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Page No. 1 \wp51\stt\ipcs\18 November 1996
Classification using Risk- and Safety Phrases
Substance CAS number Symbol Risk-phrases Safety phrases
ACEPHATE 30560-19-1 Xn 22 (2)-36
ACETAL 105-57-7 F,Xi 11-36/38 (2-)9-16-33
ACETALDEHYDE 75-07-0 F+,Xn 12-36/37-40 (2-)16-33-36/37
ACETAMIDE 60-35-5 Xn 40 (2-)36/37
ACETIC ACID, conc.>90% 64-19-7 C 10-35 (1/2-)23-26-45 Note B
ACETIC ACID, conc. 25%-90% C 34 (1/2-)23-26-45 Note B
ACETIC ANHYDRIDE 108-24-7 C 10-34 (1/2-)26-45
ACETONE 67-64-1 F 11 (2-)9-16-23-33
ACETONE CYANOHYDRIN 75-86-5 T+,N 26/27/28-50 (1/2-)7/9-27-45-61
ACETONITRILE 75-05-8 F,T 11-23/24/25 (1/2-)16-27-45
ACETOPHENONE 98-86-2 Xn 22-36 (2-)26
ACETYLACETONE 123-54-3 Xn 10-22 (2-)21-23-24/25
ACETYL CHLORIDE 75-36-5 F,C 11-14-34 (1/2-)9-16-26-45
ACETYLENE 74-86-2 F+ 5-6-12 (2-)9-16-33
3-ACETYL-6-METHYL-2H-PYRAN-2,4(3H)-DIONE 520-45-6 Xn 22 (2)
ACLONIFEN 74070-46-5 N 50/53 60-61
ACONITINE 302-27-2 T+ 26/28 (1/2-)24-45
ACONITINE, SALTS T+ 26/28 (1/2-)24-45 Note A
ACROLEIN 107-02-8 F,T+ 11-25-26-34 (1/2-)3/9/14-26-36/37/39-38-45
ACRYLALDEHYDE 107-02-8 F,T+ 11-25-26-34 (1/2-)3/9/14-26-36/37/39-38-45
ACRYLAMIDE 79-06-1 T 45-46-24/25-48/23/24/25 53-45 Note D, E
ACRYLATES, with the exception of those Xi 36/37/38 (2-)26-28
specified elsewhere in this Annex, conc.³10%
ACRYLIC ACID 79-10-7 C 10-34 (1/2-)26-36-45 Note D
ACRYLONITRILE 107-13-1 F,T 45-11-23/24/25-38 53-45 Note D, E
ADIPIC ACID 124-04-9 Xi 36 (2)
ADZN 78-67-1 E,Xn 2-11-20/22 (2-)39-41-47
ALACHLOR 15972-60-8 Xn 22-40-43 (2-)36/37/39
ALDICARB 116-06-3 T+ 27/28 (1/2-)22-36/37-45
ALDRIN 309-00-2 T,N 24/25-40-48/24/25-50/53 (1/2-)22-36/37-45-60-61
ALLETHRIN 584-79-2 Xn 22 (2-)36
ALLIDOCHLOR 93-71-0 Xn 21/22-36/38 (2-)26-28-36/37/39
ALLYL ALCOHOL 107-18-6 T,N 10-23/24/25-36/37/38-50 (1/2-)36/37/39-38-45-61
ALLYLAMINE 107-11-9 F,T,N 11-23/24/25-51/53 (1/2-)9-16-24/25-45-61
5-ALLYL-1,3-BENZODIOXOLE 94-59-7 T 45-22-40 53-45 Note E
ALLYL CHLORIDE 107-05-1 F,T+,N 11-26-50 (1/2-)16-29-33-45-61 Note D
ALLYL 2,3-EPOXYPROPYL ETHER 106-92-3 Xn 20-43 (2-)24/25
ALLYL GLYCIDYL ETHER 106-92-3 Xn 20-43 (2-)24/25
ALLYL IODIDE 556-56-9 C 10-34 (1/2-)7-26-45
ALUMINIUM, ALKYLS F,C 14-17-34 (1/2-)16-43-45 Note A
ALUMINIUM CHLORIDE, anhydrous 7446-70-0 C 34 (1/2-)7/8-28-45
ALUMINIUM LITHIUM HYDRIDE 16853-85-3 F 15 (2-)7/8-24/25-43
ALUMINIUM PHOSPHIDE 20859-73-8 F,T+ 15/29-28-32 (1/2-)3/9/14-30-36/37-45
ALUMINIUM POWDER, PYROPHORIC 7429-90-5 F 15-17 (2-)7/8-43
ALUMINIUM POWDER, STABILIZED - 10-15 (2-)7/8-43
ALUMINIUM-TRI-ISOPROPOXIDE 555-31-7 F 11 (2-)8-16
AMETRYN 834-12-8 Xn 22 (2-)36
AMIDITHION 919-76-6 Xn 22 (2-)24-36
AMINES, POLYETHYLENEPOLY- 68131-73-7 C,N 21/22-34-43-50/53 (1/2-)26-36/37/39-45-60-61
4-AMINOAZOBENZENE 60-09-3 T 45 53-45
o-AMINOAZOTOLUENE 97-56-3 T 45-43 53-45
3-AMINOBENZENE SULPHONIC ACID 121-47-1 Xn 20/21/22 (2-)25-28
4-AMINOBENZENE SULPHONIC ACID 121-57-3 Xi 36/38-43 (2-)24-37
4-AMINOBIPHENYL 92-67-1 T 45-22 53-45 Note E
4-AMINOBIPHENYL, SALTS T 45-22 53-45 Note A, E
1-AMINOBUTANE 109-73-9 F,C 11-20/21/22-35 (1/2-)3-16-26-29-36/37/39-45
2-AMINOBUTANE 13952-84-6 F,C,N 11-20/22-35-50 (1/2-)9-16-26-28-36/37/39-45-61
AMINOCARB 2032-59-9 T 24/25 (1/2-)28-36/37-45
5-AMINO-4-CHLORO-2-PHENYLPYRIDAZIN-3(2H)-ONE 1698-60-8 Xi 43 (2-)24-37
4-AMINO-N,N-DIETHYLANILINE 93-05-0 T 25-34 (1/2-)26-36-45
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Substance CAS number Symbol Risk-phrases Safety phrases
3-AMINO-N,N'-DIMETHYLANILINE 2836-04-6 T 23/24/25 (1/2-)28-45 Note C
4-AMINO-N,N-DIMETHYLANILINE 99-98-9 T 23/24/25 (1/2-)28-45 Note C
4-AMINO-2',3-DIMETHYLAZOBENZENE 97-56-3 T 45-43 53-45
2-AMINO-4,6-DINITROPHENOL 96-91-3 E,Xn 1-20/21/22-52/53 (2-)35-61
2-AMINOETHANOL 141-43-5 Xn 20-36/37/38 (2)
2-AMINOETHYLDIMETHYLAMINE 108-00-9 F,C 11-21/22-35 (1/2-)16-23-26-28-36-45
4-AMINO-3-FLUOROPHENOL 399-95-1 T,N 45-22-43-51/53 53-45-61 Note E
2-AMINO-2-METHYLPROPANOL 124-68-5 Xi 36/38 (2)
3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE 2855-13-2 C 21/22-34-43-52/53 (1/2-)26-36/37/39-45-61
2-AMINOPHENOL 95-55-6 Xn 20/22-40 (2-)28-36/37
5-AMINO-PHENYL-1,2,4-TRIAZOL-1-YL-N,N,N',N'- 1031-47-6 T+ 27/28 (1/2-)22-28-36/37-45
TETRAMETHYL PHOSPHONIC DIAMIDE
2-AMINOPROPANE 75-31-0 F+,Xi 12-36/37/38 (2-)16-26-29
1-AMINOPROPAN-2-OL 78-96-6 C 34 (1/2-)23-26-36-45
3-AMINOPROPYLDIETHYLAMINE 104-78-9 C 10-21/22-34-43 (1/2-)26-36/37/39-45
3-AMINOPROPYLDIMETHYLAMINE 109-55-7 C 10-22-34-43 (1/2-)26-36/37/39-45
3-AMINOPROPYLTRIETHOXYSILANE 919-30-2 C 22-34 (1/2-)26-36/37/39-45
2-AMINOTOLUENE 95-53-4 T,N 45-23/25-36-50 53-45-61 Note E
AMITRAZ 33089-61-1 Xn 22 (2-)22
AMITROLE 61-82-5 Xn,N 40-48/22-51/53 (2-)36-37-61
AMMONIA, anhydrous 7664-41-7 T,N 10-23-34-50 (1/2-)9-16-26-36/37/39-45-61
AMMONIA SOLUTION conc.³25% 1336-21-6 C,N 34-50 (1/2-)26-36/37/39-45-61 Note B
AMMONIA SOLUTION 5%£conc.<10% 1336-21-6 Xi 36/37/38 (2-)7-26 Note B
AMMONIUM BIFLUORIDE 1341-49-7 T,C 25-34 (1/2-)22-26-37-45
AMMONIUM BIS(2,4,6-TRINITROPHENYL)AMINE 2844-92-0 E,T+,N 1-26/27/28-33-51/53 (1/2-)28-36/37-45-61
AMMONIUM CHLORIDE 12125-02-9 Xn 22-36 (2-)22
AMMONIUM DICHROMATE 7789-09-5 E,T+,N 49-46-1-8-21-25-26- 53-45-60-61 Note E
37/38-41-43-50/53
AMMONIUM FLUORIDE 12125-01-8 T 23/24/25 (1/2-)26-45
AMMONIUM HEXAFLUOROSILICATE 16919-19-0 T 23/24/25 (1/2-)26-45 Note A
AMMONIUM HYDROGEN DIFLUORIDE 1341-49-7 T,C 25-34 (1/2-)22-26-37-45
AMMONIUM PERCHLORATE 7790-98-9 O 9-44 (2-)14-16-27-36/37 Note G
AMMONIUM POLYSULPHIDES 9080-17-5 C 31-34 (1/2-)26-45
AMYL ACETATE 628-63-7 - 10 (2-)23 Note C
AMYLALCOHOL, except tert-PENTANOL 30899-19-5 Xn 10-20 (2-)24/25 Note C
AMYLASE, I- 9000-90-2 Xn 42 (2-)22-24-36/37
AMYLASES with exception of those specified Xn 42 (2-)22-24-36/37
elsewhere in this Annex
AMYL FORMATE 638-49-3 - 10 (2) Note C
AMYL PROPIONATE 624-54-4 - 10 (2-)23 Note C
ANILAZINE 101-05-3 Xi 36/38 (2-)22
ANILINE 62-53-3 T,N 20/21/22-40- (1/2-)28-36/37-45-61
48/23/24/25-50
ANILINE, SALTS T,N 20/21/22-40- (1/2-)28-36/37-45-61 Note A
48/23/24/25-50
o-ANISIDINE 90-04-0 T+,N 45-26/27/28-33-51/53 53-45-61 Note E
p-ANISIDINE 104-94-9 T+,N 26/27/28-33-50 (1/2-)28-36/37-45-61
ANTIMONY COMPOUNDS except TETROXIDE and Xn 20/22 (2-)22* Note A
PENTOXIDE, TRISULPHIDE, PENTASULPHIDE and
those specified elsewhere in this Annex *If appropriate
ANTIMONY PENTACHLORIDE 7647-18-9 C 34-37 (1/2-)26-45
ANTIMONY TRICHLORIDE 10025-91-9 C 34-37 (1/2-)26-45
ANTIMONY TRIFLUORIDE 7783-56-4 T 23/24/25 (1/2-)7-26-45
ANTIMONY TRIOXIDE 1309-64-4 Xn 40 (2-)22-36/37
ANTU 86-88-4 T+ 28-40 (1/2-)25-36/37-45
ARSENIC 7440-38-2 T 23/25 (1/2-)20/21-28-45
ARSENIC ACID and its SALTS T 45-23/25 53-45 Note A, E
ARSENIC COMPOUNDS, conc.³0.2%, with the T 23/25 (1/2-)20/21-28-45 Note A
