45-22-51/53 53-45-61 Note A, E
I-NAPHTHYLAMINE 134-32-7 Xn,N 22-51/53 (2-)24-61
ß-NAPHTHYLAMINE 91-59-8 T,N 45-22-51/53 53-45-61 Note E
1,5-NAPHTYLENEDIAMINE 2243-62-1 Xn,N 40-50/53 (2-)36/37-60-61
1,5-NAPHTHYLENE DI-ISOCYANATE 3173-72-6 Xn 20-36/37/38-42 (2-)26-28-38-45
NAPHTHYLINDANDIONE 1786-03-4 T 25 (1/2-)13-45
2-(1-NAPHTHYL)-INDAN-1,3-DIONE 1786-03-4 T 25 (1/2-)13-45
1-NAPHTHYL-n-METHYLCARBAMATE 63-25-2 Xn 22 (2-)22-24
1-NAPHTHYLTHIOUREA 86-88-4 T+ 28-40 (1/2-)25-36/37-45
1-(1-NAPHTHYL)-2-THIOUREA 86-88-4 T+ 28-40 (1/2-)25-36/37-45
NEOPENTANE 463-82-1 F+ 12 (2-)9-16-33
NEOPENTYLGLYCOL DIACRYLATE 2223-82-7 T 24-36/38-43 (1/2-)28-39-45 Note D
NICKEL 7440-02-0 Xn 40-43 (2-)22-36
NICKEL CARBONATE 3333-67-3 Xn 22-40-43 (2-)22-36/37
NICKEL DIHYDROXIDE 12054-48-7 Xn 20/22-40-43 (2-)22-36
NICKEL DIOXIDE 12035-36-8 T 49-43 53-45
NICKEL MONOXIDE 1313-99-1 T 49-43 53-45
NICKEL SUBSULPHIDE 12035-72-2 T 49-43 53-45
NICKEL SULPHATE 7786-81-4 Xn 22-40-42/43 (2-)22-36/37
NICKEL SULPHIDE 16812-54-7 T 49-43 53-45
NICKEL TETRACARBONYL 13463-39-3 F,T+ 61-11-26-40 53-45 Note E
NICOTINE 54-11-5 T+ 25-27 (1/2-)36/37-45
NICOTINE, SALTS T+ 26/27/28 (1/2-)13-28-45 Note A
NITRAPYRIN 1929-82-4 Xn 22 (2-)24
NITRIC ACID, conc.>20% 7697-37-2 O,C 8-35 (1/2-)23-26-36-45 Note B
NITRIC ACID, 5%£conc.<20% C 35 (1/2-)23-26-27 Note B
NITRIC ACID and SULPHURIC ACID, 51602-38-1 O,C 8-35 (1/2-)23-26-30-36-45 Note B
mixture NITRIC ACID conc.>30%
1,1',1"-NITRILOTRIPROPAN-2-OL 122-20-3 Xi 36 (2-)26
5-NITROACENAPHTHENE 602-87-9 T 45 53-45
Page No. 28
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Substance CAS number Symbol Risk-phrases Safety phrases
NITROANILINE, all isomers 99-09-2 (o) T 23/24/25-33-52/53 (1/2-)28-36/37-45-61 Note C
2-NITRO-p-ANISIDINE 96-96-8 T+ 26/27/28-33-52/53 (1/2-)28-36/37-45-61
NITROBENZENE 98-95-3 T,N 23/24/25-40-48/23/24- (1/2-)28-36/37-45-61
51/53-62
4-NITROBIPHENYL 92-93-3 T 45 53-45
NITROCELLULOSE, containing a maximum of 12.6% F 11 (2-)16-33-37/39
NITROGEN
NITROCELLULOSE, containing more than 12,6% E 1-3 (2-)35
NITROGEN
NITROETHANE 79-24-3 Xn 10-20/22 (2-)9-25-41
NITROFEN 1836-75-5 T 45-61 53-45
NITROGEN DIOXIDE 10102-44-0 T+ 26-34 (1/2-)9-26-28-36/37/39-45
NITROGLYCERINE 55-63-0 E,T+ 3-26/27/28-33 (1/2-)33-35-36/37-45
NITROGLYCOL 628-96-6 E,T+ 2-26/27/28-33 (1/2-)33-35-36/37-45
NITROMANNITE 15825-70-4 E 3 (2-)35
NITROMETHANE 75-52-5 Xn 5-10-22 (2-)41
2-NITRONAPHTHALENE 581-89-5 T 45 53-45
4-NITROPHENOL 100-02-7 Xn 20/21/22-33 (2-)28
p-NITROPHENOL 100-02-7 Xn 20/21/22-33 (2-)28
1-NITROPROPANE 108-03-2 Xn 10-20/21/22 (2-)9
2-NITROPROPANE 79-46-9 T 45-10-20/22 53-45 Note E
4-NITROSOANILINE 659-49-4 Xn 20/21/22 (2-)25-28
N-NITROSODIMETHYLAMINE 62-75-9 T+,N 45-25-26-48/25-51/53 53-45-61 Note E
NITROSODIPROPYLAMINE 621-64-7 T,N 45-22-51/53 53-45-61 Note E
2,2'-(NITROSOIMINO)BISETHANOL 1116-54-7 T 45 53-45
2-NITROTOLUENE 88-72-2 T,N 23/24/25-33-51/53 (1/2-)28-37-45-61 Note C
4-NITROTOLUENE 99-99-0 T,N 23/24/25-33-51/53 (1/2-)28-37-45-61 Note C
NITROTOLUIDINE T,N 23/24/25-33-51/53 (1/2-)28-36/37-45-61 Note C
NONANOIC ACID 112-05-0 C 34 (1/2-)26-28-36/37/39-45
5-NONYL-1,2,4-TRIAZOL-3-YLAMINE Xn,N 22-36-51/53 (2-)22-26-61
NORBORMIDE 991-42-4 Xn 22 (2)
NORURON 2163-79-3 Xn 22 (2)
1,3,4,5,6,7,8,8-OCTACHLORO-1,3,3a,4,7,7a-HEXA 297-78-9 T+,N 27/28-50 (1/2-)28-36/37-45-61
HYDRO-4,7-METHANOISOBENZOFURAN
1,2,4,5,6,7,8,8-OCTACHLORO-3a,4,7,7a-TETRA- 57-74-9 Xn,N 21/22-40-50/53 (2-)36/37-60-61
HYDRO-4,7-METHANOINDAN
OCTAMETHYLPYROPHOSPHORAMIDE 152-16-9 T+ 27/28 (1/2-)36/37-38-45
OCTANE 111-65-9 F 11 (2-)9-16-29-33
OCTYLENE GLYCOL 94-96-2 Xi 36 (2-)26
2-(OCTYLTHIO)ETHANOL 3547-33-9 Xi 41 (2-)26
OCTYL 3,4,5-TRIHYDROXYBENZOATE 1034-01-0 Xn 22-43 (2-)24-37
OLEUM ... % SO3 C 14-35-37 (1/2-)26-30-45 Note B
OMETHOATE 1113-02-6 T,N 21-25-50 (1/2-)23-36/37-45-61
ORTOPHOSPHORIC ACID, 10%£conc.<25% Xi 36/38 (2-)25 Note B
ORTOPHOSPHORIC ACID, conc.³25% 7664-38-2 C 34 (1/2-)26-45 Note B
OSMIC ACID 20816-12-0 T+ 26/27/28-34 (1/2-)7/9-26-45
OSMIUM TETROXIDE 20816-12-0 T+ 26/27/28-34 (1/2-)7/9-26-45
OUABAIN 630-60-4 T 23/25-33 (1/2-)45
OXADIAZON 19666-30-9 N 50/53 60-61
OXALIC ACID 144-62-7 Xn 21/22 (2-)24/25
OXALIC ACID, SALTS Xn 21/22 (2-)24/25 Note A
OXALIC ACID DIETHYLESTER 95-92-1 Xn 22-36 (2-)23
OXAMYL 23135-22-0 T+ 21-26/28 (1/2-)36/37-45
OXIRANE 75-21-8 F+,T 45-46-12-23-36/37/38 53-45 Note E
OXYCARBOXIN 5259-88-1 Xn 22 (2)
