 |
ANNEX 7.
Substances and Quantities Potential to Cause Major Accidents |
|
No. |
Major hazard substance |
Quantity |
CAS No. |
|
1 |
4-AMINODIPHENYL |
1kg |
92-67-1 |
|
2 |
BENZIDINE |
1kg |
92-87-5 |
|
3 |
BENZIDINE AND SALTS |
1kg |
|
|
4 |
DIMETHYLNITROSAMINE |
1kg |
62-75-9 |
|
5 |
2-NAPHTHYLAMINE |
1kg |
91-59-8 |
|
6 |
BERYLLIUM (powders, compounds) |
10kg |
7440-41-7 |
|
7 |
BIS(CHLOROMETHYL)ETHER |
1kg |
542-88-1 |
|
8 |
1,3-PROPANESULTONE |
1kg |
1120-71-4 |
|
9 |
2,3,7,8-TETRACHLORODIBENZO-P-DIOXIN |
1kg |
1746-01-6 |
|
10 |
ARSENIC PENTOXIDE, ARSENIC(V)ACID and SALTS |
500kg |
1303-28-2 |
|
11 |
ARSENIC TRIOXIDE, ARSENIOUS(III)ACIDS and SALTS |
100kg |
1327-53-3 |
|
12 |
ARSENIC HYDRIDE (ARSINE) |
10kg |
7784-42-1 |
|
13 |
DIMETHYLCARBAMOYL CHLORIDE |
1kg |
79-44-7 |
|
14 |
4-(CHLOROFORMYL) MORPHOLINE |
1kg |
15159-40-7 |
|
15 |
CARBONYL CHLORIDE (PHOSGENE) |
750kg |
75-44-5 |
|
16 |
CHLORINE |
25t |
7782-50-5 |
|
17 |
HYDROGEN SULPHIDE |
50t |
7783-06-4 |
|
18 |
ACRYLONITRILE |
200t |
107-13-1 |
|
19 |
HYDROGEN CYANIDE |
20t |
74-90-8 |
|
20 |
CARBON DISULFIDE |
200t |
75-15-0 |
|
21 |
BROMINE |
500t |
7726-95-6 |
|
22 |
AMMONIA |
500t |
7664-41-7 |
|
23 |
ACETYLENE (ETHYNE) |
50t |
74-86-2 |
|
24 |
HYDROGEN |
50t |
1333-74-0 |
|
25 |
ETHYLENE OXIDE |
50t |
75-21-8 |
|
26 |
PROPYLENE OXIDE |
50t |
75-56-9 |
|
27 |
2-CYANOPROPAN-2-OL (ACETONE CYANOHYDRIN) |
200t |
75-56-9 |
|
28 |
2-PROPENAL (ACROLEIN) |
200t |
107-02-8 |
|
29 |
2-PROPEN-1-OL (ALLYL ALCOHOL) |
200t |
107-18-6 |
|
30 |
ALLYLAMINE |
200t |
107-11-9 |
|
31 |
ANTIMONY HYDRIDE (STIBINE) |
100kg |
7803-52-3 |
|
32 |
ETHYLENEIMINE |
50t |
151-56-4 |
|
33 |
FORMALDEHYDE (CONCENTRATION= 90%) |
50t |
50-00-0 |
|
34 |
HYDROGEN PHOSPHIDE (PHOSPHINE) |
100kg |
7803-51-2 |
|
35 |
BROMOMETHANE (METHYL BROMIDE) |
200t |
74-83-9 |
|
36 |
METHYL ISOCYANATE |
150kg |
624-83-9 |
|
37 |
NITROGEN OXIDES |
50t |
11104-93-1 |
|
38 |
SODIUM SELENITE |
100kg |
10102-18-8 |
|
39 |
BIS(2-CHLOROETHYL) SULPHIDE |
1kg |
505-60-2 |
|
40 |
PHOSACETIM |
100kg |
4104-14-7 |
|
41 |
TETRAETHYL LEAD |
50t |
78-00-2 |
|
42 |
TETRAMETHYL LEAD |
50t |
75-74-1 |
|
43 |
PROMURIT ( 1-(3,4-DICHLOROPHENYL)- 3-TRIAZENETHIOCARBOXAMIDE ) |
100kg |
5836-73-7 |
|
44 |
CHLORFENVINPHOS |
100kg |
470-90-6 |
|
45 |
CRIMIDINE |
100kg |
535-89-7 |
|
46 |
CHLOROMETHYL METHYL ETHER |
1kg |
107-30-2 |
|
47 |
DIMETHYL PHOSPHORAMIDOCYANIDIC ACID |
1t |
63917-41-9 |
|
48 |
CARBONPHENOTHION |
100kg |
786-19-6 |
|
49 |
DIALIFOS |
100kg |
10311-84-9 |
|
50 |
CYANTHOATE |
100kg |
3734-95-0 |
|
51 |
AMITON |
1kg |
78-53-5 |
|
52 |
OXYDISULFOTON |