exception of those specified elsewhere in this Annex
ARSENIC OXIDE 1303-28-2 T 45-23/25 53-45 Note E
ARSENIC PENTOXIDE 1303-28-2 T 45-23/25 53-45 Note E
ARSENIC TRIOXIDE 1327-53-3 T+ 45-28-34 53-45 Note E
ARSINE 7784-42-1 F+,T+,N 12-26-48/20-50/53 (1/2-)9-16-28-33-36/37-45-60-61
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Substance CAS number Symbol Risk-phrases Safety phrases
ASBESTOS T 45-48/23 53-45 Note E
ATRAZINE 1912-24-9 Xn 20/22-36-40-43 (2-)36/37-46
ATROPINE 51-55-8 T+ 26/28 (1/2-)25-45
ATROPINE, SALTS T+ 26/28 (1/2-)25-45 Note A
AURAMINE 492-80-8 Xn,N 22-36-40-51/53 (2-)36/37-61
AURAMINE, SALTS Xn,N 22-36-40-51/53 (2-)36/37-61 Note A
AZACONAZOLE 60207-31-0 Xn 22-44 (2-)24
AZINPHOS-ETHYL 2642-71-9 T+ 24-28 (1/2-)28-36/37-45
AZINPHOS-METHYL 86-50-0 T+ 24-28 (1/2-)28-36/37-45
AZIRIDINE 151-56-4 F,T+,N 45-46-11-26/27/28-34- 53-45-61 Note D, E
51/53
AZOBENZENE 103-33-3 Xn 20/22 (2-)28
AZOTHOATE 5834-96-8 Xn 20/22 (2-)13
AZOXYBENZENE 495-48-7 Xn 20/22 (2-)28
BARBAN 101-27-9 Xn 22-43 (2-)24-36/37
BARIUM CARBONATE 513-77-9 Xn 22 (2-)24/25
BARIUM CHLORATE 13477-00-4 O,Xn 9-20/22 (1/2-)13-27
BARIUM CHLORIDE 10361-39-4 T 20-25 (1/2-)45
BARIUM SALTS, conc.³1%, with the exception Xn 20/22 (2-)28 Note A
of BARIUM SULPHATE, salts of 1-AZO-2-HYDROXUNAPHTHALENYL ARYL SULPHONIC ACID
and salts specified elsewhere in this Annex
BARIUM PERCHLORATE 13465-95-7 O,Xn 9-20/22 (2-)27
BARIUM PEROXIDE 1304-29-6 O,Xn 8-20/22 (2-)13-27
BARIUM POLYSULPHIDES 50864-67-0 Xi 31-36/37/38 (2-)28
BARIUM SULPHIDE 21109-95-5 Xn 20/22-31 (2-)28
BENAZOLIN 3813-05-6 Xi 36/38 (2-)22
BENDIOCARB 22781-23-2 T 21-25 (1/2-)22-36/37-45
BENOMYL 17804-35-2 Xn 40 (2-)36/37
BENQUINOX 495-73-8 T 21-25 (1/2-)36/37-45
BENSULIDE 741-58-2 Xn 22 (2-)24-36
BENTAZONE 25057-89-0 Xn 22-36 (2-)26
BENZAL CHLORIDE 98-87-3 T 22-23-37/38-40-41 (1/2-)36/37-38-45
BENZALDEHYDE 100-52-7 Xn 22 (2-)24
BENZENE 71-43-2 F,T 45-11-48/23/24/25 53-45 Note E
BENZENE-1,3-DIAMINE DIHYDROCHLORIDE 541-69-5 T,N 23/24/25-43-50/53 (1/2-)28-36/37-45-60-61 Note C
BENZENE-1,4-DIAMINE DIHYDROCHLORIDE 624-18-0 T,N 23/24/25-43-50/53 (1/2-)28-36/37-45-60-61 Note C
1,3-BENZENEDIOL 108-46-3 Xn,N 22-36/38-50 (2-)26-61
BENZENE-1,2:3,4-TETRACARBOXYLIC DIANHYDRIDE 89-32-7 Xi 36/37/38 (2-)25
BENZENE-1,2,4-TRICARBOXYLIC-1,2-ANHYDRIDE 552-30-7 Xn 36/37/38-42 (2-)22-28
BENZIDINE 92-87-5 T,N 45-22-50/53 53-45-60-61 Note E
BENZIDINE, SALTS T,N 45-22-50/53 53-45-60-61 Note A, E
BENZIDINE BASED AZO DYES; T 45 53-45 Note A
4,4'-DIARYLAZOBIPHENYL DYES, with exception
of those specified elsewhere in this Annex
1,2-BENZISOTHIAZOL-3(2H)-ONE 2634-33-5 Xn 22-38-43 (2-)24-37
BENZO[e]ACEPHENANTHRYLENE 205-99-2 T 45 53-45
BENZO[a]ANTHRACENE 56-55-3 T 45 53-45
BENZO[d,e,f]CHRYSENE 50-32-8 T 45-46-60-61 53-45
BENZO[b]FLUORANTHENE 205-99-2 T 45 53-45
BENZO[j]FLUORANTHENE 205-82-3 T 45 53-45
BENZO[k]FLUORANTHENE 207-08-9 T 45 53-45
BENZOGUANAMINE 91-76-9 Xn 22 (2)
BENZONITRILE 100-47-0 Xn 21/22 (2-)23
BENZOPHENONE-3,3',4,4'-TETRACARBOXYLIC 2421-28-5 Xi 36/37 (2-)25
DIANHYDRIDE
BENZO[a]PYRENE 50-32-8 T 45-46-60-61 53-45
p-BENZOQUINONE 106-51-4 T 23/25-36/37/38 (1/2-)26-28-45
p-BENZOQUINONE 1-BENZOYLHYDRAZONE 4-OXIME 495-73-8 T 21-25 (1/2-)36/37-45
BENZOTHIAZOLE-2-THIOL 149-30-4 Xi,N 43-50/53 (2-)24-37-60-61
1-(2-BENZOTHIAZOLYL)-3-METHYLUREA 1929-88-0 Xn 22 (2-)24/25
(BENZOTHIAZOL-2-YLTHIO)SUCCINIC ACID 95154-01-1 Xi 43 (2-)24-37
Page No. 4
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Substance CAS number Symbol Risk-phrases Safety phrases
I-3-(3-(2H-BENZOTRIAZOL-2-YL)-5-tert- Xn,N 43-48/22-51/53 (2-)36/37-61
BUTYL-4-HYDROXYPHENYL)PROPIONYL-
omega-HYDROXYPOLY(OXYETHYLENE) and
I-3-(3-(2H-BENZOTRIAZOL-2-YL)-5-tert-BUTYL-4-HYDROXYPHENYL)PROPIONYL-
omega-3(3-(2H-BENZOTRIAZOL-2-YL)-5-tert-BUTYL-4-HYDROXYPHENYL)PROPIONYL-
HYDROXYPOLY(OXYETHYLENE)
BENZOTRICHLORIDE 98-07-7 T 45-22-23-37/38-41 53-45 Note E
BENZOTRIFLUORIDE 98-08-8 F,N 11-51/53 (2-)16-23-61
BENZOYL CHLORIDE 98-88-4 C 34 (1/2-)26-45
BENZOYL PEROXIDE 94-36-0 E,Xi 2-7-36-43 (2-)3/7-14-36/37/39
BENZOYLPROP-ETHYL 33878-50-1 Xn 22 (2-)24
BENZTHIAZURON 1929-88-0 Xn 22 (2-)24/25
BENZYL ALCOHOL 100-51-6 Xn 20/22 (2-)26
BENZYLAMINE 100-46-9 C 21/22-34 (1/2-)26-36/37/39-45
BENZYL BENZOATE 120-51-4 Xn 22 (2-)25
BENZYL BROMIDE 100-39-0 Xi 36/37/38 (2-)39
BENZYL CHLORIDE 100-44-7 T 22-23-37/38-40-41 (1/2-)36/37-38-45
BENZYL CHLOROFORMATE 501-53-1 C 34-37 (1/2-)26-45
S-BENZYL DIISOPROPYL PHOSPHOROTHIOATE 26087-47-8 Xn 22 (2)
BENZYLDIMETHYLAMINE 103-83-3 C 10-20/21/22-34-52/53 (1/2-)26-36-45-61
S-BENZYL N,N-DIPROPYLTHIOCARBAMATE 52888-80-9 Xn,N 22-48/22-51/53 (2-)37-61
(N-BENZYL-N-ETHYL)AMINO-3'- 55845-90-4 Xi,N 41-51/53 (2-)26-39-61
HYDROXYACETOPHENONE HYDROCHLORIDE
BENZYL-2-HYDROXYDECYLDIAMMONIUM BENZOATE 113694-52-3 C,N 22-34-50/53 (1/2-)26-28-36/37/39-45-60-61
BENZYLIDENE CHLORIDE 98-87-3 T 22-23-37/38-40-41 (1/2-)36/37-38-45
BENZYLTRIBUTYLAMMONIUM 4-HYDROXYNAPHTHALENE- 102561-46-6 Xn,N 20-51/53 (2-)22-61
1-SULPHONATE
BENZYL VIOLET 4B 1694-09-3 Xn 40 (2-)36/37
BERYLLIUM 7440-41-7 T+ 49-25-26-36/37/38-
43-48/23 53-45, Note E
BERYLLIUM COMPOUNDS T+ 49-25-26-36/37/38-
43-48/23 53-45 Note A, E
BHC 608-73-1 T,N 21-25-40-50/53 (1/2-)22-36/37-45-60-61 Note C
BINAPACRYL 485-31-4 T 61-21/22 53-45 Note E
BIOALLETHRIN 584-79-2 Xn 22 (2-)24
S-BIOALLETHRIN 28434-00-6 Xn,N 21/22-50/53 (2-)36/37-60-61
BIPHENYL 92-52-4 Xi,N 36/37/38-50/53 (2-)23-60-61
BIPHENYL-4-YLAMINE 92-67-1 T 45-22 53-45 Note E
BIPHENYL-4-YLAMINE, SALTS T 45-22 53-45 Note A, E
BIPHENYL-4,4'-YLENEDIAMINE 92-87-5 T,N 45-22-50/53 53-45-60-61 Note E
BIPHENYL-4,4'-YLENEDIAMINE, SALTS T,N 45-22-50/53 53-45-60-61 Note A, E
2,2-BIS(ACRYLOYLOXYMETHYL)BUTYL ACRYLATE 15625-89-5 Xi 36/38-43 (2-)39 Note D
N,N-BIS(3-AMINOPROPYL)METHYLAMINE 105-83-9 T 22-23/24-34 (1/2-)26-36/37/39-45
BIS(2-CHLOROETHYL) ETHER 111-44-4 T+ 10-26/27/28-40 (1/2-)7/9-27-38-45
BIS(CHLOROMETHYL) ETHER 542-88-1 T+ 45-10-22-24-26 53-45 Note E
O,O-BIS(4-CHLOROPHENYL) 4104-14-7 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
N-ACETIMIDOYLPHOSPHOROAMIDOTHIOATE
1,1-BIS(4-CHLOROPHENYL)ETHANOL 80-06-8 Xn 22 (2-)36
BIS(2-DIMETHYLAMINOETHYL)(METHYL)AMINE 3030-47-5 T 22-24-34 (1/2-)26-36/37/39-45
BIS(I,I-DIMETHYLBENZYL) PEROXIDE 80-43-3 O,Xi 7-36/38 (2-)3/7-14-36/37/39
2,5-BIS(1,1-DIMETHYLBUTYL)HYDROQUINONE N 51/53 61
1,1'-BIS(3,5-DIMETHYLMORPHOLINOCARBONYL- Xn 22-36/37/38 (2-)22-36
METHYL)-4,4'-BIPYRIDYLIUM ION
1,3-BIS(2,3-EPOXYPROPOXY)BENZENE 101-90-6 T 23/24/25-40-43 (1/2-)23-24-45
1,4-BIS(2,3-EPOXYPROPOXY)BUTANE 2425-79-8 Xn 20/21-36/38-43 (2-)26-28-37/39
1,3-BIS(2,3-EPOXYPROPOXY)-2,2-DIMETHYLPROPANE 17557-23-2 Xi 38-43 (2-)24-37
BIS[4-(2,3-EPOXYPROPOXY)PHENYL]PROPANE 1675-54-3 Xi 36/38-43 (2-)28-37/39