OXYDEMETON-METHYL 301-12-2 T,N 24/25-50 (1/2-)23-36/37-45-61
2,2'-OXYDIETHYL DIACRYLATE 4074-88-8 T 24-36/38-43 (1/2-)28-39-45 Note D
OXYDIETHYLENE BIS(CHLOROFORMATE) 106-75-2 Xn 22-38-41 (2-)23-26
OXYDISULFOTON 2497-07-6 T+ 24-28 (1/2-)28-36/37-45
OXYGEN 7782-44-7 O 8 (2-)17
PAPAIN 9001-73-4 Xn 36/37/38-42 (2-)22-24-26-36/37
PAPAVERINE 58-74-2 Xn 22 (2-)22
PAPAVERINE, SALTS Xn 22 (2-)22 Note A
Page No. 29
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Substance CAS number Symbol Risk-phrases Safety phrases
PARALDEHYDE 123-63-7 F 11 (2-)9-16-29-33
PARAQUAT 4685-14-7 T 24/25-36/37/38 (1/2-)22-36/37/39-45
PARAQUAT, SALTS T 24/25-36/37/38 (1/2-)22-36/37/39-45 Note A
PARATHION 56-38-2 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
PARATHION-METHYL 298-00-0 T+ 24-28 (1/2-)28-36/37-45
PCB 1336-36-3 Xn,N 33-50/53 (2-)35-60-61 Note C
PEBULATE 1114-71-2 Xn 22 (2-)23
PENDIMETHALIN 40487-42-1 Xn 22 (2)
PENTACHLOROBENZENE 608-93-5 F,Xn,N 11-22-50/53 (2-)41-46-50-60-61
PENTACHLOROETHANE 76-01-7 T,N 40-48/23-51/53 (1/2-)23-36/37-45-61
PENTACHLORONAPHTHALENE Xn,N 21/22-36/38-50/53 (2-)35-60-61 Note C
PENTACHLORONITROBENZENE 82-68-8 Xi 43 (2-)24-37
PENTACHLOROPHENOL 87-86-5 T+,N 24/25-26-36/37/38-
40-50/53 (1/2-)22-36/37-45-52-60-61
PENTACHLOROPHENOL, SALTS T+,N 24/25-26-36/37/38- (1/2-)22-
40-50/53 36/37-45-52-60-61 Note A
PENTAERYTHRITOL TETRA-ACRYLATE 4986-89-4 Xi 36/38-43 (2-)26-39 Note D
PENTAERYTHRITOL TETRANITRATE 78-11-5 E 3 (2-)35
PENTAERYTHRITOL TRIACRYLATE 3524-68-3 Xi 36/38-43 (2-)39 Note D
PENTAETHYLENEHEXAMINE 4067-16-7 C,N 34-43-50/53 (1/2-)26-36/37/39-45-60-61
PENTANE 109-66-0 F 11 (2-)9-16-29-33 Note C
1,5-PENTANEDIAL 111-30-8 T,N 23/25-34-42/43-50 (1/2-)26-36/37/39-45-61
PENTANE-2,4-DIONE 123-54-6 Xn 10-22 (2-)21-23-24/25
tert-PENTANOL 75-85-4 F,Xn 11-20 (2-)9-16-24/25
PENTAN-3-ONE 96-22-0 F 11 (2-)9-16-33
PENTRIT 78-11-5 E 3 (2-)35
PENTYL ACETATE 628-63-7 - 10 (2-)23 Note C
PENTYL METHYLPHOSPHINATE and 87025-52-3 C 34 (1/2-)26-36/37/39-45
2-METHYLBUTYL METHYLPHOSPHINATE mixture
PENTYL NITRITE, mixture of isomers 463-04-7 F,Xn 11-20/22 (2-)16-24-46
110-46-3
PENTYL PROPIONATE 624-54-4 - 10 (2-)23 Note C
PEPSIN A 9001-75-6 Xn 36/37/38-42 (2-)22-24-26-36/37
PERACETIC ACID, conc.³10% 79-21-0 O,C 7-10-20/21/22-35 (1/2-)3/7-14-36/37/39-45
Note B, D
PERCHLORIC ACID, conc.³50% 7601-90-3 O,C 5-8-35 (1/2-)23-26-36-45 Note B
PERCHLORIC ACID, 10%£conc.<50% C 34 (1/2-)23-28-36 Note B
PERCHLOROETHYLENE 127-18-4 Xn,N 40-51/53 (2-)23-36/37-61
PERMETHRIN 52645-53-1 Xn 22 (2)
PEROXYACETIC ACID, conc.³10% 79-21-0 O,C 7-10-20/21/22-35 (1/2-)3/7-14-36/37/39-45
Note B, D
P.E.T.N. 78-11-5 E 3 (2-)35
PETROLEUM DISTILLATES, T 45 53-45
light naphthalenic distillate solvent 64742-03-6
heavy paraffinic distillate solvent 64742-04-7
light paraffinic distillate solvent 64742-05-8
heavy naphthalenic distillate solvent 64742-11-6
PETROLEUM DISTILLATES, T 45 53-45
light vacuum gas oil solvent 91995-78-7
1,10-PHENANTHROLINE 66-71-7 T 25 (1/2-)45
o-PHENETIDINE 94-70-2 T 23/24/25-33 (1/2-)28-36/37-45 Note C
p-PHENETIDINE 156-43-4 T 23/24/25-33 (1/2-)28-36/37-45 Note C
PHENKAPTON 2275-14-1 T,N 23/24/25-50/53 (1/2-)13-45-60-61
PHENOL 108-95-2 T 24/25-34 (1/2-)28-45
2-PHENOXYETHANOL 122-99-6 Xn 22-36 (2-)26
PHENTHOATE 2597-03-7 Xn 21/22 (2-)22-36/37
PHENYL 5,6-DICHLORO-2-TRIFLUOROMETHYL- 14255-88-0 Xn 21/22 (2-)36/37
BENZIMIDAZOLE-1-CARBOXYLATE
m-PHENYLENEDIAMINE 108-45-2 T,N 23/24/25-43-50/53 (1/2-)28-36/37-45-60-61 Note C
o-PHENYLENEDIAMINE 95-54-5 T,N 23/24/25-43-50/53 (1/2-)28-36/37-45-60-61 Note C
p-PHENYLENEDIAMINE 106-50-3 T,N 23/24/25-43-50/53 (1/2-)28-36/37-45-60-61 Note C
m-PHENYLENEDIAMINE DIHYDROCHLORIDE 541-69-5 T,N 23/24/25-43-50/53 (1/2-)28-36/37-45-60-61 Note C
p-PHENYLENEDIAMINE DIHYDROCHLORIDE 624-18-0 T,N 23/24/25-43-50/53 (1/2-)28-36/37-45-60-61 Note C
Page No. 30
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Substance CAS number Symbol Risk-phrases Safety phrases
1-PHENYLETHYLAMINE 98-84-0 C 21/22-34 (1/2-)26-28-36/37/39-45
PHENYL GLYCIDYL ETHER 122-60-1 Xn 21-43 (2-)24/25
PHENYLHYDRAZINE 100-63-0 T,N 23/24/25-36-50 (1/2-)28-45-61
PHENYMERCURY ACETATE 62-38-4 T 25-34-48/24/25 (1/2-)23-24/25-37-45
PHENYLMERCURY HYDROXIDE and 8003-05-2 T 25-34-37-44-48/24/25 (1/2-)23-24/25-37-45
PHENYLMERCURY NITRATE mixture
PHENYLOXIRANE 96-09-3 T 45-21-36 53-45 Note E
2-PHENYLPHENOL 90-43-7 Xi 36/38 (2-)22