100kg |
2497-07-6 |
|
53 |
OO-DIETHYL S-ETHYLSULPHINYLMETHYL PHOSPHOROTHIOATE |
100kg |
2588-05-8 |
|
54 |
OO-DIETHYL S-ETHYLSULPHONYLMETHYL PHOSPHOROTHIOATE |
100kg |
2588-06-9 |
|
55 |
DISULFOTON |
100kg |
298-04-4 |
|
56 |
DEMETON |
100kg |
8065-48-3 |
|
57 |
PHORATE |
100kg |
298-02-2 |
|
58 |
OO-DIETHYL S-ETHYLTHIOMETHYL PHOSPHOROTHIOATE |
100kg |
2600-69-3 |
|
59 |
OO-DIETHYL S-ISOPROPYLTHIOMETHYL PHOSPHORODITHIOATE |
100kg |
78-52-4 |
|
60 |
PYRAZOXON |
100kg |
108-34-9 |
|
61 |
PENSULFOTHION |
100kg |
115-90-2 |
|
62 |
PARAOXON (DIETHYL 4-NITROPHENYLPHOSPHATE) |
100kg |
311-45-5 |
|
63 |
PARATHION |
100kg |
56-38-2 |
|
64 |
AZINPHOS-ETHYL |
100kg |
2642-71-9 |
|
65 |
OO-DIETHYL S-PROPYLTHIOMETHYL PHOSPHORODITHIOATE |
100kg |
3309-68-0 |
|
66 |
THIONAZIN |
100kg |
297-97-2 |
|
67 |
CARBOFURAN |
100kg |
1563-66-2 |
|
68 |
PHOSPHAMIDON |
100kg |
13171-21-6 |
|
69 |
TIRPATE(2,4-DIMETHYL-1,3-DITHIOLANE- 2-CARBOXALDEHYDEO-METHYLCARBAMOYLOXIME) |
100kg |
26419-73-8 |
|
70 |
MEVINPHOS |
100kg |
7786-34-7 |
|
71 |
PARATHION-METHYL |
100kg |
298-00-0 |
|
72 |
AZINPHOS-METHYL |
100kg |
86-50-0 |
|
73 |
CYCLOHEXIMIDE |
100kg |
66-81-9 |
|
74 |
DIPHACINONE |
100kg |
82-66-6 |
|
75 |
TETRAMETHYLENEDISULPHOTETRAMINE |
1kg |
80-12-6 |
|
76 |
EPN |
100kg |
2104-64-5 |
|
77 |
4-FLUOROBUTYRIC ACID |
1kg |
462-23-7 |
|
78 |
4-FLUOROBUTYRIC ACID, SALTS |
1kg |
|
|
79 |
4-FLUOROBUTYRIC ACID, ESTERS |
1kg |
|
|
80 |
4-FLUOROBUTYRIC ACID, AMIDES |
1kg |
|
|
81 |
4-FLUOROCROTONIC ACID |
1kg |
37759-72-1 |
|
82 |
4-FLUOROCROTONIC ACID, SALTS |
1kg |
|
|
83 |
4-FLUOROCROTONIC ACID, ESTERS |
1kg |
|
|
84 |
4-FLUOROCROTONIC ACID, AMIDES |
1kg |
|
|
85 |
FLUOROACETIC ACID |
1kg |
144-49-0 |
|
86 |
FLUOROACETIC ACID, SALTS |
1kg |
|
|
87 |
FLUOROACETIC ACID, ESTERS |
1kg |
|
|
88 |
FLUOROACETIC ACID, AMIDES |
1kg |
|
|
89 |
FLUENETIL |
100kg |
4301-50-2 |
|
90 |
4-FLUORO-2-HYDROXYBUTYRIC ACID |
1kg |
|
|
91 |
4-FLUORO-2-HYDROXYBUTYRIC ACID, SALTS |
1kg |
|
|
92 |
4-FLUORO-2-HYDROXYBUTYRIC ACID, ESTERS |
1kg |
|
|
93 |
4-FLUORO-2-HYDROXYBUTYRIC ACID, AMIDES |
1kg |
|
|
94 |
HYDROGEN FLUORIDE |
50t |
7664-39-3 |
|
95 |
HYDROXYACETONITRILE (GLYCOLONITRILE) |
100kg |
107-16-4 |
|
96 |
1,2,3,7,8,9-HEXACHLORODIBENZO-P-DIOXIN |
100kg |
19408-74-3 |
|
97 |
ISODRIN |
100kg |
465-73-6 |
|
98 |
HEXAMETHYLPHOSPHOROAMIDE |
1kg |
680-31-9 |
|
99 |
JUGLONE (5-HYDROXYNAPHTHALENE-1,4-DIONE) |
100kg |
481-39-0 |
|
100 |
WARFARIN |
100kg |
81-81-2 |
|
101 |
4,4'-METHYLENEBIS(2-CHLOROANILINE) |
10kg |
101-14-4 |
|
102 |
ETHION |
100kg |
563-12-2 |
|
103 |
ALDICARB |
100kg |
116-06-3 |
|
104 |