1,2-BIS(ETHOXYCARBONYL)ETHYL O,O-DIMETHYL 121-75-5 Xn 22 (2-)24
PHOSPHORODITHIOATE
3-[BIS(2-ETHYLHEXYL)AMINOMETHYL] 105254-85-1 C,N 34-43-50/53 (1/2-)26-28-36/37/39-45-60-61
BENZOTHIAZOLE-2(3H)-THIONE
N,N-BIS(2-ETHYLHEXYL)-((1,2,4-TRIAZOL- 91273-04-0 C,N 34-43-51/53 (1/2-)26-28-36/37/39-45-61
1-YL)METHYL)AMINE
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Substance CAS number Symbol Risk-phrases Safety phrases
BIS(4-FLUOROPHENYL)-METHYL-(1,2,4-TRIAZOL- Xi,N 36-51/53 (2-)26-61
4-YLMETHYL)SILANE HYDROCHLORIDE
BIS(HYDROXYLAMMONIUM) SULPHATE 10039-54-0 Xn,N 22-36/38-43-48/22-50 (2-)22-24-37-61
2,5-BIS-(HYDROXYMETHYL)OXOLANE 104-80-3 Xi 36/37/38 (2-)39
BIS(8-HYDROXYQUINOLINE) SULPHATE 134-31-6 Xn 22 (2-)36
BIS(2-METHOXYETHYL) PHTHALATE 117-82-8 T 61-62 53-45
BIS(METHOXYTHIOCARBONOYL) DISULPHIDE 1468-37-7 Xn 22 (2)
BISPHENOL-A-DIGLYCIDYL ETHER 1675-54-3 Xi 36/38-43 (2-)28-37/39
BIS(PIPERIDINOTHIOCARBONYL) DISULPHIDE 94-37-1 Xi 36/37/38-43 (2-)24-26-37
BIS(2,2,6,6-TETRAMETHYL-4-PIPERIDYL)SUCCINATE 62782-03-0 Xi 36-52/53 (2-)26-61
BIS(2,4,6-TRINITROPHENYL)AMINE 131-73-7 E,T+,N 2-26/27/28-33-51/53 (1/2-)35-36-45-61
4,4'-BI-o-TOLUIDINE 119-93-7 T,N 45-22-51/53 53-45-61 Note E
BLASTICIDIN-S 2079-00-7 T+ 28 (1/2-)24/25-36/37-45
BORON TRIBROMIDE 10294-33-4 T+,C 14-26/28-35 (1/2-)9-26-28-36/37/39-45
BORON TRICHLORIDE 10294-34-5 T+ 14-26/28-34 (1/2-)9-26-28-36/37/39-45
BORON TRIFLUORIDE 7637-07-2 T+,C 14-26-35 (1/2-)9-26-28-36/37/39-45
BRODIFACOUM 56073-10-0 T+ 27/28-48/24/25 (1/2-)36/37-45
BROMELAIN, juice 9001-00-7 Xn 36/37/38-42 (2-)22-24-26-36/37
BROMINE 7726-95-6 T+,C 26-35 (1/2-)7/9-26-45
BROMOACETIC ACID 79-08-3 T,C 23/24/25-35 (1/2-)36/37/39-45
BROMOBENZENE 108-86-1 Xi,N 10-38-51/53 (2-)61
BROMOBENZYLBROMOTOLUENE, mixture of isomers 99688-47-8 Xn,N 43-48/22-50/53 (2-)24-37-41-60-61
0-4-BROMO-2,5-DICHLOROPHENYL O,O-DIETHYL 4824-78-6 T,N 21-25-50/53 (1/2-)28-36/37-45-60-61
PHOSPHOROTHIOATE
O-4-BROMO-2,5-DICHLOROPHENYL O-METHYL 21609-90-5 T,N 21-25-39/25-50/53 (1/2-)25-36/37/39-45-60-61
PHENYLPHOSPHONOTHIOATE
BROMOETHANE 74-96-4 Xn 20/21/22 (2-)28
2-(2-BROMOETHOXY)ANISOLE 4463-59-6 Xn 22-52/53 (2-)22-61
BROMOETHYLENE 593-60-2 F+,T 45-12 53-45
BROMOFENOXIM 13181-17-4 Xn 22 (2-)25
BROMOFORM 75-25-2 T,N 23-36/38-51/53 (1/2-)28-45-61
BROMOMETHANE 74-83-9 T,N 23-36/37/38-50/53-59 (1/2-)15-27-36/37/39-38-
45-59-61
BROMOPHOS 2104-96-3 Xn 22 (2-)36
BROMOPHOS-ETHYL 4824-78-6 T,N 21-25-50/53 (1/2-)28-36/37-45-60-61
1-BROMOPROPANE 106-94-5 Xn 10-20 (2-)9-24
I-BROMOTOLUENE 100-39-0 Xi 36/37/38 (2-)39
BROMOXYNIL 1689-84-5 T 25-63 (1/2-)36/37-45
BROMOXYNIL OCTANOATE 1689-99-2 Xn 21/22-63 (2-)36/37
BRONOPOL 52-51-7 Xn,N 21/22-37/38-41-50/53 (2-)26-37/39-60-61
BRUCINE 357-57-3 T+ 26/28 (1/2-)13-45
BRUCINE, SALTS T+ 26/28 (1/2-)13-45 Note A
BUFENCARB 8065-36-9 T 24/25 (1/2-)28-36/37-45
BUTANAL 123-72-8 F 11 (2-)9-29-33
1,3-BUTADIENE 106-99-0 F+,T 45-12 53-45 Note D
BUTADIENE DIEPOXIDE 1464-53-5 T 23/24/25-36/37/38-40-
42/43 (1/2-)23-24-45
BUTANEDIOLDIGLYCIDYL ETHER 2425-79-8 Xn 20/21-36/38-43 (2-)26-28-37/39
BUTANE 106-97-8 F+ 12 (2-)9-16 Note C
BUTANOL, except tert-BUTYL ALCOHOL 71-36-3(n) Xn 10-20 (2-)16 Note C
tert-BUTANOL 75-65-0 F,Xn 11-20 (2-)9-16
2-BUTANONE 78-93-3 F,Xi 11-36/37 (2-)9-16-25-33
2-BUTANONE OXIME 96-29-7 Xi 36-43 (2-)23-24
2-BUTENAL 123-73-9 F,T 11-23-36/37/38 (1/2-)29-33-45
BUTENE, all isomers F+ 12 (2-)9-16-33 Note C
2-BUTOXYETHANOL 111-76-2 Xn 20/21/22-37 (2-)24/25
2-(2-BUTOXYETHOXY)ETHANOL 112-34-5 Xi 36 (2-)26
2-(2-BUTOXYETHOXY)ETHYL THIOCYANATE 112-56-1 T 10-24/25 (1/2-)13-36/37-45
2-BUTOXYETHYL ACETATE 112-07-2 Xn 20/21 (2-)24
3-BUTOXY-2-PROPANOL 5131-66-8 Xi 36/38 (2)
1-(2-BUTOXYPROPOXY)PROPAN-2-OL 24083-03-2 Xn 21/22 (2)
n-BUTYL ACETATE 123-86-4 - 10 (2)
sec-BUTYL ACETATE 105-46-4 F 11 (2-)16-23-29-33 Note C
Page No. 6
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Substance CAS number Symbol Risk-phrases Safety phrases
tert-BUTYL ACETATE 540-88-5 F 11 (2-)16-23-29-33 Note C
ISOBUTYL ACETATE 110-19-0 F 11 (2-)16-23-29-33 Note C
n-BUTYL ACRYLATE 141-32-2 Xi 10-36/37/38-43 (2-)9 Note D
tert-BUTYL ALCOHOL 75-65-0 F,Xn 11-20 (2-)9-16
BUTYL ALCOHOL, except tert-BUTYL ALCOHOL 71-36-3 (n) Xn 10-20 (2-)16 Note C
BUTYLAMINE 109-73-9 F,C 11-20/21/22-35 (1/2-)3-16-26-29-36/37/39-45
sec-BUTYLAMINE 13952-84-6 F,C,N 11-20/22-35-50 (1/2-)9-16-26-28-36/37/39-
45-61
2-tert-BUTYLAMINOETHYL METHACRYLATE 3775-90-4 Xi 36/38-43 (2-)26 Note D
BUTYL BUTYRATE 109-21-7 - 10 (2) Note C
BUTYL CHLORIDE 109-69-3 F 11 (2-)9-16-29
BUTYL CHLOROFORMATE 592-34-7 T 10-23-34 (1/2-)26-36-45
4-tert-BUTYL-2-CHLOROPHENYL METHYL 299-86-5 Xn,N 21/22-50/53 (2-)36/37-60-61
METHYLPHOSPHORAMIDATE
tert-BUTYL CUMYL PEROXIDE 3457-61-2 O,Xi 7-38 (2-)3/7-14-36/37/39
BUTYL (DIALKYLOXY(DIBUTOXYPHOSPHORYLOXY))- F,Xi,N 11-36-51/53 (2-)7/9-16-26-43-61
TITANIUM (TRIALKYLOXY)TITANIUM PHOSPHATE
tert-BUTYL-I,I-DIMETHYL- 3457-61-2 O,Xi 7-38 (2-)3/7-14-36/37/39
BENZYL PEROXIDE
6-sec-BUTYL-2,4-DINITROPHENOL 88-85-7 T,N 61-62-24/25-36-44-50/53 53-45-60-61 Note E
2-tert-BUTYL-4,6-DINITROPHENOL 1420-07-1 T 61-24/25-36-44 53-45 Note E
2-sec-BUTYL-4,6-DINITROPHENYL 973-21-7 T 25 (1/2-)37-45
ISOPROPYL CARBONATE
2-sec-BUTYL-4,6-DINITROPHENYL-3-METHYL- 485-31-4 T 61-21/22 53-45 Note E
CROTONATE
1,3-BUTYLENEGLYCOL DIACRYLATE 19485-03-1 C 21-34-43 (1/2-)26-36/37/39-45 Note D
1,4-BUTYLENEGLYCOL DIACRYLATE 1070-70-8 C 21-34-43 (1/2-)26-36/37/39-45 Note D
BUTYL-2,3-EPOXYPROPYL ETHER 2426-08-6 Xn 20-43 (2-)24/25
BUTYL ETHYL KETONE 106-35-4 Xn 10-20-36 (2-)24
BUTYL FORMATE, all isomers 592-84-7(n) F 11 (2-)9-16-33 Note C
BUTYL GLYCIDYL ETHER 2426-08-6 Xn 20-43 (2-)24/25
BUTYLGLYCOL ACETATE 112-07-2 Xn 20/21 (2-)24
n-BUTYL METHACRYLATE 97-88-1 Xi 10-36/37/38-43 (2) Note D
BUTYL METHYL KETONE 591-78-6 F,T 11-48/23 (1/2-)9-16-29-45-51
1-BUTYL-2-METHYLPYRIDIUM BROMIDE 26576-84-1 Xn 22-52/53 (2-)61
sec-BUTYL NITRITE 924-43-6 F,Xn 11-20/22 (2-)16-24-46
tert-BUTYL NITRITE 540-80-7 F,Xn 11-20/22 (2-)16-24-46
BUTYL PROPIONATE, all isomers 591-01-2(n) - 10 (2) Note C
2-BUTYNE-1,4-DIOL 110-65-6 T 25-34 (1/2-)22-36-45
BUTYRALDEHYDE 123-72-8 F 11 (2-)9-29-33
BUTYRALDEHYDE OXIME 110-69-0 T 22-24-36 (1/2-)23-36-45
BUTYRIC ACID 107-92-6 C 34 (1/2-)26-36-45
n-BUTYRONITRILE 109-74-0 T 10-23/24/25 (1/2-)45
BUTYRYL CHLORIDE 141-75-3 F,C 11-34 (1/2-)16-23-26-36-45
CADMIUM CHLORIDE 10108-64-2 T 45-48/23/25 53-45 Note E
CADMIUM COMPOUNDS, except CADMIUM Xn 20/21/22 (2-)22* Note A
SULPHOSELENIDE, mixture of CADMIUM
SULPHIDE with ZINC- or MERCURY SULPHIDE *If appropriate
CADMIUMCYANIDE 542-83-6 T+ 26/27/28-32-33-40 (1/2-)7-28-29-45
CADMIUM FLUORIDE 7790-79-6 T 23/25-33-40 (1/2-)22-45
CADMIUM FLUOROSILICATE 17010-21-8 T 23/25-33-40 (1/2-)22-45