2-PHENYLPHENOL, SODIUM SALT 132-27-4 Xn 22-38-41 (2-)22-26
1-PHENYL-3-PYRAZOLIDONE 92-43-3 Xn 22 (2)
PHORATE 298-02-2 T+ 27/28 (1/2-)28-36/37-45
PHOSACETIM 4104-14-7 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
PHOSALONE 2310-17-0 T,N 21-25-50/53 (1/2-)36/37-45-60-61
PHOSFOLAN 947-02-4 T+ 27/28 (1/2-)28-36/37-45
PHOSGENE 75-44-5 T+ 26-34 (1/2-)9-26-36/37/39-45
PHOSMET 732-11-6 Xn 21/22 (2-)22-36/37
PHOSNICHLOR 5826-76-6 Xn 20/21/22 (2-)13
PHOSPHAMIDON 13171-21-6 T+,N 24-28-40-50/53 (1/2-)23-36/37-45-60-61
PHOSPHORIC ACID, conc.³25% 7664-38-2 C 34 (1/2-)26-45 Note B
PHOSPHORIC ACID, 10%£conc.<25% Xi 36/38 (2-)25 Note B
PHOSPHORUS OXYCHLORIDE 10025-87-3 C 34-37 (1/2-)7/8-26-45
PHOSPHORUS PENTACHLORIDE 10026-13-8 C 34-37 (1/2-)7/8-26-45
PHOSPHORUS PENTASULPHIDE 1314-80-3 F,Xn 11-20/22-29 (2)
PHOSPHORUS PENTOXIDE 1314-56-3 C 35 (1/2-)22-26-45
PHOSPHORUS, RED F 11-16 (2-)7-43
PHOSPHORUS SESQUISULPHIDE 1314-85-8 F,Xn 11-22 (2-)7-16-24/25
PHOSPHORUS TRIBROMIDE 7789-60-8 C 14-34-37 (1/2-)26-45
PHOSPHORUS TRICHLORIDE 7719-12-2 C 34-37 (1/2-)7/8-26-45
PHOSPHORUS, WHITE and YELLOW 12185-10-3 F,T+,C 17-26/28-35 (1/2-)5-26-28-45
PHOSPHORYL CHLORIDE 10025-87-3 C 34-37 (1/2-)7/8-26-45
PHOXIM 14816-18-3 Xn 22 (2-)36
PHTHALIC ANHYDRIDE 85-44-9 Xi 36/37/38 (2)
PHYSOSTIGMINE 57-47-6 T+ 26/28 (1/2-)25-45
PHYSOSTIGMINE, SALTS T+ 26/28 (1/2-)25-45 Note A
2-PICOLINE 109-06-8 Xn 10-20/21/22-36/37 (2-)26-36
4-PICOLINE 108-89-4 T 10-20/22-24-36/37/38 (1/2-)26-36-45
PICRAMIC ACID 96-91-3 E,Xn 1-20/21/22-52/53 (2-)35-61
PICRIC ACID 88-89-1 E,T 2-4-23/24/25 (1/2-)28-35-37-45
PICRIC ACID, SALTS E,T 3-23/24/25 (1/2-)28-35-37-45 Note A
PILOCARPINE 92-13-7 T+ 26/28 (1/2-)25-45
PILOCARPINE, SALTS T+ 26/28 (1/2-)25-45 Note A
PINDONE 83-26-1 T 25-48/25 (1/2-)37-45
PIPERAZINE 110-85-0 C 34-42/43-52/53 (1/2-)22-26-36/37/39-45-61
2-PIPERAZIN-1-YLETHYLAMINE 140-31-8 C 21/22-34-43-52/53 (1/2-)26-36/37/39-45-61
PIPERIDINE 110-89-4 F,T 11-23/24-34 (1/2-)16-26-27-45
PIPEROPHOS 24151-93-7 Xn 22 (2)
PIRIMICARB 23103-98-2 T 25 (1/2-)22-37-45
PIRIMIPHOS-ETHYL 23505-41-1 T,N 21-25-50/53 (1/2-)23-36/37-45-60-61
PIRIMIPHOS-METHYL 29232-93-7 Xn 22 (2)
2-PIVALOYLINDAN-1,3-DIONE 83-26-1 T 25-48/25 (1/2-)37-45
POLYCHLOROBIPHENYLS 1336-36-3 Xn,N 33-50/53 (2-)35-60-61 Note C
POLYETHYLENEPOLYAMINES with the exception C,N 21/22-34-43-50/53 (1/2-)26-36/37/39-45-60-61
of those specified elsewhere in this Annex
POTASSIUM 7440-09-7 F,C 14/15-34 (1/2-)5*-8-45 *If appropriate
POTASSIUM BIFLUORIDE 7789-29-9 T,C 25-34 (1/2-)22-26-37-45
POTASSIUM BROMATE 7758-01-2 O,T 45-9-25 53-45 Note E
POTASSIUM CHLORATE 3811-04-9 O,Xn 9-20/22 (2-)13-16-27
POTASSIUM CHROMATE 7789-00-6 T,N 49-46-36/37/38-43-50/53 53-45-60-61 Note E
POTASSIUM CYANATE 590-28-3 Xn 22 (2-)24/25
POTASSIUM DICHROMATE 7778-50-9 T+,N 49-46-21-25-26-37/38- 53-45-60-61 Note E
41-43-50/53
POTASSIUM FLUORIDE 7789-23-3 T 23/24/25 (1/2-)26-45
POTASSIUM mu-FLUORO-BIS(TRIETHYLALUMINIUM) 12091-08-6 F,C 11-14/15-20-35 (1/2-)16-30-36/39-43-45
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Substance CAS number Symbol Risk-phrases Safety phrases
POTASSIUM HEKSAFLUOROSILICATE 16871-90-2 T 23/24/25 (1/2-)26-45 Note A
POTASSIUM HYDROGEN DIFLUORIDE 7789-29-9 T,C 25-34 (1/2-)22-26-37-45
POTASSIUM HYDROGENSULPHATE 7646-93-7 C 34-37 (1/2-)26-36/37/39-45
POTASSIUM HYDROXIDE 1310-58-3 C 35 (1/2-)26-37/39-45
POTASSIUM HYDROXIDE SOLUTION, conc.³5% C 35 (1/2-)26-27-37/39
POTASSIUM HYDROXIDE SOLUTION, 0.5%£conc.<2% Xi 36/38 (2-)26
POTASSIUM 2-HYDROXYCARBAZOLE-1-CARBOXYLATE 96566-70-0 Xn 22-36/37-52/53 (2-)22-26-61
POTASSIUM NITRITE 7758-09-0 O,T 8-25 (1/2-)45
POTASSIUM PERCHLORATE 7778-74-7 O,Xn 9-22 (2-)13-22-27
POTASSIUM PERMANGANATE 7722-64-7 O,Xn 8-22 (2)
POTASSIUM POLYSULPHIDES 37199-66-9 C 31-34 (1/2-)26-45
POTASSIUM SULPHIDE 1312-73-8 C 31-34 (1/2-)26-45
PROFENOFOS 41198-08-7 Xn 20/21/22 (2-)36/37
PROFLURALIN 26399-36-0 Xi 36 (2)
PROMECARB 2631-37-0 T 25 (1/2-)24-37-45
PROPACHLOR 1918-16-7 Xn 22-36-43 (2-)24-37
PROPANAL 123-38-6 F,Xi 11-36/37/38 (2-)9-16-29
PROPANE 74-98-6 F+ 12 (2-)9-16-33
1,3-PROPANESULTONE 1120-71-4 T 45-21/22 53-45 Note E
PROPANIL 709-98-8 Xn 22 (2-)22
1-PROPANOL 71-23-8 F 11 (2-)7-16 Note C
PROPAN-2-OL 67-63-0 F 11 (2-)7-16 Note C
3-PROPANOLIDE 57-57-8 T+ 45-26-36/38 53-45 Note E
PROPARGITE 2312-35-8 Xn 22-36 (2-)24
PROPARGYL ALCOHOL 107-19-7 T 10-23/24/25-34 (1/2-)26-28-36-45
PROPAZINE 139-40-2 Xn 40 (2-)36/37
