GOODS REQUIRING SUPERVISION

ANNEX 3. GOODS REQUIRING SUPERVISION Compiled from the European Agreement concerning the international carriage of dangerous goods by road (ADR). The lists of goods and substances in different classes presented below are not comprehensive. Transport units carrying dangerous goods in quantities above the values indicated should be supervised or, alternatively, may be parked unsupervised in an isolated location in the open at a secure depot or factory premises.
Class	Goods	Weight requiring surveillance	Nature of surveillance
1. Explosives:	All explosive loads	over 50 kg	all the time
2. Gases:	Boron trifluoride and fluorine	1000 kg	limited
Toxic or corrosive:	Ammonia, chlorine, chlorine trifluoride, hydrogen bromide, hydrogen chloride, methyl bromide, nitrogen oxides, phosgene, sulphur dioxide, tungsten hexafluoride	1000 kg	limited
Toxic and flammable:	Arsine, dichlorosilane, dimethylamine, dimethylsilane, ethylamine, hydrogen selenide, hydrogen sulphide, methylamine, methyl chloride, methyl mercaptan	1000 kg	limited
Chemically unstable, toxic:	Cyanogen, cyanogen chloride, ethylene oxide, hydrogen iodide (anhydrous), methyl vinyl ether, trifluorochloroethylene (R113), vinyl bromide	1000 kg	limited
	Ethyl chloride	10 000 kg	limited
Chemically unstable:	1,2-butadiene, 1,3-butadiene, vinyl chloride	10 000 kg	limited
Deeply-refrigerated (cryogenic) liquified:	Argon, carbon dioxide, helium, nitrous oxide (N2O), oxygen	1000 kg	limited
Deeply-refrigerated (cryogenic) liquified, flammable:	Ethane, ethylene, natural gas	10 000 kg	limited
3. Flammable liquids:
Flash point below 21°C, not toxic:	Acetaldehyde, vinylidene chloride, methyl isopropyl ether, methyl formate, isopentane, ethyl ether, isoprene, propylene oxide, normal pentane, petroleum ether, benzene, cyclohexane, ethylbenzene(techn.), hexanes, octanes, toluene, propylene dichloride, isopropanol, acetone, methyl ethyl ketone, ethyl acetate, methyl acetate, vinyl acetate, ethyl acrylate, methyl methacrylate, propyl mercaptan, thiophene, solutions containing nitrocellulose 20%-55%,	10 000 kg	limited
	solutions of 1%-5% nitroglycerine	5000 kg	limited
Flash point below 21°C, toxic:	Acrylonitrile, acetonitrile, ethyleneimine, methyl isocyanate, allylamine, 1,2-dimethylhydrazine, pyridine, chloroprene, allyl chloride, 1,2-dichloroethane, acrolein, methanol, carbon disulphide, ethyl mercaptan, some pesticides	5000 kg	limited
Flash point below 21°C, corrosive	Some chlorosilanes, isopropylamine, n-propylamine, aqueous solutions (having a boiling point less than 35°C) of dimethylamine and of ethylamine, 1,1-dimethylhydrazine, sodium methylate, acetyl chloride	10 000 kg	limited
4.1 Flammable solids:
Explosive substances in the non-explosive state		1000 kg	limited
	Musk xylene (UN No 2959)	100 kg	limited
Self-reactive substances	only UN No 2951, 2954, 2970, 2971, 2972, 2973, 3033, 3034, 3040, 3041, 3042, 3043	1000 kg	limited
Self-reactive substance	Azonium zinc chlorides (UN No 3035-3039)	100 kg	limited
Self-reactive substances	Valeronitriles (UN No 2953 and 2955)		all the time
4.2 Substances liable to spontaneous combustion:	Pyrophoric organic or inorganic solid n.o.s. (UN No 2846), pyrophoric organic or inorganic liquid n.o.s. (UN No 2845), white or yellow phosphorus, calcium (pyrophoric), dry metal catalyst, titanium trichloride (pyrophoric), aluminium borohydride, diethylzinc, magnesium diphenyl, metal alkyls n.o.s., metal alkyl halides n.o.s., metal alkyl hydrides n.o.s.	10 000 kg	limited
4.3 Substances which in contact with water emit flammable gases:	Ethyldichlorosilane, trichlorosilane, methyl magnesium bromide in ethyl ether, alkalimetal amalgams, potassium sodium alloys, sodium, zinc powder, calcium hydride, aluminium hydride, lithium nitride, sodium phosphide, magnesium phosphide, and their empty packagings	10 000 kg	limited