CADMIUMFORMATE 4464-23-7 T 23/25-33-40 (1/2-)22-45
CADMIUM HEXAFLUOROSILICATE 17010-21-8 T 23/25-33-40 (1/2-)22-45
CADMIUM IODIDE 7790-80-9 T 23/25-33-40 (1/2-)22-45
CADMIUM OXIDE 1306-19-0 T 49-22-48/23/25 53-45 Note E
CADMIUM SULPHATE 10124-36-4 T 49-22-48/23/25 53-45 Note E
CADMIUM SULPHIDE 1306-23-6 T 22-40-48/23/25 (1/2-)22-36/37-45
CAFFEINE 58-08-2 Xn 22 (2)
CALCIUM 7440-70-2 F 15 (2-)8-24/25-43
CALCIUM CARBIDE 75-20-7 F 15 (2-)8-43
CALCIUM CHLORIDE 10043-52-4 Xi 36 (2-)22-24
CALCIUM CHROMATE 13765-19-0 T,N 45-22-50/53 53-45-60-61 Note E
CALCIUM CYANAMIDE 156-62-7 Xn 22-37-41 (2-)22-26-36/37/39
Page No. 7
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Substance CAS number Symbol Risk-phrases Safety phrases
CALCIUM CYANIDE 592-01-8 T+ 28-32 (1/2-)7/8-23-36/37-45
CALCIUM HYDRIDE 7789-78-8 F 15 (2-)7/8-24/25-43
CALCIUM HYPOCHLORITE, active Chlorine>39% 7778-54-3 O,C 8-31-34 (1/2-)26-43-45
CALCIUM IODOXYBENZOATE, all isomers E 1 (2-)35 Note C
CALCIUM OCTADECYLXYLENESULPHONATE C,N 34-51/53 (1/2-)26-28-36/37/39-45-61
CALCIUM PHOSPHIDE 1305-99-3 F,T+ 15/29-28 (1/2-)22-43-45
CALCIUM POLYSULPHIDES 1344-81-6 Xi 31-36/37/38 (2-)28
CALCIUM SULPHIDE 20548-54-3 Xi 31-36/37/38 (2-)28
CALOMEL 10112-91-1 Xn 22-36/37/38 (2-)13-24/25-46
CAMPHECHLOR 8001-35-2 T,N 21-25-37/38-40-50/53 (1/2-)36/37-45-60-61
epsilon-CAPROLACTAM 105-60-2 Xn 20/22-36/37/38 (2)
CAPTAFOL 2425-06-1 T 45-43 53-45
CAPTAN 133-06-2 Xn 36-40-43 (2-)36/37
CARBADOX 6804-07-5 F,T 45-11-22 53-45 Note E
CARBANONITRIL 420-04-2 T 21-25-36/38-43 (1/2-)3-22-36/37-45
CARBARYL 63-25-2 Xn 22 (2-)22-24
CARBENDAZIM 10605-21-7 Xn 40 (2-)36/37
CARBOFURAN 1563-66-2 T+ 26/28 (1/2-)36/37-45
4,4'CARBONIMIDOYLBIS[N,N-DIMETHYLANILINE] 492-80-8 Xn,N 22-36-40-51/53 (2-)36/37-61
4,4'CARBONIMIDOYLBIS[N,N-DIMETHYLANILINE], SALTS Xn,N 22-36-40-51/53 (2-)36/37-61 Note A
CARBON DISULPHIDE 75-15-0 F,T 11-36/38-48/23-62-63 (1/2-)16-33-36/37-45
CARBON MONOXIDE 630-08-0 F+,T 61-12-23-48/23 53-45, Note E
CARBON TETRACHLORIDE 56-23-5 T,N 23/24/25-40-48/23- (1/2-)23-36/37-45-59-61
52/53-59
CARBONYL CHLORIDE 75-44-5 T+ 26-34 (1/2-)9-26-36/37/39-45
4,4'-CARBONYLDI(PHTHALIC ANHYDRIDE) 2421-28-5 Xi 36/37 (2-)25
CARBOPHENOTHION 786-19-6 T,N 24/25-50/53 (1/2-)28-36/37-45-60-61
CARTAP HYDROCHLORIDE 15263-52-2 Xn 21/22 (2-)36/37
CAUSTIC POTASH 1310-58-3 C 35 (1/2-)26-37/39-45
CAUSTIC SODA 1310-73-2 C 35 (1/2-)26-37/39-45
CELLOBIOHYDROLASE, exo- 37329-65-0 Xn 42 (2-)22-24-36/37
CELLULASE 9012-54-8 Xn 42 (2-)22-24-36/37
CELLULASES with exception of those specified 9012-54-8 Xn 42 (2-)22-24-36/37
elsewhere in this Annex
CELLULOSE NITRATE, containing a maximum of F 11 (2-)16-33-37/39
12.6% NITROGEN
CELLULOSE NITRATE, containing more than 12,6% 9004-70-0 E 1-3 (2-)35
NITROGEN
CHLORAL HYDRATE 302-17-0 T 25-36/38 (1/2-)25-45
2-CHLORALLYL (DIETHYL)DITHIOCARBAMATE 95-06-7 T 45-22 53-45, Note E
CHLORALOSE 15879-93-3 Xn 20/22 (2-)16-24/25-28
CHLORAMINE-T, SODIUM SALT 127-65-1 Xi 36/37/38 (2-)7-15
CHLORANIL 118-75-2 Xi,N 36/38-50/53 (2)37-60-61
CHLORDANE 57-74-9 Xn,N 21/22-40-50/53 (2-)36/37-60-61
CHLORDECONE 143-50-0 T 24/25-40 (1/2-)22-36/37-45
CHLORDIMEFORM 6164-98-3 Xn 21/22-40 (2-)22-36/37
CHLORDIMEFORM HYDROCHLORIDE 19750-95-9 Xn 22-40 (2-)22-36/37
CHLORENDIC ANHYDRIDE 115-27-5 Xi 36/37/38 (2-)25
CHLORFENAC 85-34-7 Xn 22 (2-)36
CHLORFENETHOL 80-06-8 Xn 22 (2-)36
CHLORFENPROP-METHYL 14437-17-3 Xn 21/22 (2-)36/37
CHLORFENSON 80-33-1 Xn 22-38 (2-)37
CHLORFENVINPHOS 470-90-6 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
CHLORINE 7782-50-5 T,N 23-36/37/38-50 (1/2-)9-45-61
CHLORMEPHOS 24934-91-6 T+ 27/28 (1/2-)28-36/37-45
CHLORMEQUAT CHLORIDE 999-81-5 Xn 21/22 (2-)36/37
CHLOROACETIC ACID 79-11-8 T,N 25-34-50 (1/2-)23-37-45-61
CHLOROACETONITRILE 107-14-2 T 23/24/25 (1/2-)45
CHLOROACETYL CHLORIDE 79-04-9 C 34-37 (1/2-)9-26-45
S-2-CHLOROALLYL (DIETHYL)DITHIOCARBAMATE 95-06-7 T 45-22 53-45, Note E
CHLOROANILINE mono-, di-, tri- T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61 Note C
CHLOROANILINES with exception of those T+,N 26/27/28-33-51/53 (1/2-)28-36/37-45-61 Note C
specified elsewhere in this Annex
Page No. 8
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Substance CAS number Symbol Risk-phrases Safety phrases
2-CHLOROBENZALDEHYDE 89-98-5 C 34 (1/2-)26-45
o-CHLOROBENZALDEHYDE 89-98-5 C 34 (1/2-)26-45
CHLOROBENZENE 108-90-7 Xn,N 10-20-51/53 (2-)24/25-61
CHLOROBENZILATE 510-15-6 Xn 22 (2)
2-CHLOROBENZONITRILE 873-32-5 Xn 21/22-36 (2-)23
2-CHLOROBUTA-1,3-DIENE 126-99-8 F,Xn 11-20/22-36 (2-)16 Note D
1-CHLOROBUTANE 109-69-3 F 11 (2-)9-16-29
4-CHLOROBUT-2-YNYL 3-CHLOROPHENYLCARBAMATE 101-27-9 Xn 22-43 (2-)24-36/37
CHLOROCRESOL 59-50-7 Xn,N 21/22-41-43-50 (2-)26-36/37/39-61
4-CHLORO-m-CRESOL 59-50-7 Xn,N 21/22-41-43-50 (2-)26-36/37/39-61
3-CHLORO-6-CYANO-BICYCLO(2.2.1)HEPTAN-2-ONE- 15271-41-7 T+ 24-28 (1/2-)28-36/37-45
O(N-METHYLCARBAMOYL)OXIME
2-(4-CHLORO-6-ETHYLAMINO-1,3,5-TRIAZINE-2- 21725-46-2 Xn 22 (2-)37
YLAMINO)-2-METHYLPROPIONITRILE
2-CHLORO-1-(2,4-DICHLOROPHENYL)VINYL DIETHYL 470-90-6 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
PHOSPHATE
2-CHLORO-2-DIETHYLCARBAMOYL-1-METHYLVINYL 13171-21-6 T+,N 24-28-40-50/53 (1/2-)23-36/37-45-60-61
DIMETHYL PHOSPHATE
2-CHLORO-4-DIMETHYLAMINO-6-METHYLPYRIMIDINE 535-89-7 T+ 28 (1/2-)36/37-45
CHLORODIMETHYL ETHER 107-30-2 F,T 45-11-20/21/22 53-45 Note E
CHLORODINITROBENZENE T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61 Note C
1-CHLORO-2,3-EPOXYPROPANE 106-89-8 T 45-10-23/24/25-34-43 53-45 Note E
CHLOROETHANE 75-00-3 F+,Xn 12-40-52/53 (2-)9-16-33-36/37-61
2-CHLOROETHANOL 107-07-3 T+ 26/27/28 (1/2-)7/9-28-45
2-CHLOROETHYL CHLOROPROPYL 2-CHLOROETHYL- Xn 22 (2)
PHOSPHONATE and 2-CHLOROETHYL CHLOROPROPYL
2-CHLOROPROPYLPHOSPHONATE, mixture of isomers
CHLOROETHYLENE 75-01-4 F+,T 45-12 53-45 Note D
2-CHLOROETHYLTRIMETHYL AMMONIUM CHLORIDE 999-81-5 Xn 21/22 (2-)36/37
CHLOROFORM 67-66-3 Xn 22-38-40-48/20/22 (2-)36/37
CHLOROFORMIC ACID BUTYL ESTER 592-34-7 T 10-23-34 (1/2-)26-36-45
CHLOROFORMIC ACID PROPYL ESTER 109-61-5 T 10-23-34 (1/2-)26-36-45
2-CHLORO-N-ISOPROPYLACETANILIDE 1918-16-7 Xn 22-36-43 (2-)24-37
CHLOROMETHANE 74-87-3 F+,Xn 12-40-48/20 (2-)9-16-33
(CHLOROMETHYL)BIS(4-FLUOROPHENYL)METHYLSILANE 85491-26-5 N 51/53 61
O-(3-CHLORO-4-METHYLCOUMARIN-7-YL) O,O- 56-72-4 T+,N 21-28-50/53 (1/2-)28-36/37-45-60-61
DIETHYL PHOSPHOROTHIOATE
CHLOROMETHYL METHYL ETHER 107-30-2 F,T 45-11-20/21/22 53-45 Note E
4-CHLORO-3-METHYLPHENOL 59-50-7 Xn,N 21/22-41-43-50 (2-)26-36/37/39-61
4-(4-CHLORO-o-TOLYLOXY) BUTYRIC ACID 94-81-5 Xn 22 (2-)24/25
2-(4-CHLORO-O-TOLYLOXY) PROPIONIC ACID 93-65-2 Xn 22-38-41 (2-)26-37/39
3-CHLORO-2-METHYLPROPENE 563-47-3 F,C,N 11-20/22-34-43-51/53 (2-)9-16-26-29-36/37/39-45-61