PROPENE 115-07-1 F+ 12 (2-)9-16-33
2(-3(PROP-1-EN-2-YL)PHENYL)PROP-2-YL 2094-99-7 T+,N 26-34-42/43-48/20-50/53 (1/2-)7-15-28-36/37/39-38-
ISOCYANATE 45-60-61
PROPETAMPHOS 31218-83-4 T 25 (1/2-)37-45
1,3-PROPIOLACTONE 57-57-8 T+ 45-26-36/38 53-45 Note E
PROPIONALDEHYDE 123-38-6 F,Xi 11-36/37/38 (2-)9-16-29
PROPIONIC ACID, conc.³25% 79-09-4 C 34 (1/2-)23-36-45 Note B
PROPIONIC ACID, 10%£conc.<25% 79-09-4 Xi 36/37/38 (2)
PROPIONIC ANHYDRIDE 123-62-6 C 34 (1/2-)26-45
PROPIONYL CHLORIDE 79-03-8 F,C 11-14-34 (1/2-)9-16-26-45
PROPOXUR 114-26-1 T 25 (1/2-)37-45
PROPYL ACETATE 109-60-4 F 11 (2-)16-23-29-33 Note C
PROPYL BENZENE 103-65-1 Xi 10-37 (2) Note C
PROPYL BROMIDE 106-94-5 Xn 10-20 (2-)9-24
S-PROPYLBUTYLETHYL THIOCARBAMATE 1114-71-2 Xn 22 (2-)23
PROPYL CHLORIDE 540-54-5 F,Xn 11-20/21/22 (2-)9-29 Note C
PROPYL CHLOROFORMATE 109-61-5 T 10-23-34 (1/2-)26-36-45
PROPYLENE 115-07-1 F+ 12 (2-)9-16-33
PROPYLENE CARBONATE 108-32-7 Xi 36 (2)
PROPYLENEDIAMINE 78-90-0 C 10-21/22-35 (1/2-)26-37/39-45
PROPYLENE GLYCOL MONOBUTYL ETHER 5131-66-8 Xi 36/38 (2)
PROPYLENEIMINE 75-55-8 F,T+ 45-11-26/27/28-41 53-45 Note E
PROPYLENE OXIDE 75-56-9 F+,T 45-12-20/21/22-36/37/38 53-45 Note E
1,3-PROPYLENE OXIDE 503-30-0 F,Xn 11-20/21/22 (2-)9-16-26-29
PROPYLENETHIOUREA 2122-19-2 Xn 40 (2-)36/37
PROPYL FORMATE 110-74-7 F 11 (2-)9-16-33 Note C
PROPYLISOME 83-59-0 T 22-24 (1/2-)36/37-45
2-(PROPYLOXY)ETHANOL 2807-30-9 Xn 10-21-36 (2-)24/25-36/37
PROPYL PROPIONATE 106-36-5 - 10 (2)
PROPYL 3,4,5-TRIHYDROXYBENZOATE 121-79-9 Xn 22-43 (2-)24-37
PROP-2-YN-1-OL 107-19-7 T 10-23/24/25-34 (1/2-)26-28-36-45
PROTEASES, with exception of those specified Xn 36/37/38-42 (2-)22-24-26-36/37
elsewhere in this Annex
PROTEINASE, microbial neutral 9068-59-1 Xn 36/37/38-42 (2-)22-24-26-36/37
PROTHIOCARB HYDROCHLORIDE 19622-19-6 Xn 22 (2)
PROTHOATE 2275-18-5 T+ 27/28 (1/2-)28-36/37-45
PROXAN-SODIUM 140-93-2 Xn 22-38 (2-)13
Page No. 32
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Substance CAS number Symbol Risk-phrases Safety phrases
PYRAZON 1698-60-8 Xi 43 (2-)24-37
PYRAZOPHOS 13457-18-6 Xn 22 (2)
PYRAZOXON 108-34-9 T+ 26/27/28 (1/2-)13-28-45
PYRETHRIN I 121-21-1 Xn 20/21/22 (2-)13
PYRETHRIN II 121-29-9 Xn 20/21/22 (2-)13
PYRETHRINS including CINERINS Xn 20/21/22 (2-)13
PYRIDINE 110-86-1 F,Xn 11-20/21/22 (2-)26-28
PYROCATECHOL 120-80-9 Xn 21/22-36/38 (2-)22-26-37
PYROGALLOL 87-66-1 Xn 20/21/22 (2)
PYROMELLITIC DIANHYDRIDE 89-32-7 Xi 36/37/38 (2-)25
QUINALPHOS 13593-03-8 T 21-25 (1/2-)22-36/37-45
QUINOL 123-31-9 Xn 20/22 (2-)24/25-39
QUINOMETHIONATE 2439-01-2 Xi 36-43 (2-)24-37
QUINONE 106-51-4 T 23/25-36/37/38 (1/2-)26-28-45
QUINTOZENE 82-68-8 Xi 43 (2-)24-37
RED SQUILL 507-60-8 T+ 28 (1/2-)36/37-45
RENNIN 9001-98-3 Xn 36/37/38-42 (2-)22-24-26-36/37
RESMETHRIN 10453-86-8 Xn 22 (2)
RESORCINOL 108-46-3 Xn 22-36/38 (2-)26
RESORCINOL DIGLYCIDYL ETHER 101-90-6 T 23/24/25-40-43 (1/2-)23-24-45
ROSIN 8050-09-7 Xn 42/43 (2-)22-23-24-37
ROTENONE 83-79-4 T 25-36/37/38 (1/2-)22-24/25-36-45
RYANIA 15662-33-6 Xn 21/22 (2-)36/37
SABADILLA 8051-02-3 Xi 36/37/38 (2-)36/37/39
SAFROLE 94-59-7 T 45-22-40 53-45 Note E
SCHRADAN 152-16-9 T+ 27/28 (1/2-)36/37-38-45
SCILLIROSIDE 507-60-8 T+ 28 (1/2-)36/37-45
SCOPOLAMINE 51-34-3 T+ 26/27/28 (1/2-)25-45
SECBUMETON 26259-45-0 Xn 22-36 (2)
SELENIUM 7782-49-2 T 23/25-33 (1/2-)20/21-28-45
SELENIUM COMPOUNDS except CADMIUM T 23/25-33 (1/2-)20/21-28-45 Note A
SULPHOSELENIDE
SESAMEX 51-14-9 Xn 22 (2)
SILVER NITRATE 7761-88-8 C 34 (2-)26-45
SIMAZINE 122-34-9 Xn 40 (2-)36/37
SIMETRYN 1014-70-6 Xn 22 (2)
SODIUM 7440-23-5 F,C 14/15-34 (1/2-)5*-8-43-45
*If appropriate
SODIUM AZIDE 26628-22-8 T+ 28-32 (1/2-)28-45
SODIUM BIFLUORIDE 1333-83-1 T,C 25-34 (1/2-)22-26-37-45
SODIUM 2-BIPHENYLATE 132-27-4 Xn 22-38-41 (2-)22-26
SODIUM CARBONATE 497-19-8 Xi 36 (2-)22-26
SODIUM CHLORATE 7775-09-9 O,Xn 9-22 (2-)13-17-46
SODIUM CHLOROACETATE 3926-62-3 T 25-38 (1/2-)22-37-45
SODIUM 3-CHLOROACRYLATE 4312-97-4 Xn 21/22 (2-)36/37
SODIUM-N-CHLORO-p-TOLUENESULPHONAMIDE 127-65-1 Xi 36/37/38 (2-)7-15
SODIUM CYANATE 917-61-3 Xn 22 (2-)24/25
SODIUM DEHYDRACETATE 4418-26-2 Xn 22 (2)
SODIUM DICHLOROISOCYANURATE, DIHYDRATE 51580-86-0 Xn 22-31-36/37 (2-)8-26-41
SODIUM DICHROMATE 10588-01-9 O,T+,N 49-46-8-21-25-26- 53-45-60-61 Note E
37/38-41-43-50/53
SODIUM DICHROMATE, DIHYDRATE 7789-12-0 T+,N 49-46-21-25-26-37/38- 53-45-60-61 Note E
41-43-50/53