5.1 Oxidizing substances:	Aqueous solutions with more than 60% hydrogen peroxide (stabilized), perchloric acid, bromine pentafluoride, bromine trifluoride, iodine pentafluoride, potassium peroxide, sodium peroxide, oxidizing solid or liquid, toxic or corrosive n.o.s.	10 000 kg	limited
5.2 Organic peroxides:
	UN No 3111 and 3112 type B	500 kg	all the time
	UN No 3101 and 3102 type B, UN No 3113 and 3114 type C	1000 kg	limited
	UN No 3103 and 3104 type C UN No 3115 and 3116 type D	2000 kg	limited
	UN No 3105 and 3106 type D, 3117 and 3118 type E	5000 kg	limited
6.1 Toxic substances:
Highly toxic, flash point below 21°C	Hydrocyanic acid (completely absorbed by an inert porous substance or in the liquid state), solution of hydrocyanic acid which meet the given criteria, iron pentacarbonyl, nickel tetracarbonyl	1000 kg	limited
Highly toxic, flash point 21°C or more	Acetone cyanohydrin, allyl alcohol, dimethyl sulphate, chloropicrin, thiophenol	1000 kg	limited
Highly toxic, in contact with water or acids emit toxic gases	Solid cyanides or complex cyanides and their solutions, aluminium phosphide, magnesium phosphide	1000 kg	limited
Highly toxic	Liquid arsenical compounds, arsenic trichloride, selenates, selenites, osmium tetroxide, tetraethyl lead, tetramethyl lead	1000 kg	limited
Highly toxic, used as pesticides, rodenticides	Demphion, Demeton, Demeton-O, Dimefox, Disulfoton, EPN, Ethopropos, Fenamiphos, Fensulfothion, Fonofos, Mephosfolan, Mevinphos, Oxydisulfoton, Paraoxon, Parathion, Phorate, Pyraoxon, TEPP, Trebufos, Thionazin, Endrin, Isobenzan, Cycloheximide, Aldicarb, Promurit, Strychnine, Brodifacoum, Chlorophacinone, ANTU, Norbormide	1000 kg	limited
Toxic, flash point 21°C or more	Aniline, benzonitrile, N,N-dimethylaniline, chloronitrobenzenes, dinitroanilines, dinitrotoluenes, nitrobenzene, phenylhydrazine, toluidines, xylidines, aldol, phenol, benzoquinone, cresols, diethyl sulphate, xylenols, ethyl bromide, chloroform, chloral, carbon tetrachloride, trichlorobutene, cyclohexyl isocyanate, phenyl isocyanate, 2,4-toluylene di-isocyanate, 3,4-dichlorophenyl isocyanate, tosyl isocyanate, thioglycol, triethyl phosphine, triethylene phophoramide, benzoyl cyanide	5000 kg	limited
Toxic, in contact with water or acids, emit toxic gases	Sodium azide, zinc phosphide	5000 kg	limited
Toxic	Dibutyl tin chloride, arsenic trichloride, arsenic pentoxide, various arsenites, mercuric acetate, mercuric chloride, mercury nitrates, selenium disulphide, selenium dioxide, vanadates	5000 kg	limited
Toxic, used as pesticides, rodenticides	Chlorfenvinphos, Chlormephos, Demeton-S-methyl, Dialifos, Dichlorvos, Dicrotophos, Dioxathion, Endothion, Ethion, Mecarbam, Methamidophos, Methidathion, Monocrotophos, Oxydemeton-methyl, Parathion-methyl, Phospholan, Phosphamidon, Propaphos, Schradan, Sulfotep, Triamiphos, Trichloronat, Aldrin, Dieldrin, Endosulfan, Heptachlor, Isodrin, Pentachlorophenol, Dinoseb, Dinoterb, DNOC, Aminocarb, Carbofuran, Dimetilan, Formetanate, Isolan, Mercaptodimethur, Methomyl, Mexacarbate, Oxamyl, PMA, Chloro-methoxyethyl mercury, Coumaphos, Coumatetralyl, Paraquat	5000 kg	limited
7. Radioactive substances:			all the time
8. Corrosive substances:	Bromine	1000 kg	limited
Highly corrosive	Chromosulphuric acid, sulphur trioxide, oleum, red fuming nitric acid, mixtures of sulphuric acid with more than 30% of nitric acid, aqueous solutions (60-85%) of hydrofluoric acid, selenic acid, chlorosulphonic acid, chromyl chloride, disulphur dichloride, sulphuryl chloride, thionyl chloride, sulphur dichloride, boron bromide, trifluoracetic acid, aqueous solutions (more than 64%) of hydrazine, allyl chloroformate, benzyl chloroformate	10 000 kg	limited
9. Miscellaneous:		5000 kg	limited
Substances which, on inhalation as fine dust, may endanger health	Crocidolite, amosite
Substances and apparatures which in event of fire may form dioxins	PCB, PTB and their mixtures (over 50 mg/kg)
Table of contents

Updated by AS. Approved by EC. Last update: 30.11.2004.

ANNEX 3.