CHLORONITROANILINES with exception of those T+,N 26/27/28-33-51/53 (1/2-)28-36/37-45-61 Note C
specified elsewhere in this Annex
2-CHLORO-4-NITROANILINE 121-87-9 Xn,N 22-51/53 (2-)22-24-61
1-CHLORO-4-NITROBENZENE 100-00-5 T 23/24/25-33 (1/2-)28-37-45
p-CHLORONITROBENZENE 100-00-5 T 23/24/25-33 (1/2-)28-37-45
2-CHLORO-6-NITRO-3-PHENOXYANILINE 74070-46-5 N 50/53 60-61
O-(3-CHLORO-4-NITROPHENYL) O,O-DIMETHYL 500-28-7 Xn 20/21/22 (2-)13
PHOSPHOROTHIOATE
O-4-CHLORO-3-NITROPHENYL O,O-DIMETHYL 5826-76-6 Xn 20/21/22 (2-)13
PHOSPHOROTHIOATE
1-CHLORO-1-NITROPROPANE 600-25-9 Xn 20/22 (2)
S-(6-CHLORO-2-OXOBENZOXAZOLIN-3-YLMETHYL) 2310-17-0 T,N 21-25-50/53 (1/2-)36/37-45-60-61
O,O-DIETHYL PHOSPHORODITHIOATE
1-CHLOROPENTANE 543-59-9 F,Xn 11-20/21/22 (2-)9-29 Note C
2-CHLOROPENTANE 625-29-6 F,Xn 11-20/21/22 (2-)9-29 Note C
3-CHLOROPENTANE 616-20-6 F,Xn 11-20/21/22 (2-)9-29 Note C
3-CHLORO-4,5,I,I,I-PENTAFLUOROTOLUENE 77227-99-7 Xn,N 10-20/22-50-58 (2-)51-60-61
CHLOROPHACINONE 3691-35-8 T+ 23-27/28-48/24/25 (1/2-)36/37-45
CHLOROPHENOL, all isomers Xn 20/21/22 (2-)28 Note C
4-CHLOROPHENOXYACETIC ACID 122-88-3 Xn 22 (2)
O-4-(4-CHLOROPHENYLAZO)PHENYL O,O-DIMETHYL 5834-96-8 Xn 20/22 (2-)13
PHOSPHOROTHIOATE
Page No. 9
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Substance CAS number Symbol Risk-phrases Safety phrases
4-CHLOROPHENYL BENZENESULPHONATE 80-38-6 Xn 22-36 (2-)24-26
(CHLOROPHENYL)(CHLOROTOLYL)METHANE N 50/53 60-61
2-(4-(3-(4-CHLOROPHENYL)-4,5- 106359-93-7 Xi,N 36-50/53 (2-)26-60-61
DIHYDROPYRAZOLYL)PHENYLSULPHONYL)ETHYL-
DIMETHYLAMMONIUM HYDROGEN PHOSPHONATE
3-(4-CHLOROPHENYL)-1,1-DIMETHYLUREA 150-68-5 Xn 22-40 (2-)36/37
4-(2-CHLOROPHENYLHYDRAZONO)-3-METHYL-5- 5707-69-7 T 25 (1/2-)22-24-36/37-45
ISOXAZOLONE
3-(4-CHLOROPHENYL)-1-METHOXY-1-METHYLUREA 1746-81-2 Xn 22 (2-)22
2-[2-(4-CHLOROPHENYL)-2-PHENYLACETYL]INDAN- 3691-35-8 T+ 23-27/28-48/24/25 (1/2-)36/37-45
1,3-DIONE
2-(4-(3-(4-CHLOROPHENYL)-2-PYRAZOLIN-1-YL) C,N 34-43-48/22-50/53 (1/2-)24-26-28-37/39-45-60-61
PHENYLSULPHONYL)ETHYLDIMETHYLAMMONIUM FORMATE
S-(4-CHLOROPHENYLTHIOMETHYL) O,O-DIETHYL 786-19-6 T,N 24/25-50/53 (1/2-)28-36/37-45-60-61
PHOSPHORODITHIOATE
2-CHLORO-1-PHTHALIMIDOETHYL O,O-DIETHYL 10311-84-9 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
PHOSPHORODITHIOATE
CHLOROPICRIN 76-06-2 T+ 22-26-36/37/38 (1/2-)36/37-38-45
CHLOROPRENE 126-99-8 F,Xn 11-20/22-36 (2-)16 Note D
1-CHLOROPROPANE 540-54-5 F,Xn 11-20/21/22 (2-)9-29 Note C
2-CHLOROPROPANE 75-29-6 F,Xn 11-20/21/22 (2-)9-29 Note C
3-CHLOROPROPENE 107-05-1 F,T+,N 11-26-50 (1/2-)16-29-33-45-61 Note D
2-CHLOROPROPIONIC ACID 598-78-7 C 22-35 (1/2-)23-26-28-36-45
CHLOROSULPHONIC ACID 7790-94-5 C 14-35-37 (1/2-)26-45
CHLOROSULPHURIC ACID 7790-94-5 C 14-35-37 (1/2-)26-45
CHLOROTHALONIL 1897-45-6 Xn 40 (2-)36/37
2-CHLOROTOLUENE 95-49-8 Xn,N 20-51/53 (2-)24/25-61 Note C
3-CHLOROTOLUENE 108-41-8 Xn,N 20-51/53 (2-)24/25-61 Note C
4-CHLOROTOLUENE 106-43-3 Xn,N 20-51/53 (2-)24/25-61 Note C
CHLOROTOLUENE 25168-05-2 Xn,N 20-51/53 (2-)24/25-61 Note C
I-CHLOROTOLUENE 100-44-7 T 22-23-37/38-40-41 (1/2-)36/37-38-45
N2-(4-CHLORO-o-TOLYL)-N1,N1-DIMETHYL- 6164-98-3 Xn 21/22-40 (2-)22-36/37
FORMAMIDINE
N2-(4-CHLORO-o-TOLYL)-N1,N1-DIMETHYL- 19750-95-9 Xn 20-40 (2-)22-36/37
FORMAMIDINE HYDROCHLORIDE
4-CHLORO-o-TOLYLOXYACETIC ACID 94-74-6 Xn 22-38-41 (2-)26-37-39
4-(2-CHLORO-4-TRIFLUOROMETHYL)PHENOXY-2- T,N 22-41-43-48/25-50/53 (1/2-)26-36/37/39-45-60-61
FLUOROANILINE HYDROCHLORIDE
3-CHLORO-5-TRIFLUOROMETHYL-2-PYRIDYLAMINE 79456-26-1 Xn 22-52/53 (2-)61
CHLOROTRINITROBENZENE (mix) 28260-61-9 E,T+ 2-26/27/28 (1/2-)35-45 Note C
CHLORPHONIUM CHLORIDE 115-78-6 T 21-25-36/38 (1/2-)36/37/39-45
CHLORPYRIFOS 2921-88-2 T,N 24/25-50/53 (1/2-)28-36/37-45-60-61
CHLORTHIAMID 1918-13-4 Xn 22 (2-)36
CHLORTHION 500-28-7 Xn 20/21/22 (2-)13
CHLORTHIOPHOS 21923-23-9 T+ 24-28 (1/2-)28-36/37-45
CHOLCHICINE 64-86-8 T+ 26/28 (1/2-)13-45
CHROMIC CHROMATE 24613-89-6 O,T,C,N 45-8-35-43-50/53 53-45-60-61
CHROMIC OXYCHLORIDE 14977-61-8 O,T,C,N 49-46-8-35-43-50/53 53-45-60-61 Note E
CHROMIUM III CHROMATE 24613-89-6 O,T,C,N 45-8-35-43-50/53 53-45-60-61
CHROMIUM VI COMPOUNDS with exception of T,N 49-43-50/53 53-45-60-61 Note A, E
BARIUM CHROMATE and compounds specified
elsewhere in this Annex
CHROMIUM TRIOXIDE 1333-82-0 O,T,C,N 49-8-25-35-43-50/53 53-45-60-61 Note E
CHROMYL DICHLORIDE 14977-61-8 O,T,C,N 49-46-8-35-43-50/53 53-45-60-61 Note E
C.I. DIRECT BLACK 38 1937-37-7 T 45-63 53-45
C.I. DIRECT BLUE 6 2602-46-2 T 45-63 53-45
C.I. DIRECT BROWN 95 16071-86-6 T 45 53-45
C.I. DIRECT RED 28 573-58-0 T 45-63 53-45
C.I. SOLVENT YELLOW 34 492-80-8 Xn,N 22-36-40-51/53 (2-)36/37-61
CINERIN I 25402-06-6 Xn 22 (2)
CINERIN II 121-20-0 Xn 22 (2)
CITRAL 5392-40-5 Xi 38-43 (2-)24/25-37
CLOFOP-ISOBUTYL 51337-71-4 Xn 22 (2)
Page No. 10
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Substance CAS number Symbol Risk-phrases Safety phrases
CLOPYRALID 1702-17-6 Xi,N 41-51/53 (2-)26-39-61
COBALT 7440-48-4 Xn 42/43 (2-)22-24-37
COBALT OXIDE 1307-96-6 Xn 22-43 (2-)24-37
COBALT SULPHIDE 1317-42-6 Xi 43 (2-)24-37
COLCHICINE 64-86-8 T+ 26/28 (1/2-)13-45
COLOPHONY 8050-09-7 Xn 43 (2-)24-37
COPPER CHLORIDE 7758-89-6 Xn 22 (2-)22
COPPER(I) O,O-DIISOPROPYL PHOSPHORODITHIOATE N 50/53 60-61
and COPPER(I) O-ISOPROPYL O-(4-METHYLPENT-
2-YL) PHOSPHORODITHIOATE and COPPER(I)
O,O-BIS(4-METHYLPENT-2-YL) PHOSPHORODITHIOATE
COPPER NAPHTHENATE 1338-02-9 Xn 10-22 (2)
COPPER (I) OXIDE 1317-39-1 Xn 22 (2-)22
COPPER SULPHATE 7758-98-7 Xn 22-36/38 (2-)22
COUMACHLOR 81-82-3 Xn 48/22 (2-)37
COUMAFURYL 117-52-2 T 25-48/25 (1/2-)37-45
COUMAPHOS 56-72-4 T+,N 21-28-50/53 (1/2-)28-36/37-45-60-61
COUMATETRALYL 5836-29-3 T+ 27/28-48/24/25 (1/2-)36/37-45
COUMITHOATE 572-48-5 T 25 (1/2-)28-36/37-45
4-CPA 122-88-3 Xn 22 (2)
CRESOL, all isomers T 24/25-34 (1/2-)36/37/39-45 Note C
CRESYL GLYCIDYL ETHER 26447-14-3 Xi 38 (2-)26-28 Note C
CRIMIDINE 535-89-7 T+ 28 (1/2-)36/37-45
CROTONALDEHYDE 123-73-9 F,T 11-23-36/37/38 (1/2-)29-33-45
CROTOXYPHOS 7700-17-6 T 24/25 (1/2-)28-36/37-45
CRUFOMATE 299-86-5 Xn,N 21/22-50-53 (2-)36/37-60-61
CRYOLITE 15096-52-3 T 20/22-48/23/25 (1/2-)22-37-45
CUMENE 98-82-8 Xi 10-37 (2) Note C
CUMENE HYDROPEROXIDE 80-15-9 O,C 7-20/22-34 (1/2-)3/7-14-36/37/39-45-50
CUMITHOATE 572-48-5 T 25 (1/2-)28-36/37-45
CYANAMIDE 420-04-2 T 21-25-36/38-43 (1/2-)3-22-36/37-45
CYANAZINE 21725-46-2 Xn 22 (2-)37
CYANIDES, with the exception of COMPLEX T+ 26/27/28-32 (1/2-)7-28-29-45 Note A
CYANIDES as FERROCYANIDES, FERRICYANIDES
and MERCURIC OXOCYANIDE
S-[N-(1-CYANO-1-METHYLETHYL)CARBAMOYLMETHYL] 3734-95-0 T+ 24-28 (1/2-)36/37-45
O,O-DIETHYL PHOSPHOROTHIOATE
CYANOFENPHOS 13067-93-1 T 21-25-36-39/25 (1/2-)36/37-45
CYANOGEN 460-19-5 F,T 11-23 (1/2-)23-45