SODIUM 4-DIMETHYLAMINOBENZENEDIAZOSULPHONATE 140-56-7 T 21-25 (1/2-)36/37-45
SODIUM DITHIONITE 7775-14-6 Xn 7-22-31 (2-)7/8-26-28-43
SODIUM FLUORIDE 7681-49-4 T 25-32-36/38 (1/2-)22-36-45
SODIUM FLUOROACETATE 62-74-8 T+ 26/27/28 (1/2-)13-22-36/37-45
SODIUM HEXAFLUOROSILICATE 16893-85-9 T 23/24/25 (1/2-)26-45 Note A
SODIUM HYDRIDE 7646-69-7 F 15 (2-)7/8-24/25-43
SODIUM HYDROGENSULPHATE 7681-38-1 C 34-37 (1/2-)26-36/37/39-45
SODIUM HYDROSULPHITE 7775-14-6 Xn 7-22-31 (2-)7/8-26-28-43
SODIUM HYDROXIDE 1310-73-2 C 35 (1/2-)26-37/39-45
SODIUM HYDROXIDE SOLUTION, conc.³5% C 35 (1/2-)26-27-37/39-45
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Substance CAS number Symbol Risk-phrases Safety phrases
SODIUM HYDROXIDE SOLUTION, 2£conc.<5% C 34 (1/2-)26-27-37/39-45
SODIUM HYDROXIDE SOLUTION, 0.5%£conc.<2% Xi 36/38 (2-)26
SODIUM HYPOCHLORITE SOLUTION, active 7681-52-9 C 31-34 (1/2-)28-45-50 Note B
Chlorine³10%
SODIUM HYPOCHLORITE SOLUTION, 5%£active 7681-52-9 Xi 31-36/38 (2-)25-46-50 Note B
Chlorine conc.<10%
SODIUM ISOPROPYLXANTHATE 140-93-2 Xn 22-38 (2-)13
SODIUM METHYLDITHIOCARBAMATE 137-42-8 Xn 21/22-31-41 (2-)26-36/37/39
SODIUM NITRITE 7632-00-0 O,T 8-25 (1/2-)45
SODIUM 3-NITROBENZENESULPHONATE 127-68-4 Xi 36-43 (2-)24-26-37
SODIUM PERCHLORATE 7601-89-0 O,Xn 9-22 (2-)13-22-27
SODIUM PEROXIDE 1313-60-6 O,C 8-35 (1/2-)8-27-39-45
SODIUM POLYSULPHIDES 1344-08-7 C 31-34 (1/2-)26-45
SODIUM SULPHIDE 1313-82-2 C 31-34 (1/2-)26-45
SODIUM TRICHLOROACETATE 650-51-1 Xn 22 (2-)24-25
SODIUM 4-2,4,4-TRIMETHYLPENTYLCARBONYLOXY) T 22-23-36/37-43-48/23 (1/2-)22-24-36-45
BENZENESULPHONATE
STANNIC CHLORIDE 7646-78-8 C 34-37 (1/2-)7/8-26-45
STRONTIUM CHROMATE 7789-06-2 T,N 45-22-50/53 53-45-60-61 Note E
g-STROPHANTIN 630-60-4 T 23/25-33 (1/2-)45
STROPHANTIN-K 11005-63-3 T 23/25-33 (1/2-)45
STRYCHNINE 57-24-9 T+ 27/28 (1/2-)36/37-45
STRYCHNINE, SALTS T+ 26/28 (1/2-)13-28-45 Note A
STYPHNIC ACID 82-71-3 E,Xn 2-4-20/21/22 (2-)35
STYRENE 100-42-5 Xn 10-20-36/38 (2-)23 Note D
STYRENE OXIDE 96-09-3 T 45-21-36 53-45 Note E
SUBTILISIN 9014-01-1 Xn 36/37/38-41-42 (2-)22-24-26-36/37/39
SUCCINIC ANHYDRIDE 108-30-5 Xi 36/37 (2-)25
SULFALLATE 95-06-7 T 45-22 53-45 Note E
SULFOTEP 3689-24-5 T+ 27/28 (1/2-)23-28-36/37-45
SULPHAMIC ACID 5329-14-6 Xi 36/38 (2-)26-28
SULPHANILIC ACID 121-57-3 Xi 36/38-43 (2-)24-37
SULPHOLANE 126-33-0 Xn 22 (2-)25
SULPHUR DICHLORIDE 10545-99-0 C 14-34-37 (1/2-)26-45
SULPHUR DIOXIDE 7446-09-5 T 23-34 (1/2-)9-26-36/37/39-45
SULPHURIC ACID, conc.>15% 7664-93-9 C 35 (1/2-)26-30-45 Note B
SULPHURIC ACID, 5%30% HNO3
SULPHUR TETRACHLORIDE 13451-08-6 C 14-34-37 (1/2-)26-45
SULPHURYL CHLORIDE 7791-25-5 C 14-34-37 (1/2-)26-45
SULPHURYL DIFLUORIDE 2699-79-8 T 23/25-36/37/38 (1/2-)23-37/38-45
SWEP 1918-18-9 Xn 22 (2)
2,4,5-T 93-76-5 Xn 22-36/37/38 (2-)24
2,4,5-T, SALTS AND ESTERS Xn 22-36/37/38 (2-)24 Note A
2,3,6-TBA 50-31-7 Xn 22 (2)
TECNAZENE 117-18-0 Xi 43 (2-)24-37
TEPP 107-49-3 T+,N 27/28-50 (1/2-)36/37/39-38-45-61
TERBUFOS 13071-79-9 T+ 27/28 (1/2-)36/37-45
TERBUMETON 33693-04-8 Xn 22 (2)
3,6,9,12-TETRA-AZATETRADECAMETHYLENEDIAMINE 4067-16-7 C,N 34-43-50/53 (1/2-)26-36/37/39-45-60-61
TETRACHLORO-p-BENZOQUINONE 118-75-2 Xi,N 36/38-50/53 (2-)37-60-61
1,1,2,2-TETRABROMOETHANE 79-27-6 T+ 26-36-52/53 (1/2-)24-27-45-61
1,1,2,2-TETRACHLOROETHANE 79-34-5 T+ 26/27 (1/2-)38-45
TETRACHLOROETHYLENE 127-18-4 Xn,N 40-51/53 (2-)23-36/37-61
TETRACHLOROISOPHTHALONITRILE 1897-45-6 Xn 40 (2-)36/37
TETRACHLOROMETHANE 56-23-5 T,N 23/24/25-40-48/23- (1/2-)23-36/37-45-59-61
52/53-59
2,3,5,6-TETRACHLORO-4-(METHYLSULPHONYL) 13108-52-6 Xn 21/22-36-43 (2-)26/28
PYRIDINE
2,3,4,6-TETRACHLOROPHENOL 58-90-2 T 25-36/38 (1/2-)26-28-37-45
TETRACHLOROTEREPHTHALONITRILE 1897-41-2 Xi 43-53 (2-)24-37-61
O,O,O',O'-TETRAETHYL DITHIOPYROPHOSPHATE 3689-24-5 T+ 27/28 (1/2-)23-28-36/37-45
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Substance CAS number Symbol Risk-phrases Safety phrases
TETRAETHYLENEPENTAMINE 112-57-2 C,N 21/22-34-43-51/53 (1/2-)26-36/37/39-45-61
O,O,O',O'-TETRAETHYL S,S'-METHYLENE 563-12-2 T 21-25 (1/2-)25-36/37-45
DI(PHOSPHORODITHIOATE)
TETRAETHYL PYROPHOSPHATE 107-49-3 T+,N 27/28-50 (1/2-)36/37/39-38-45-61
TETRAETHYL SILICATE 78-10-4 Xn 10-20-36/37 (2)
TETRAHYDRO-3,5-DIMETHYL-1,3,5-THIADIAZINE- 533-74-4 Xn 22-36 (2-)15-22-24
2-THIONE
TETRAHYDROFURAN 109-99-9 F,Xi 11-19-36/37 (2-)16-29-33
TETRAHYDROFURAN-2,5-DIYLDIMETHANOL 104-80-3 Xi 36/37/38 (2-)39