NICKEL TETRACARBONYL |
10kg |
13463-39-3 |
|
105 |
ISOBENZAN |
100kg |
297-78-9 |
|
106 |
PENTABORANE |
100kg |
19624-22-7 |
|
107 |
1-PROPEN-2-CHLORO-1,3-DIOL-DIACETATE |
10kg |
10118-77-6 |
|
108 |
PROPYLENEIMINE |
50t |
75-55-8 |
|
109 |
OXYGEN DIFLUORIDE |
10kg |
7783-41-7 |
|
110 |
SULPHUR DICHLORIDE |
1t |
10545-99-0 |
|
111 |
SELENIUM HEXAFLUORIDE |
10kg |
7783-79-1 |
|
112 |
HYDROGEN SELENIDE |
10kg |
7783-07-5 |
|
113 |
TEPP |
100kg |
107-49-3 |
|
114 |
SULFOTEPP |
100kg |
3689-24-5 |
|
115 |
DIMEFOX |
100kg |
115-26-4 |
|
116 |
1-TRI(CYCLOHEXYL)STANNYL-1H-1,2,4-TRIAZOLE |
100kg |
41083-11-8 |
|
117 |
TRIETHYLENEMELAMINE |
10kg |
51-18-3 |
|
118 |
COBALT METAL, OXIDES, CARBONATES, SULPHIDES, as powders |
1t |
7440-48-4 |
|
119 |
NICKEL METAL, OXIDES, CARBONATES, SULPHIDES, as powders |
1t |
7440-02-0 |
|
120 |
ANABASINE |
100kg |
494-52-0 |
|
121 |
TELLURIUM HEXAFLUORIDE |
100kg |
7783-80-4 |
|
122 |
TRICHLOROMETHANESULPHENYL CHLORIDE |
100kg |
594-42-3 |
|
123 |
1,2-DIBROMOETHANE (ETHYLENE DIBROMIDE) |
50t |
106-93-4 |
|
124 |
FLAMMABLE SUBSTANCES as defined in 82/501/EEC Annex IV(c)(i) |
200t |
|
|
125 |
FLAMMABLE SUBSTANCES as defined in 82/501/EEC Annex IV(c)(ii) |
50 000t |
|
|
126 |
DIAZODINITROPHENOL |
10t |
87-31-0 |
|
127 |
DIETHYLENE GLYCOL DINITRATE |
10t |
693-21-0 |
|
128 |
DINITROPHENOL, SALTS |
50t |
|
|
129 |
1-GUANYL-4-NITROSAMINOGUANYL-1-TETRAZENE |
10t |
109-27-3 |
|
130 |
BIS(2,4,6-TRINITROPHENYL)AMINE |
50t |
131-73-7 |
|
131 |
HYDRAZINE NITRATE |
50t |
13464-97-6 |
|
132 |
NITROGLYCERIN |
10t |
55-63-0 |
|
133 |
PENTAERYTHRITOL TETRANITRATE |
50t |
78-11-5 |
|
134 |
CYCLOTRIMETHYLENE TRINITRAMINE |
50t |
121-82-4 |
|
135 |
TRINITROANILINE |
50t |
29652-12-1 |
|
136 |
2,4,6-TRINITROANISOLE |
50t |
606-35-9 |
|
137 |
TRINITROBENZENE |
50t |
99-35-4 |
|
138 |
TRINITROBENZOIC ACID |
50t |
35860-50-5; 129-66-8 |
|
139 |
CHLOROTRINITROBENZENE |
50t |
28260-61-9 |
|
140 |
N-METHYL-N,2,4,6-TETRANITROANILINE |
50t |
479-45-8 |
|
141 |
2,4,6-TRINITROPHENOL (PICRIC ACID) |
50t |
88-89-1 |
|
142 |
TRINITROCRESOL |
50t |
28905-71-7 |
|
143 |
2,4,6-TRINITROPHENETOLE |
50t |
4732-14-3 |
|
144 |
2,4,6-TRINITRORESORCINOL (STYPHNIC ACID) |
50t |
82-71-3 |
|
145 |
2,4,6-TRINITROTOLUENE |
50t |
118-96-7 |
|
146 |
(a) AMMONIUM NITRATES1
(b) AMMONIUM NITRATES IN THE FORM OF FERTILISERS2 |
2 500t
10 000t |
6484-52-2 |
|
147 |
NITROCELLULOSE (containing > 12,6% of NITROGEN) |
100t |
9004-70-0 |
|
148 |
SULPHUR DIOXIDE |
250t |
7446-09-5 |
|
149 |
HYDROGEN CHLORIDE (LIQUIFIED GAS) |
250t |
7647-01-0 |
|
150 |
FLAMMABLE SUBSTANCES as defined in 82/501/EEC Annex IV(c)(iii) |