O-4-CYANOPHENYL O,O-DIMETHYL PHOSPHOROTHIOATE 2636-26-2 Xn,N 21/22-50/53 (2-)36/37-60-61
CYANOPHOS 2636-26-2 Xn,N 21/22-50/53 (2-)36/37-60-61
2-CYANOPROPAN-2-OL 75-86-5 T+,N 26/27/28-50 (1/2-)7/9-27-45-61
CYANTHOATE 3734-95-0 T+ 24-28 (1/2-)36/37-45
CYANURIC CHLORIDE 108-77-0 Xi 36/37/38 (2-)28
CYCLOBUTANE-1,3-DIONE 15506-53-3 F 11 (2-)9-16-33
CYCLOHEXANE 110-82-7 F 11 (2-)9-16-33
CYCLOHEXANE-1,2-DICARBOXYLIC ANHYDRIDE 85-42-7 Xi 36/37/38 (2-)23-39CYCLOHEXANOL 108-93-0 Xn 20/22-37/38 (2-)24/25
CYCLOHEXANONE 108-94-1 Xn 10-20 (2-)25
CYCLOHEXANONE PEROXIDE, mixture 12262-58-7 E,C 2-7-22-34 (1/2-)3/7-14-36/37/39-45 Note C
CYCLOHEX-4-ENE-1,2-DICARBOXYLIC ANHYDRIDE 85-43-8 Xi 36/37 (2-)25
CYCLOHEXYL ACRYLATE 3066-71-5 Xi 37/38 (2) Note D
CYCLOHEXYLAMINE 108-91-8 C 10-21/22-34 (1/2-)36/37/39-45
2-CYCLOHEXYL-4,6-DINITROPHENOL 131-89-5 T 23/24/25 (1/2-)13-45
CYCLOOCT-4-EN-1-YL METHYL CARBONATE 87731-18-8 Xi 43 (2-)24-37
CYCLOPENTANE 287-92-3 F 11 (2-)9-16-29-33
CYCLOPENTANE-1,2,3,4-TETRACARBOXYLIC 6053-68-5 Xi 36/37 (2-)25
DIANHYDRIDE
CYCLOPENTANONE 120-92-3 Xi 10-36/38 (2-)23
CYCLOPROPANE 75-19-4 F+ 12 (2-)9-16-33
CYHEXATIN 13121-70-5 Xn 20/21/22 (2-)13
CHYMOTRYPSIN 9004-07-3 Xn 36/37/38-42 (2-)22-24-26-36/37
2,4-D 94-75-7 Xn 22-36/37/38 (2-)36/37
Page No. 11
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Substance CAS number Symbol Risk-phrases Safety phrases
2,4-D, SALTS and ESTERS Xn 20/21/22 (2-)13 Note A
DALAPON 75-99-0 Xn 22-38-41 (2-)26-39
DAMINOZIDE 1596-84-5 Xn 40 (2-)36/37
DAPSONE 80-08-0 Xn 22 (2-)22
DAZOMET 533-74-4 Xn 22-36 (2-)15-22-24
2,4-DB 94-82-6 Xn 21/22 (2-)36/37
2,4-DB, SALTS Xn 20/21/22 (2-)13 Note A
DDT 50-29-3 T,N 25-40-48/25-50/53 (1/2-)22-36/37-45-60-61
DECACHLOROPENTACYCLO 143-50-0 T 24/25-40 (1/2-)22-36/37-45
(5.2.1.02,6.03,9.05,8) DECAN-4-ONE
DECARBOFURAN 1563-67-3 T 23/24/25 (1/2-)13-36/37-45
DEHYDRACETIC ACID 520-45-6 Xn 22 (2)
DEMEPHION-O 682-80-4 T+ 24-28 (1/2-)28-36/37-45
DEMEPHION-S 2587-90-8 T+ 24-28 (1/2-)28-36/37-45
DEMETON 8065-48-3 T+,N 27/28-50 (1/2-)28-36/37-45-61
DEMETON-O 298-03-3 T+,N 27/28-50 (1/2-)28-36/37-45-60-61
DEMETON-O-METHYL 867-27-6 T 25 (1/2-)24-36/37-45
DEMETON-S 126-75-0 T+ 27/28 (1/2-)28-36/37-45
DEMETON-S-METHYL 919-86-8 T,N 24/25-51/53 (1/2-)28-36/37-45-61
DEMETON-S-METHYL SULPHONE 17040-19-6 T 21-25 (1/2-)22-28-36/37-45
2,4-DES 149-26-7 Xn 22-38-41 (2-)26
DESMETRYNE 1014-69-3 Xn 21/22 (2-)36/37
DIACETONE ALCOHOL 123-42-2 F,Xi 11-36 (2-)7-16-24/25
DIACETONE ALCOHOL, TECHNICAL 123-42-2 F,Xi 11-36 (2-)7-16-24/25
N,N'-DIACETYLBENZIDINE 613-35-4 Xn 20/21/22 (2-)22-36
DIALIFOS 10311-84-9 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
DI-ALLATE 2303-16-4 Xn 22-40 (2-)25-36/37
N,N-DIALLYLCHLOROACETAMIDE 93-71-0 Xn 21/22-36/38 (2-)26-28-36/37/39
DIALLYL PHTHALATE 131-17-9 Xn 22 (2-)24/25
4,4'-DIAMINOBIPHENYL 92-87-5 T,N 45-22-50/53 53-45-60-61 Note E
4,4'-DIAMINODIPHENYLMETHANE 101-77-9 T,N 45-20/21/22-43- 53-45-61 Note E
48/20/21-51/53
4,4'-DIAMINO DIPHENYL SULPHONE 80-08-0 Xn 22 (2-)22
1,2-DIAMINOETHANE 107-15-3 C 10-21/22-34-42/43 (1/2-)23-26-36/37/39-45
2,5-DIAMINOTOLUENE SULPHATE 6369-59-1 T,N 20/21-25-43-50/53 (1/2-)24-37-45-60-61
S-(4,6-DIAMINO-1,3,5-TRIAZIN-2-YLMETHYL) 78-57-9 Xn 22-52/53 (2-)61
O,O-DIMETHYL PHOSPHORODITHIOATE
DIAMMINEDIISOCYANATOZINC Xn,N 22-41-42/43-50 (2-)22-26-36/37/39-41-61
o-DIANISIDINE 119-90-4 T 45-22 53-45 Note E
o-DIANISIDINE, SALTS T 45-22 53-45 Note A, E
3,6-DIAZAOCTANE-1,8-DIAMINE 112-24-3 C 21-34-43-52/53 (1/2-)26-36/37/39-45-61
DIAZINON 333-41-5 Xn,N 22-50/53 (2-)24/25-60-61
DIAZOMETHANE 334-88-3 T 45 53-45
DIBENZ[a,h]ANTHRACENE 53-70-3 T 45 53-45
DIBENZOYL PEROXIDE 94-36-0 E,Xi 2-7-36-43 (2-)3/7-14-36/37/39
1,2-DIBROMO-3-CHLOROPROPANE 96-12-8 T 45-46-60-25-48/20/22- 53-45-61 Note E
52/53
O-1,2-DIBROMO-2,2-DICHLOROETHYL 300-76-5 Xn 21/22-36/38 (2-)36/37
DIMETHYL PHOSPHATE
1,2-DIBROMOETHANE 106-93-4 T,N 45-23/24/25-36/37/38- 53-45-61 Note E
51/53
3,5-DIBROMO-4-HYDROXYBENZALDEHYDE 13181-17-4 Xn 22 (2-)25
O-(2,4-DINITROPHENYL) OXIME
3,5-DIBROMO-4-HYDROXYBENZONITRILE 1689-84-5 T 25-63 (1/2-)36/37-45
DIBROMOMETHANE 74-95-3 Xn 20-52/53 (2-)24-61
DI-n-BUTYLAMINE 111-92-2 Xn 10-20/21/22 (2)
DI-sec-BUTYLAMINE 626-23-3 Xn 10-20/21/22 (2)
DIBUTYL ETHER 142-96-1 Xi 10-36/37/38 (2)
DI-n-BUTYL ETHER 142-96-1 Xi 10-36/37/38 (2)
DI-tert-BUTYL PEROXIDE 110-05-4 O,F 7-11 (2-)3/7-14-16-36/37/39
DIBUTYLTIN HYDROGEN BORATE 75113-37-0 T,N 21/22-41-43-48/25-50/53 (1/2-)22-26-36/37-45-60-61
DICHLOBENIL 1194-65-6 Xn 21 (2-)36/37
DICHLOFENTHION 97-17-6 Xn,N 22-50/53 (2)-60-61
Page No. 12
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Substance CAS number Symbol Risk-phrases Safety phrases
DICHLOFLUANID 1085-98-9 Xi,N 36-43-50/53 (2-)22-24-60-61
DICHLONE 117-80-6 Xn 22-36/38 (2-)26
DICHLOROACETIC ACID 79-43-6 C 35 (1/2-)26-45
DICHLOROACETYL CHLORIDE 79-36-7 C 35 (1/2-)9-26-45
DICHLOROACETYLENE 7572-29-4 E,Xn 2-40-48/20 (2-)36/37
S-2,3-DICHLOROALLYL DIISOPROPYLTHIOCARBAMATE 2303-16-4 Xn 22-40 (2-)25-36/37
DICHLOROANILINE T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61 Note C
1,2-DICHLOROBENZENE 95-50-1 Xn,N 22-36/37/38-50/53 (2-)23-60-61
1,3-DICHLOROBENZENE 541-73-1 Xn,N 22-51/53 (2-)61
1,4-DICHLOROBENZENE 106-46-7 Xn 22-36/38 (2-)22-24/25-46
o-DICHLOROBENZENE 95-50-1 Xn,N 22-36/37/38-50/53 (2-)23-60-61
p-DICHLOROBENZENE 106-46-7 Xn 22-36/38 (2-)22-24/25-46
3,3'-DICHLOROBENZIDINE 91-94-1 T,N 45-21-43-50/53 53-45-60-61 Note E
3,3'-DICHLOROBENZIDINE, SALTS T,N 45-21-43-50/53 53-45-60-61 Note A, E
2,6-DICHLOROBENZONITRILE 1194-65-6 Xn 21 (2-)36/37
3,3'-DICHLOROBIPHENYL-4,4'-YLENEDIAMINE 91-94-1 T,N 45-21-43-50/53 53-45-60-61 Note E
3,3'-DICHLOROBIPHENYL-4,4'-YLENEDIAMINE, SALTS T,N 45-21-43-50/53 53-45-60-61 Note A, E
1,4-DICHLOROBUT-2-ENE 764-41-0 T+,N 45-24/25-26-34-50/53 53-45-60-61 Note E
DICHLORO 76253-60-6 N 50/53 60-61
[(DICHLOROPHENYL)METHYL]METHYLBENZENE
2,2'-DICHLORODIETHYL ETHER 111-44-4 T+ 10-26/27/28-40 (1/2-)7/9-27-38-45
3,5-DICHLORO-2,4-DIFLUOROBENZOYL FLUORIDE 101513-70-6 T,C 22-23-29-34-43-52/53 (1/2-)26-36/37/39-45-61
1,1-DICHLOROETHANE 75-34-3 F,Xn 11-22-36/37-52/53 (2-)16-23-61
1,2-DICHLOROETHANE 107-06-2 F,T 45-11-22-36/37/38 53-45 Note E
1,1-DICHLOROETHYLENE 75-35-4 F+,Xn 12-20-40 (2-)7-16-29 Note D
1,2-DICHLOROETHYLENE 540-59-0 F,Xn 11-20-52/53 (2-)7-16-29-61 Note C
cis-DICHLOROETHYLENE 156-59-2 F,Xn 11-20-52/53 (2-)7-16-29-61 Note C
trans-DICHLOROETHYLENE 156-60-5 F,Xn 11-20-52/53 (2-)7-16-29-61 Note C
1,3-DICHLORO-5-ETHYL-5-METHYLIMIDAZOLIDINE- 89415-87-2 O,T+,N 8-22-26-34-43-50 (1/2-)8-26-36/39-45-61
2,4-DIONE
2,4-DICHLORO-3-ETHYLPHENOL C,N 34-50/53 (1/2-)26-36/39-45-60-61
N'-DICHLOROFLUOROMETHYLTHIO-N,N-DIMETHYL-N'- 1085-98-9 Xi,N 36-43-50/53 (2-)22-24-60-61
PHENYLSULPHAMIDE