TETRAHYDROFURFURYL ALCOHOL 97-99-4 Xi 36 (2-)39
TETRAHYDRO-2-FURYLMETHANOL 97-99-4 Xi 36 (2-)39
3a,4,7,7a-TETRAHYDRO-4,7-METHANOINDENE 77-73-6 F,Xn,N 11-20/22-36/37/38-51-53 (2-)36/37-61
1,2,3,4-TETRAHYDRONAPHTHALENE 119-64-2 Xi 19-36/38 (2-)26-28
1,2,3,4-TETRAHYDRO-1-NAPHTHYL HYDROPEROXIDE 771-29-9 O,C 7-22-34 (1/2-)3/7-14-36/37/39-45
TETRAHYDROPHTHALIC ANHYDRIDE 85-43-8 Xi 36/37 (2-)25
TETRAHYDROTHIOPHENE 110-01-0 F,Xn 11-20/21/22-36/37 (2-)16-23-36/37
TETRAHYDROTHIOPHENE-1,1-DIOXIDE 126-33-0 Xn 22 (2-)25
TETRALIN HYDROPEROXIDE 771-29-9 O,C 7-22-34 (1/2-)3/7-14-36/37/39-45
TETRAMETHYLENE DIACRYLATE 1070-70-8 C 21-34-43 (1/2-)26-36/37/39-45 Note D
N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE 110-18-9 F,C 11-20/22-34 (1/2-)16-26-36/37/39-45
N,N,N',N''-TETRAMETHYL-p-PHENYLENEDIAMINE 100-22-1 Xn 20/21/22 (2-)28
N,N,N',N'-TETRAMETHYLPHOSPHORODIAMINIC 115-26-4 T+ 27/28 (1/2-)23-28-36/37-38-45
FLUORIDE
TETRAMETHYLTHIURAM DISULPHIDE 137-26-8 Xn 20/22-36/37-40-43 (2-)36/37
1,2,3,4-TETRANITROCARBAZOLE 6202-15-9 E,Xn 1-20/21/22 (2-)35
TETRANITRONAPHTHALENE (mix) 55810-18-9 E,Xn 2-20/21/22-33 (2-)35 Note C
O,O,O',O'-TETRAPROPYL DITHIOPYROPHOSPHATE 3244-90-4 Xn,N 21/22-50/53 (2-)36/37-60-61
TETRASODIUM 5'-(4,6-DICHLORO-5-CYANOPYRIMIDIN- Xn,N 45-51/53 (2-)22-61
2-YLAMINO)-4'-HYDROXY-2,3'-AZODINAPHTHALENE-
1,2',5,7'-DISULPHONATE
TETRYL 479-45-8 E,T 2-23/24/25-33 (1/2-)35-45
TGIC (triglycidylisocyanurate) 2451-62-9 T 46-23/25-41-43-48/22- 53-45-61 Note E
52/53
THALLIC SULPHATE 7446-18-6 T+ 28-38-48/25 (1/2-)13-36/37-45
THALLIUM 7440-28-0 T+ 26/28-33 (1/2-)13-28-45
THALLIUM COMPOUNDS T+ 26/28-33 (1/2-)13-28-45 Note A
THIAZFLURON 25366-23-8 Xn 22 (2)
THIOACETAMIDE 62-55-5 T 45-22-36/38 53-45 Note E
THIOBENCARB 28249-77-6 Xn 22 (2)
THIOCARBAMIDE 62-56-6 Xn,N 22-40-51/53 (2-)22-24-36/37-61
THIOCARBONYL CHLORIDE 463-71-8 T 22-23-36/37/38 (1/2-)7-9-36/37-45
THIOCYANIC ACID 463-56-9 Xn 20/21/22-32 (2-)13
THIOCYANIC ACID, SALTS Xn 20/21/22-32 (2-)13 Note A
THIOCYCLAM-OXALATE 31895-22-4 Xn 21/22 (2-)36/37-46
2,2'-THIODIETHANOL 111-48-8 Xi 36 (2)
2-THIO-1,3-DITHIOLO-[4,5-b]QUINOXALINE 93-75-4 Xn 22 (2-)24
THIOFANOX 39196-18-4 T+ 27/28 (1/2-)27-36/37-45
THIODIGLYCOL 111-48-8 Xi 36 (2)
THIOGLYCOLIC ACID 68-11-1 T 23/24/25-34 (1/2-)25-27-28-45
THIOMETON 640-15-3 T 21-25 (1/2-)36/37-45
THIONAZIN 297-97-2 T+ 27/28 (1/2-)36/37/39-38-45
THIONYL CHLORIDE 7719-09-7 C 14-34-37 (1/2-)26-45
THIOPHANATE-METHYL 23564-05-8 Xn 40 (2-)36/37
THIOQUINOX 93-75-4 Xn 22 (2-)24
THIOUREA 62-56-6 Xn,N 22-40-51/53 (2-)22-24-36/37-61
THIRAM 137-26-8 Xn 20/22-36/37-40-43 (2-)36/37
THYMOL 89-83-8 C 22-34 (1/2-)26-28-36/37/39
TIN(II) METHANESULPHONATE 53408-94-9 C 22-34-43 (1/2-)22-26-36/37/39-45
TITANIUM TETRACHLORIDE 7550-45-0 C 14-34-36/37 (1/2-)7/8-26-45
TNT 118-96-7 E,T 2-23/24/25-33 (1/2-)35-45
o-TOLIDINE, SALTS T,N 45-22-51/53 53-45-61 Note A, E
TOLUENE 108-88-3 F,Xn 11-20 (2-)16-25-29-33
TOLUENE-2,4-DIAMMONIUM SULPHATE 65321-67-7 T,N 45-21-25-36-43-50/53 53-45-60-61 Note E
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Substance CAS number Symbol Risk-phrases Safety phrases
TOLUENE-2,6-DIISOCYANATE 91-08-7 T 23-36/37/38-42 (1/2-)23-26-28-38-45 Note C
TOLUENE-2,4-DIISOCYANATE 548-84-9 T 23-36/37/38-42 (1/2-)23-26-28-38-45 Note C
p-TOLUENESULPHONIC ACID, containing more C 34 (1/2-)26-37/39-45
than 5% H2SO4
p-TOLUENESULPHONIC ACID, containing a maximum 104-15-4 Xi 36/37/38 (2-)26-37
of 5% H2SO4
4-TOLUENESULPHONYLISOCYANATE 4083-64-1 Xn 14-36/37/38-42 (2-)26-28-30
m-TOLUIDINE 108-44-1 T,N 23/24/25-33-50 (1/2-)28-36/37-45-61 Note C
p-TOLUIDINE 106-49-0 T,N 23/24/25-33-50 (1/2-)28-36/37-45-61 Note C
o-TOLUIDINE 95-53-4 T,N 45-23/25-36-50 53-45-61 Note E
4-o-TOLYLAZO-o-TOLUIDINE 97-56-3 T 45-43 53-45
TOSYLISOCYANATE 4083-64-1 Xn 14-36/37/38-42 (2-)26-28-30
TOXAPHENE 8001-35-2 T,N 21-25-37/38-40-50/53 (1/2-)36/37-45-60-61
TRIADIMEFON 43121-43-3 Xn 22 (2)
TRIALKYLBORANES F,C 17-34 (1/2-)7-23-26-36/37/39
-43-45 Note A
TRI-ALLATE 2303-17-5 Xn 22 (2)
TRIAMIPHOS 1031-47-6 T+ 27/28 (1/2-)22-28-36/37-45
TRIARIMOL 26766-27-8 Xn 22 (2)
3,6,9-TRIAZAUNDECAMETHYLENEDIAMINE 112-57-2 C,N 21/22-34-43-51/53 (1/2-)26-36/37/39-45-61
1,2,4-TRIAZOL-3-YLAMINE 61-82-5 Xn,N 40-48/22-51/53 (2-)36-37-61
TRIAZOPHOS 24017-47-8 T 24/25 (1/2-)23-36/37-45
TRIBROMOMETHANE 75-25-2 T,N 23-36/38-51/53 (1/2-)28-45-61
TRIBUTYL-(2,4-DICHLOROBENZYL) PHOSPHONIUM 115-78-6 T 21-25-36/38 (1/2-)36/37/39-45