200t |
|
|
151 |
SODIUM CHLORATE |
250t |
7775-09-9 |
|
152 |
tert-BUTYL PEROXYACETATE (concentration 70%) |
50t |
107-71-7 |
|
153 |
tert-BUTYL PEROXYISOBUTYRATE (concentration 80%) |
50t |
109-13-7 |
|
154 |
tert-BUTYL PEROXYMALEATE (concentration 80%) |
50t |
1931-62-0 |
|
155 |
trt-BUTYL PEROXY ISOPROPYL CARBONATE (concentration 80%) |
50t |
2372-21-6 |
|
156 |
IBENZYL PEROXYDICARBONATE (concentration 90%) |
50t |
2144-45-8 |
|
157 |
2,2-BIS(tert-BUTYLPEROXY)BUTANE (concentration 70%) |
50t |
2167-23-9 |
|
158 |
1,1-BIS(tert-BUTYLPEROXY)CYCLOHEXANE (concentration 80%) |
50t |
3006-86-8 |
|
159 |
DI-sec-BUTYL PEROXYDICARBONATE (concentration 80%) |
50t |
19910-65-7 |
|
160 |
2,2-DIHYDROPEROXYPROPANE (concentration 30%) |
50t |
2614-76-8 |
|
161 |
DI-N-PROPYL PEROXYDICARBONATE (concentration 80%) |
50t |
16066-38-9 |
|
162 |
3,3,6,6,9,9-HEXAMETHYL- 1,2,4,5-TETROXACYCLONONANE (concentration 75%) |
50t |
22397-33-7 |
|
163 |
METHYL ETHYL KETONE PEROXIDE (concentration 60%) |
50t |
1338-23-4 |
|
164 |
METHYL ISOBUTYL KETONE PEROXIDE (concentration 60%) |
50t |
37206-20-5 |
|
165 |
PERACETIC ACID (concentration 60%) |
50t |
79-21-0 |
|
166 |
LEAD AZIDE |
50t |
13424-46-9 |
|
167 |
LEAD 2,4,6-TRINITRORESORCINOXIDE LEAD STYPHNATE) |
50t |
63918-97-8 |
|
168 |
MERCURY FULMINATE |
10t |
20820-45-5; 628-86-4 |
|
169 |
CYCLOTETRAMETHYLENETETRANITRAMINE |
50t |
2691-41-0 |
|
170 |
2,2',4,4',6,6'-HEXANITROSTILBENE |
50t |
20062-22-0 |
|
171 |
1,3,5-TRIAMINO-2,4,6-TRINITROBENZENE |
50t |
3058-38-6 |
|
172 |
ETHYLENE GLYCOL DINITRATE |
10t |
628-96-6 |
|
173 |
ETHYL NITRATE |
50t |
625-58-1 |
|
174 |
SODIUM PICRAMATE |
50t |
831-52-7 |
|
175 |
BARIUM AZIDE |
50t |
18810-58-7 |
|
176 |
DI-ISOBUTYL PEROXIDE (concentration 50%) |
50t |
3437-84-1 |
|
177 |
DIETHYL PEROXYDICARBONATE (concentration 30%) |
50t |
14666-78-5 |
|
178 |
tert-BUTYL PEROXYPIVALATE (concentration 77%) |
50t |
927-07-2 |
|
179 |
LIQUID OXYGEN |
2 000t |
7782-44-7 |
|
180 |
SULFUR TRIOXIDE |
100t |
7446-11-9 |
|
1This applies to ammonium nitrate and mixtures of ammonium nitrate where the nitrogen content derived from ammonium nitrate is >28% by weight, and to aqueous solutions with concentration more than 90% of ammonium nitrate
2This applies to ammonium nitrate fertilizers (defined in Directive 80/876/EEC) and to compound fertilizers where the nitrogen content derived from ammonium nitrate is >28% by weight. The compound fertilizer may contain also other fertilizing agents, such as phosphate and potash.
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Table of contents |