N-(DICHLOROFLUOROMETHYLTHIO)PHTHALIMIDE 719-96-0 Xi 38 (2-)28
DICHLOROISOCYANURIC ACID 2782-57-2 O,Xn 8-22-31-36/37 (2-)8-26-41
DICHLOROISOCYANURIC ACID, SODIUM SALT, 2893-78-9 O,Xn 8-22-31-36/37 (2-)8-26-41
and POTASSIUM SALT 2244-21-5
DICHLOROMETHANE 75-09-2 Xn 40 (2-)23-24/25-36/37
2,2'-DICHLORO-4,4'-METHYLENEDIANILINE 101-14-4 T,N 45-22-50/53 53-45-60-61 Note E
2,2'-DICHLORO-4,4'-METHYLENEDIANILINE, SALTS T,N 45-22-50/53 53-45-60-61 Note A, E
2,3-DICHLORO-1,4-NAPHTHOQUINONE 117-80-6 Xn 22-36/38 (2-)26
1,1-DICHLORO-1-NITROETHANE 594-72-9 T 23/24/25 (1/2-)26-45
DICHLOROPHEN 97-23-4 Xn 22-36 (2-)26
2,4-DICHLOROPHENOL 120-83-2 C,N 21/22-34-51/53 (1/2-)26-36/37/39-45-61
2,4-DICHLOROPHENOXYACETIC ACID 94-75-7 Xn 22-36/37/38 (2-)36/37
4-(2,4-DICHLOROPHENOXY) BUTYRIC ACID 94-82-6 Xn 21/22 (2-)36/37
2-(2,4-DICHLOROPHENOXY)ETHYL HYDROGENSULPHATE 149-26-8 Xn 22-38-41 (2-)26
2-(2,4-DICHLOROPHENOXY) PROPIONIC ACID 120-36-5 Xn 21/22-38-41 (2-)26-36/37
O-(2,4-DICHLOROPHENYL) O,O-DIETHYL 97-17-6 Xn,N 22-50/53 (2)-60-61
PHOSPHOROTHIOATE
3-(3,4-DICHLOROPHENYL)-1,1-DIMETHYLUREA 330-54-1 Xn 48/22 (2-)22-37
1-(3,4-DICHLOROPHENYLIMINO) THIOSEMICARBAZIDE 5836-73-7 T+ 28 (1/2-)22-36/37-45
3-(3,4-DICHLOROPHENYL)-1-METHOXY-1-METHYLUREA 330-55-2 Xn 40 (2-)36/37
S-(2,5-DICHLOROPHENYLTHIOMETHYL) O,O-DIETHYL 2275-14-1 T,N 23/24/25-50/53 (1/2-)13-45-60-61
PHOSPHORODITHIOATE
1,2-DICHLOROPROPANE 78-87-5 F,Xn 11-20/22 (2-)16-24
1,3-DICHLORO-2-PROPANOL 96-23-1 T 45-21-25 53-45 Note E
1,1-DICHLOROPROPENE 563-58-6 F,T 11-25-52/53 (1/2-)16-29-33-45-61
1,3-DICHLOROPROPENE 542-75-6 T,N 10-20/21-25-36/37/38- (1/2-)36/37-45-60-61 Note D, C
43-50/53
(Z)-1,3-DICHLOROPROPENE 10061-01-5 T,N 10-20/21-25-36/37/38- (1/2-)36/37-45-60-61 Note D, C
43-50/53
3',4'-DICHLOROPROPIONANILIDE 709-98-8 Xn 22 (2-)22
Page No. 13
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Substance CAS number Symbol Risk-phrases Safety phrases
2,2-DICHLOROPROPIONIC ACID 75-99-0 Xn 22-38-41 (2-)26-39
3,6-DICHLOROPYRIDINE-2-CARBOXYLIC ACID 1702-17-6 Xi,N 41-51/53 (2-)26-39-61
2,4-DICHLORO-I-(PYRIMIDIN-5-YL) 26766-27-8 Xn 22 (2)
BENZHYDRYL ALCOHOL
3,7-DICHLOROQUINOLINE-8-CARBOXYLIC ACID 84-087-01-4 Xi 43 (2-)24-37
3,5-DICHLORO-4-(1,1,2,2-TETRAFLUOROETHOXY) 104147-32-2 Xn,N 22-50/53 (2-)24/25-26-57-60-61
ANILINE
2,6-DICHLORO (THIOBENZAMIDE) 1918-13-4 Xn 22 (2-)36
I,I-DICHLOROTOLUENE 98-87-3 T 22-23-36/37-38-40-41 (1/2-)36/37-38-45
DICHLORO-1,3,5-TRIAZINETRIONE 2782-57-2 O,Xn 8-22-31-36/37 (2-)8-26-41
DICHLORO-1,3,5-TRIAZINETRIONE, SODIUM SALT, 2893-78-9 O,Xn 8-22-31-36/37 (2-)8-26-41
POTASSIUM SALT 2244-21-5
2,2-DICHLOROVINYL DIMETHYL PHOSPHATE 62-73-7 T 24/25 (1/2-)23-36/37-45
2,2-DICHLOROVINYL-2-ETHYLSULPHINYLETHYL 7076-53-1 T 23/24/25 (1/2-)13-45
METHYL PHOSPHATE
DICHLORPROP 120-36-5 Xn 21/22-38-41 (2-)26-36/37
DICHLORPROP, SALTS Xn 20/21/22 (2-)13 Note A
DICHLORVOS 62-73-7 T 24/25 (1/2-)23-36/37-45
DICHROMIUM TRIS(CHROMATE) 24613-89-6 O,T,C,N 45-8-35-43-50/53 53-45-60-61
DICLOFOP-METHYL 51338-27-3 Xn 22 (2)
DICOFOL 115-32-2 Xn 21/22-38-43 (2-)36/37
DICOUMARIN 66-76-2 T 22-48/25 (1/2-)37-45
DICROTOPHOS 141-66-2 T+,N 24-28-50/53 (1/2-)28-36/37-45-60-61
DICUMYL PEROXIDE 80-43-3 O,Xi 7-36/38 (2-)3/7-14-36/37/39
5,10-DIHYDRO-5,10-DIOXONAPHTHO(2,3-b)(1,4)- 3347-22-6 Xn 22 (2-)24
DITHIAZINE-2,3-DICARBONITRILE
DICYCLOHEXYLAMINE 101-83-7 C,N 22-34-50/53 (1/2-)26-36/37/39-45-60-61
DICYCLOHEXYLAMMONIUM NITRITE 3129-91-7 Xn 20/22 (2-)15-41
DICYCLOHEXYLCARBODIIMIDE 538-75-0 T 22-24-41-43 (1/2-)24-26-37/39-45
DICYCLOHEXYLMETHANE-4,4'-DIISOCYANATE 5124-30-1 T 23-36/37/38-42/43 (1/2-)26-28-38-45
DIELDRIN 60-57-1 T+,N 25-27-40-48/25-50/53 (1/2-)22-36/37-45-60-61
1,2,3,4-DIEPOXYBUTANE 1464-53-5 T 23/24/25-36/37/38-40-
42/43 (1/2-)23-24-45
DIETHANOLAMINE 111-42-2 Xi 36/38 (2-)26
DIETHANOLAMINE SALT of 4-CPA Xn 22 (2)
1,1-DIETHOXYETHANE 105-57-7 F,Xi 11-36/38 (2-)9-16-33
I-(DIETHOXYPHOSPHINOTHIOYLIMINO) 14816-18-3 Xn 22 (2-)36
PHENYL ACETONITRILE
DIETHYLAMINE 109-89-7 F,C 11-20/21/22-35 (1/2-)3-16-26-29-36/37/39-45
2-DIETHYLAMINOETHANOL 100-37-8 Xi 36/37/38 (2-)28
2-DIETHYLAMINOETHYL METHACRYLATE 105-16-8 Xn 20-36/38-43 (2-)26 Note D
2,6-DIETHYLANILINE 579-66-8 Xn 22 (2-)23-34
N,N-DIETHYLANILINE 91-66-7 T,N 23/24/25-33-51/53 (1/2-)28-37-45-61
DIETHYLCARBAMOYL CHLORIDE 88-10-8 Xn 20/22-36/37/38-40 (2-)26-36/37
N,N-DIETHYL-1,3-DIAMINOPROPANE 104-78-9 C 10-21/22-34-43 (1/2-)26-36/37/39-45
O,O-DIETHYL O-2-DIETHYLAMINO-6- 23505-41-1 T,N 21-25-50/53 (1/2-)23-36/37-45-60-61
METHYLPYRIMIDIN-4-YL PHOSPHOROTHIOATE
DIETHYLENE GLYCOL DIACRYLATE 4074-88-8 T 24-36/38-43 (1/2-)28-39-45 Note D
DIETHYLENE GLYCOL DINITRATE 693-21-0 E,T+ 3-26/27/28-33 (1/2-)33-35-36/37-45
DIETHYLENETRIAMINE 111-40-0 C 21/22-34-43 (1/2-)26-36/37/39-45
DIETHYL ETHER 60-29-7 F+ 12-19 (2-)9-16-29-33
DIETHYL(ETHYLDIMETHYLSILANOLATO)ALUMINIUM 55426-95-4 F,C 14/15-17-35 (1/2-)6-16-30-36/39-43-45
O,O-DIETHYL S-[2-(ETHYLSULPHINYL)ETHYL] 2497-07-6 T+ 24-28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
O,O-DIETHYL-O-[2-(ETHYLTHIO)ETHYL] PHOSPHORO- 298-03-3 T+,N 27/28-50 (1/2-)28-36/37-45-61
THIOATE
O,O-DIETHYL-S-[2-(ETHYLTHIO)ETHYL] PHOSPHORO- 298-04-4 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
DITHIOATE
DIETHYL-S-[2-(ETHYLTHIO)ETHYL] PHOSPHORO- 126-75-0 T+ 27/28 (1/2-)28-36/37-45
THIOATE
O,O-DIETHYL ETHYLTHIOMETHYL 298-02-2 T+ 27/28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
O,O-DIETHYL ISOPROPYLCARBAMOYLMETHYL 2275-18-5 T+ 27/28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
Page No. 14
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Substance CAS number Symbol Risk-phrases Safety phrases
O,O-DIETHYL-O-2-ISOPROPYL-6-METHYL- 333-41-5 Xn,N 22-50/53 (2-)24/25-60-61
PYRIMIDIN-4-YL PHOSPHOROTHIOATE
DIETHYL KETONE 96-22-0 F 11 (2-)9-16-33
O,O-DIETHYL-O-(4-METHYLCOUMARIN-7-YL) 299-45-6 T+ 26/27/28 (1/2-)13-28-45
PHOSPHOROTHIOATE
DIETHYL 4-METHYL-1,3-DITHIOLAN- 950-10-7 T+,N 27/28-51/53 (1/2-)36/37/39-45-61
2-YLIDENEPHOSPHOROAMIDATE
DIETHYL 3-METHYLPYRAZOL-5-YL PHOSPHATE 108-34-9 T+ 26/27/28 (1/2-)13-28-45
O,O-DIETHYL O-[4-(METHYLSULPHINYL)PHENYL] 115-90-2 T+,N 27/28-50/53 (1/2-)23-28-36/37-45-60-61
PHOSPHOROTHIOATE
O,O-DIETHYL O-4-NITROPHENYL PHOSPHOROTHIOATE 56-38-2 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
DIETHYL OXALATE 95-92-1 Xn 22-36 (2-)23
S-(O,O-DIETHYL 4-OXOBENZOTRIAZIN-3-YLMETHYL 2642-71-9 T+ 24-28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
N,N-DIETHYL-p-PHENYLENDIAMINE 93-05-0 T 25-34 (1/2-)26-36-45
DIETHYL SULPHATE 64-67-5 T 45-46-20/21/22-34 53-45 Note E
O,O-DIETHYL O-7,8,9,10-TETRAHYDRO-6- 572-48-5 T 25 (1/2-)28-36/37-45
OXOBENZO[c]CHROMEN-3-YL PHOSPHOROTHIOATE
N,N-DIETHYL-m-TOLUAMIDE 134-62-3 Xn 22-36/38 (2)