CHLORIDE
TRIBUTYL PHOSPHATE 126-73-8 Xn 22 (2-)25
TRIBUTYLTIN COMPOUNDS with the exception of T 21-25-36/38-48/23/25 (1/2-)35-36/37/39-45 Note A
those specified elsewhere in this Annex
TRICHLORFON 52-68-6 Xn 22-43 (2-)24-37
TRICHLOROACETIC ACID 76-03-9 C 35 (1/2-)24/25-26-45
TRICHLOROACETONITRILE 545-06-2 T 23/24/25 (1/2-)45
S-2,3,3-TRICHLOROALLYL-DIISOPROPYL- 2303-17-5 Xn 22 (2)
THIOCARBAMATE
TRICHLOROANILINE T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61 Note C
2,3,6-TRICHLOROBENZOIC ACID 50-31-7 Xn 22 (2)
1,1,1-TRICHLORO-2,2-BIS(4-CHLOROPHENYL)ETHANE 50-29-3 T,N 25-40-48/25-50/53 (1/2-)22-36/37-45-60-61
2,2,2-TRICHLORO-1,1-BIS(4-CHLOROPHENYL)- 115-32-2 Xn 21/22-38-43 (2-)36/37
ETHANOL
2,3,4-TRICHLOROBUT-1-ENE 2431-50-7 T,N 22-23-36/37/38-40-50/53 (1/2-)36/37-45-60-61
1,1,1-TRICHLOROETHANE 71-55-6 Xn,N 20-59 (2-)24/25-59-61 Note F
1,1,2-TRICHLOROETHANE 79-00-5 Xn 20/21/22 (2-)9
2,2,2-TRICHLOROETHANE-1,1-DIOL 302-17-0 T 25-36/38 (1/2-)25-45
TRICHLOROETHYLENE 79-01-6 Xn 40-52/53 (2-)23-36/37-61
TRICHLOROISOCYANURIC ACID 87-90-1 O,Xn 8-22-31-36/37 (2-)8-26-41
TRICHLOROMETHANE 67-66-3 Xn 22-38-40-48/20/22 (2-)36/37
TRICHLORO(METHYL)SILANE 75-79-6 F,Xi 11-14-36/37/38 (2-)26-39
TRICHLORONATE 327-98-0 T+,N 24-28-50/53 (1/2-)23-28-36/37-45-60-61
TRICHLORONITROMETHANE 76-06-2 T+ 22-26-36/37/38 (1/2-)36/37-38-45
2,4,5-TRICHLOROPHENOL 95-95-4 Xn,N 22-36/38-50/53 (2-)26-28-60-61
2,4,6-TRICHLOROPHENOL 88-06-2 Xn 22-36/38-40 (2-)36/37
2,4,5-TRICHLOROPHENOXYACETIC ACID 93-76-5 Xn 22-36/37/38 (2-)24
2-(2,4,5-TRICHLOROPHENOXY)ETHYL 136-25-4 Xn 22 (2)
2,2-DICHLOROPROPIONATE
2-(2,4,5-TRICHLOROPHENOXY) PROPIONIC ACID 93-72-1 Xn 22-38 (2-)37
2,3,6-TRICHLOROPHENYLACETIC ACID 85-34-7 Xn 22 (2-)36
1,2,3-TRICHLOROPROPANE 96-18-4 Xn 20/21/22 (2-)37/39 Note D
TRICHLOROSILANE 10025-78-2 F 15-17 (2-)24/25-43
I,I,I-TRICHLOROTOLUENE 98-07-7 T 45-22-23-37/38-41 53-45 Note E
2,4,6-TRICHLORO-1,3,5-TRIAZINE 108-77-0 Xi 36/37/38 (2-)28
TRICHLORO-1,3,5-TRIAZINE-2,4,6-TRIONE 87-90-1 O,Xn 8-22-31-36/37 (2-)8-26-41
TRICRESYL PHOSPHATE, o-o-o, o-o-m, o-o-p, T,N 39-23/24/25-51/53 (1/2-)20/21-28-45-61 Note C
o-m-m, o-m-p, o-p-p, conc.³1%
TRICRESYL PHOSPHATE, m-m-m, m-m-p, m-p-p, Xn,N 21/2251/53 (2-)28-61 Note C
p-p-p, conc.³5%
Page No. 36
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Substance CAS number Symbol Risk-phrases Safety phrases
TRICYCLAZOLE 41814-78-2 Xn 22 (2)
TRICYCLOHEXYLTIN COMPOUNDS with the exception Xn 20/21/22 (2-)26-28 Note A
of those specified elsewhere in this Annex
TRI(CYCLOHEXYL)TIN HYDROXIDE 13121-70-5 Xn 20/21/22 (2-)13
TRIDEMORPH 24602-86-6 Xn 21/22 (2-)25-36/37
TRIETHOXYISOBUTYLSILANE 17980-47-1 Xi 38 (2-)24
TRIETHYLAMINE 121-44-8 F,C 11-20/21/22-35 (1/2-)3-16-26-29-36/37/39-45
TRIETHYLENE GLYCOL DIACRYLATE 1680-21-3 Xi 36/38-43 (2-)26-28 Note D
TRIETHYLENETETRAMINE 112-24-3 C 21-34-43-52/53 (1/2-)26-36/37/39-45-61
TRIETHYL PHOSPHATE 78-40-0 Xn 22 (2-)25
TRIETHYLTIN COMPOUNDS with the exception of T+ 26/27/28 (1/2-)26-27-28-45 Note A
those specified elsewhere in this Annex
TRIFENMORPH 1420-06-0 Xn 22 (2-)22-24
TRIFLUOROACETIC ACID, conc.>10% 76-05-1 C 20-35 (1/2-)9-26-27-28-45 Note B
TRIFLUOROACETIC ACID, 1%£conc.<5% 76-05-1 Xi 36/38 23-26
I,I,I-TRIFLUOROTOLUENE 98-08-8 F,N 11-51/53 (2-)16-23-61
TRIFLURALINE (containing <0.5ppm NPDA) 1582-09-8 Xi 36-43 (2-)24-37
TRIHEXYLTIN COMPOUNDS with the exception of Xn 20/21/22 (2-)26-28 Note A
those specified elsewhere in this Annex
1,2,3-TRIHYDROXYBENZENE 87-66-1 Xn 20/21/22 (2)
TRILEAD BIS(ORTHOPHOSPHATE) 7446-27-7 T 61-62-33-48/22 53-45 Note E
TRIMELLITIC ANHYDRIDE 552-30-7 Xn 36/37/38-42 (2-)22-28
1,2,4-TRIMETHYLBENZENE 95-63-6 Xn 10-20-36/37/38 (2-)26
1,7,7-TRIMETHYLBICYCLO(2,2,1)HEPT-2-YL 115-31-1 Xn 22 (2-)24/25
THIOCYANATOACETATE
TRIMETHYLBORATE 121-43-7 Xn 10-21 (2-)23-25
3,5,5-TRIMETHYL-2-CYCLOHEXEN-1-ONE 78-59-1 Xi 36/37/38 (2-)26
TRIMETHYLENEDIAMINETETRAACETIC ACID 1939-36-2 Xn 22-36 (2-)22-26
2,2,4-TRIMETHYLHEXAMETHYLENE-1,6-DIISOCYANATE 16938-22-0 T 23-36/37/38-42 (1/2-)26-28-38-45 Note C
2,4,4-TRIMETHYLHEXAMETHYLENE-1,6- 15646-96-5
DIISOCYANATE and their mixtures
1,3a,8-TRIMETHYL-5-METHYLCARBAMOYLOXY- 57-47-6 T+ 26/28 (1/2-)-25-45
1,2,3,3a,8,8a-HEXAHYDROPIXIOLO[2,3-b]INDOL
TRIMETHYLOLPROPANE TRIACRYLATE 15625-89-5 Xi 36/38-43 (2-)39 Note D
2,4,4-TRIMETHYLPENT-1-ENE 107-39-1 F 11 (2-)9-16-29-33
TRIMETHYLTIN COMPOUNDS with the exception of T+ 26/27/28 (1/2-)26-27-28-45 Note A
those specified elsewhere in this Annex
2,4,6-TRIMETHYL-1,3,5-TRIOXAN 123-63-7 F 11 (2-)9-16-29-33
2,4,6-TRINITROANISOLE 606-35-3 E,Xn 2-20/21/22 (2-)35
TRINITROBENZENE 25377-32-6 E,T+ 2-26/27/28-33 (1/2-)35-45 Note C
TRINITROCRESOL 28905-71-7 E,Xn 2-4-20/21/22 (2-)35 Note C
2,4,6-TRINITROPHENOL 88-89-1 E,T 2-4-23/24/25 (1/2-)28-35-37-45
2,4,6-TRINITRORESOCINOL 82-71-3 E,Xn 2-4-20/21/22 (2-)35
2,4,6-TRINITROTOLUENE 118-96-7 E,T 2-23/24/25-33 (1/2-)35-45
43-50/53 (1/2-)36/37-45-60-61
TRINITROXYLENE (mix) 67297-26-1 E,Xn 2-20/21/22-33 (2-)35 Note C
8,9,10-TRINORBORN-5-ENE-DICARBOXYLIC 129-64-6 Xi 36/37/38 (2-)39
ANHYDRIDE
8,9,10-TRINORBORN-2-YL ACRYLATE 10027-06-2 Xn 21-38-43 (2-)28 Note D
TRIOCTYLTIN COMPOUNDS with the exception of Xi 36/37/38 (2) Note A
those specified elsewhere in this Annex
1,3,5-TRIOXAN 110-88-3 Xn 22 (2-)24/25
TRIOXYMETHYLENE 110-88-3 Xn 22 (2-)24/25
TRIPENTYLTIN COMPOUNDS with the exception of Xn 20/21/22 (2-)26-28 Note A
those specified elsewhere in this Annex
TRIPHENYL PHOSPHITE 101-02-0 Xi 36/38 (2-)28
TRIPHENYLTIN ACETATE 900-95-8 T+,N 24/25-26-36/37/38-
TRIPHENYLTIN COMPOUNDS with the exception of T 23/24/25 (1/2-)26-27-28-45 Note A
those specified elsewhere in this Annex
TRIPHENYLTIN HYDROXIDE 76-87-9 T+,N 24/25-26-36/38-50/53 (1/2-)36/37-45-60-61
TRIPROPYLTIN COMPOUNDS with the exception of T 23/24/25 (1/2-)26-27-28-45 Note A
those specified elsewhere in this Annex
TRIS(2-CHLOROETHYL) PHOSPHATE 115-96-8 Xn 22-36/38 (2)
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Substance CAS number Symbol Risk-phrases Safety phrases
(TRIS(CHLOROMETHYL)PHTHALOCYANINATO)COPPER(II), Xi 36 (2-)26
reaction products with N-METHYLPIPERAZINE
and METHOXYACETIC ACID
2,4,6-TRIS(DIMETHYLAMINOMETHYL)PHENOL 90-72-2 Xn 22-36/38 (2-)26-28
TRIS(DODECYL-3-METHYL-2- 7276-58-6 Xn 22 (2-)24
PHENYLBENZIMIDAZOLIUM)HEXACYANOFERRATE
N,N,N-TRIMETHYLANILINIUM CHLORIDE 138-24-9 T 24/25 (1/2-)25-39-45-53
1,3,5-TRIS(OXIRANYLMETHYL)-1,3,5-TRIAZINE- 2451-62-9 T 46-23/25-41-43-48/22- 53-45-61 Note E
2,4,6(1H,3H,5H)-TRIONE 52/53
TRITOLYL PHOSPHATE, o-o-o, o-o-m, o-o-p, T,N 39-23/24/25-51/53 (1/2-)20/21-28-45-61 Note C
o-m-m, o-m-p, o-p-p
TRIZINC DIPHOSPHIDE 1314-84-7 F,T+ 15/29-28-32 (1/2-)3/9/14-30-36/37-45
L TROPYL-TROPAT 101-31-5 T+ 26/28 (1/2-)-24-45
TRYPSIN 9002-07-7 Xn 36/37/38-42 (2-)22-24-26-36/37
TURPENTINE (mix) 8006-64-2 Xn 10-20/21/22 (2)
URANIUM 7440-61-1 T+ 26/28-33 (1/2-)20/21-45
URANIUM COMPOUNDS T+ 26/28-33 (1/2-)20/21-45 Note A
URETHANE 51-79-6 T 45 53-45
VALERIC ACID 109-52-4 C 34 (1/2-)26-36-45
VALINAMIDE 20108-78-5 Xi 36-43 (2-)24-26-37
VAMIDOTHION 2275-23-2 T,N 21-25-50 (1/2-)36/37-45-61
VANADINIUM PENTOXIDE 1314-62-1 Xn 20 (2-)22
VERATRINE 8051-02-3 Xi 36/37/38 (2-)36/37/39
VERNOLATE 1929-77-7 Xn 22 (2)
VINYL ACETATE 108-05-4 F 11 (2-)16-23-29-33 Note D
VINYL BROMIDE 593-60-2 F+,T 45-12 53-45
VINYL CHLORIDE 75-01-4 F+,T 45-12 53-45 Note D
VINYLCYCLOHEXANE DIEPOXIDE 106-87-6 T 23/24/25-40 (1/2-)23-24-45
VINYLIDENE CHLORIDE 75-35-4 F+,Xn 12-20-40 (2-)7-16-29 Note D
2-VINYLTOLUENE 611-15-4 Xn 20 (2-)24
WARFARIN 81-81-2 T 61-48/25 53-45 Note E
XENYLAMINE, SALTS T 45-22 53-45 Note A, E
XMC 2655-14-3 Xn 22 (2)
m-XYLENE 108-38-3 Xn 10-20/21-38 (2-)25 Note C
o-XYLENE 95-47-6 Xn 10-20/21-38 (2-)25 Note C
p-XYLENE 106-42-3 Xn 10-20/21-38 (2-)25 Note C
XYLENE, mixture of isomers 1330-20-7 Xn 10-20/21-38 (2-)25 Note C
XYLENOL, all isomers (mix) 1300-71-6 T 24/25-34 (1/2-)28-45 Note C
XYLIDINE T,N 23/24/25-33-51/53 (1/2-)28-36/37-45-61 Note C
XYLYLCARB 2425-10-7 Xn 22 (2)
3,5-XYLYL METHYLCARBAMATE 2655-14-3 Xn 22 (2)
ZINC ALKYLES F,C 14-17-34 (1/2-)16-43-45 Note A
ZINC BISDIMETHYLDITHIOCARBAMATE 137-30-4 Xn 22-36/37/38-40 (2-)36/37
ZINC CHLORIDE 7646-85-7 C 34 (1/2-)7/8-28-45
ZINC CHROMATES, including ZINC POTASSIUM T,N 45-22-43-50/53 53-45-60-61 Note A, E
CHROMATE
ZINC 2-HYDROXY-5-C13-18 ALKYLBENZOATE Xi,N 36/38-51/53 (2-)26-61
ZINC PHOSPHIDE 1314-84-7 T+,F 15/29-28-32 (1/2-)3/9/14-30-36/37-45
ZINC POWDER, ZINC DUST - 10-15 (2-)7/8-43
ZINC POWDER, ZINC DUST, PYROPHORIC 7440-66-6 F 15-17 (2-)7/8-43
ZINC SULPHATE 7733-02-0 Xi 36/38 (2-)22-25
ZIRAM 137-30-4 Xn 22-36/37/38-40 (2-)36/37
ZIRCONIUM POWDER, STABILIZED - 15 (2-)7/8-43
ZIRCONIUM POWDER, PYROPHORIC 7740-67-7 F 15-17 (2-)7/8-43
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