O,O-DIETHYL O-3,5,6-TRICHLORO-2-PYRIDYL 2921-88-2 T,N 24/25-50/53 (1/2-)28-36/37-45-60-61
PHOSPHOROTHIOATE
DIFENACOUM 56073-07-5 T+ 28-48/25 (1/2-)36/37-45
DIFENZOQUAT-METHYLSULPHATE 43222-48-6 Xn 22 (2)
DIGITOXIN 71-63-6 T 23/25-33 (1/2-)-45
DIGOL DINITRATE 693-21-0 E,T+ 3-26/27/28-33 (1/2-)33-35-36/37-45
9,10-DIHYDRO-8a,10a-DIAZONIAPHENANTHRENE ION 2764-72-9 T 24/25-36/37/38 (1/2-)22-36/37/39-45
2,3-DIHYDRO-2,2-DIMETHYLBENZOFURAN-7-YL 1563-66-2 T+ 26/28 (1/2-)36/37-45
METHYLCARBAMATE
2,3-DIHYDRO-5-METHOXY-2-OXO-1,3,4-THIADIAZOL- 950-37-8 T+,N 21-28-50/53 (1/2-)22-28-36/37-45-60-61
3-YLMETHYL-O,O-DIMETHYL PHOSPHORODITHIOATE
2,3-DIHYDRO-2-METHYLBENZOFURAN-7-YL 1563-67-3 T 23/24/25 (1/2-)13-36/37-45
METHYLCARBAMATE
1,2-DIHYDROXYBENZENE 120-80-9 Xn 21/22-36/38 (2-)22-26-37
1,4-DIHYDROXYBENZENE 123-31-9 Xn 20/22 (2-)24/25-39
DI-ISOBUTYLENE 107-39-1 F 11 (2-)9-16-29-33
DI-ISOBUTYL KETONE 108-83-8 Xi 10-37 (2-)24
2,6-DI-ISOCYANATE TOLUENE 91-08-7 T 23-36/37/38-42 (1/2-)23-26-28-38-45 Note C
DI-ISOPROPANOLAMINE 110-97-4 Xi 36 (2-)26
DI-ISOPROPYL ETHER 108-20-3 F 11-19 (2-)9-16-33
DI-ISOPROPYL KETONE 565-80-0 F 11 (2-)16-23
O,O-DIISOPROPYL 2-PHENYLSULPHONYL- 741-58-2 Xn 22 (2-)24-36
AMINOETHYL PHOSPHORODITHIOATE
N,N'-DIISOPROPYLPHOSPHORODIAMINIC FLUORIDE 371-86-8 T+ 39/26/27/28 (1/2-)13-45
DIKETENE 674-82-8 Xn 10-20 (2-)3 Note D
DILAUROYL PEROXIDE 105-74-8 O 7 (2-)3/7-14-36/37/39
DILITHIUM 6-ACETAMIDO-4-HYDROXY-3-(4-((2- Xi 43 (2-)24-37
SULPHONATOOXY)ETHYLSULPHONYL)PHENYLAZO)
NAPHTHALENE-2-SULPHONATE
DIMEFOX 115-26-4 T+ 27/28 (1/2-)23-28-36/37-38-45
DIMEPRANOL 108-16-7 C 10-22-34 (1/2-)23-26-36-45
DIMERCURY DICHLORIDE 10112-91-1 Xn 22-36/37/38 (2-)13-24/25-46
DIMETAN 122-15-6 T 25 (1/2-)36/37-45
DIMETHOATE 60-51-5 Xn 21/22 (2-)36/37
3,3'-DIMETHOXYBENZIDINE 119-90-4 T 45-22 53-45 Note E
3,3'-DIMETHOXYBENZIDINE, SALTS T 45-22 53-45 Note A, E
1,1-DIMETHOXYETHANE 534-15-6 F 11 (2-)9-16-33
1,2-DIMETHOXYETHANE 110-71-4 Xn 10-19-20 (2-)24/25
DIMETHYL ACETAL 534-15-6 F 11 (2-)9-16-33
N,N-DIMETHYLACETAMIDE 127-19-5 Xn 20/21-36 (2-)26-28-36
O,S-DIMETHYL ACETYLPHOSPHORAMIDOTHIOATE 30560-19-1 Xn 22 (2-)36
2-DIMETHYLAMINO-5,6-DIMETHYLPYRIMIDIN-4-YL 23103-98-2 T 25 (1/2-)22-37-45
DIMETHYLCARBAMATE
2-DIMETHYLAMINOETHANOL 108-01-0 Xi 10-36/37/38 (2-)28
Page No. 15
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Substance CAS number Symbol Risk-phrases Safety phrases
2-DIMETHYLAMINOETHYLAMINE 108-00-9 F,C 11-21/22-35 (1/2-)16-23-26-28-36-45
3-DIMETHYLAMINOMETHYLENEAMINOPHENYL 22259-30-9 T+ 28 (1/2-)22-36/37-45
METHYLCARBAMATE
2-DIMETHYLAMINOETHYL METHACRYLATE 2867-47-2 Xn 21/22-36/38-43 (2-)26-28 Note D
3-(DIMETHYLAMINO)PROPYLUREA 31506-43-1 Xi 41 (2-)26-39
N-DIMETHYLAMINOSUCCINAMIC ACID 1596-84-5 Xn 40 (2-)36/37
4-DIMETHYLAMINO-3-TOLYL METHYLCARBAMATE 2032-59-9 T 24/25 (1/2-)28-36/37-45
4-DIMETHYLAMINO-3,5-XYLYL METHYLCARBAMATE 315-18-4 T+ 21-28 (1/2-)36/37-45
N,N-DIMETHYLANILINE 121-69-7 T,N 23/24/25-40-51/53 (1/2-)28-36/37-45-61
2,2'-DIMETHYL-2,2'AZODIPROPIONITRILE 78-67-1 E,Xn 2-11-20/22 (2-)39-41-47
N,N-DIMETHYLBENZENE-1,3-DIAMINE 2836-04-6 T 23/24/25 (1/2-)28-45 Note C
N,N'-DIMETHYLBENZENE-1,4-DIAMINE 99-98-9 T 23/24/25 (1/2-)28-45 Note C
3,3'-DIMETHYLBENZIDINE 119-93-7 T,N 45-22-51/53 53-45-61 Note E
3,3'-DIMETHYLBENZIDINE, SALTS T,N 45-22-51/53 53-45-61 Note A, E
N,N'-DIMETHYLBENZIDINE 2810-74-4 Xn 20/21/22 (2-)22-36
2,2-DIMETHYL-1,3-BENZODIOXOL-4-OL 22961-82-6 Xi 41 (2-)24-26-39
I,I-DIMETHYLBENZYL HYDROPEROXIDE 80-15-9 O,C 7-20/22-34 (1/2-)3/7-14-36/37/39-45-50
1,1'-DIMETHYL-4,4'-BIPYRIDINIUM ION 4685-14-7 T 24/25-36/37/38 (1/2-)22-36/37/39-45
DIMETHYLCARBAMOYL CHLORIDE 79-44-7 T 45-22-23-36/37/38 53-45 Note E
1-DIMETHYLCARBAMOYL-5-METHYLPYRAZOL-3-YL 644-64-4 T 21-25 (1/2-)36/37-45
DIMETHYLCARBAMATE
DIMETHYL CARBONATE 616-38-6 F 11 (2-)9-16
N,N-DIMETHYL-2-(3-(4-CHLOROPHENYL)-4,5- 10357-99-0 Xn,N 43-48/22-51/53 (2-)24-37-61
DIHYDROPYAZOL-1-YLPHENYLSULPHONYL)ETHYLAMINE
1,4-DIMETHYLCYCLOHEXANE 589-90-2 F 11 (2-)9-16-33
N,N-DIMETHYL-1,3-DIAMINOPROPANE 109-55-7 C 10-22-34-43 (1/2-)26-36/37/39-45
DIMETHYLDICHLOROSILANE 75-78-5 F,Xi 11-36/37/38 (2)
DIMETHYL cis-2-DIMETHYLCARBAMOYL-1- 141-66-2 T+,N 22-28-50/53 (1/2-)28-36/37-45-60-61
METHYLVINYL PHOSPHATE
N,N-DIMETHYL-2,2-DIPHENYLACETAMIDE 957-51-7 Xn 22 (2)
DIMETHYL ETHER 115-10-6 F+ 12 (2-)9-16-33
DIMETHYL FORMAMIDE 68-12-2 T 61-20/21-36 53-45 Note E
N,N-DIMETHYLFORMAMIDE 68-12-2 T 61-20/21-36 53-45 Note E
2,6-DIMETHYLHEPTAN-4-ONE 108-83-8 Xi 10-37 (2-)24
1,2-DIMETHYLHYDRAZINE 540-73-8 T 45-23/24/25 53-45 Note E
N,N-DIMETHYLHYDRAZINE 57-14-7 F,T 45-11-23/25-34 53-45 Note E
1,2-DIMETHYLIMIDAZOLE 1739-84-0 Xn 22-38-41 (2-)24-26
O,O-DIMETHYL-S-2-(1-METHYLCARBAMOYLETHYL- 2275-23-2 T,N 21-25-50 (1/2-)36/37-45-61
THIO)ETHYL PHOSPHOROTHIOATE
O,O-DIMETHYL METHYLCARBAMOYLMETHYL 60-51-5 Xn 21/22 (2-)36/37
PHOSPHORODITHIOATE
O,O-DIMETHYL-S-METHYLCARBAMOYLMETHYL 1113-02-6 T,N 21-25-50 (1/2-)23-36/37-45-61
PHOSPHOROTHIOATE
DIMETHYL-1-METHYL-2-(METHYLCARBAMOYL)VINYL 6923-22-4 T+,N 24-28-50/53 (1/2-)23-36/37-45-60-61
PHOSPHATE
2,2'-DIMETHYL-4,4'- 6864-37-5 T,C,N 22-23/24-35-51/53 (1/2-)26-36/37/39-45-61
METHYLENEBIS(CYCLOHEXYLAMINE)
O,O-DIMETHYL-O-(4-METHYLTHION-m-TOLYL) 55-38-9 T,N 21-25-50/53 (1/2-)36/37-45-60-61
PHOSPHOROTHIOATE
DIMETHYL 4-(METHYLTHIO)PHENYL PHOSPHATE 3254-63-5 T+ 27/28 (1/2-)28-36/37-45
O,O-DIMETHYL-O-4-NITRO-m-TOLYL 122-14-5 Xn,N 22-50/53 (2-)60-61
PHOSPHOROTHIOATE
O,O-DIMETHYL-S-(MORPHOLINOCARBONYLMETHYL) 144-41-2 T,N 23/24/25-50/53 (1/2-)13-45-60-61
PHOSPHORODITHIOATE
O,O-DIMETHYL O-4-NITROPHENYL PHOSPHOROTHIOATE 298-00-0 T+ 24-28 (1/2-)28-36/37-45
DIMETHYLNITROSOAMINE 62-75-9 T+,N 45-25-26-48/25-51/53 53-45-61 Note E
7,7-DIMETHYL-3-OXA-6-AZAOCTAN-1-OL C 22-35 (1/2-)26-28-36/37/39-45
O,O-DIMETHYL 4-OXOBENZOTRIAZIN-3-YLMETHYL 86-50-0 T+ 24-28 (1/2-)28-36/37-45
PHOSPHORODITHIOATE
5,5-DIMETHYL-3-OXOCYCLOHEX-1-ENYL 122-15-6 T 25 (1/2-)36/37-45
DIMETHYLCARBAMATE
2,4-DIMETHYLPENTAN-3-ONE 565-80-0 F 11 (2-)16-23
O,S-DIMETHYL PHOSPHOROAMIDOTHIOATE 10265-92-6 T+,N 24-28-36-50 (1/2-)22-28-36/37-45-61
Page No. 16
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Substance CAS number Symbol Risk-phrases Safety phrases
O,O-DIMETHYL S-PHTHALIMIDOMETHYL 732-11-6 Xn 21/22 (2-)22-36/37
PHOSPHORODITHIOATE
2,2-DIMETHYL PROPANE 463-82-1 F+ 12 (2-)9-16-33
N,N'-(2,2-DIMETHYLPROPYLIDENE)HEXAMETHYLENE 1000-78-8 Xi 38-43 (2-)24-37
DIAMINE
DIMETHYLSULFAMOYLCHLORIDE 13360-57-1 T+ 45-21/22-26-34 53-45 Note E
DIMETHYL SULPHATE 77-78-1 T+ 45-25-26-34 53-45 Note E
N,N-DIMETHYLTOLUIDINE, all isomers T 23/24/25-33-52/53 (1/2-)28-36/37-45-61 Note C
DIMETHYL 2,2,2-TRICHLORO-1-HYDROXY- 52-68-6 Xn 22-43 (2-)24-37
ETHYLPHOSPHONATE
O,O-DIMETHYL-O-2,4,5-TRICHLOROPHENYL 299-84-3 Xn 21/22 (2-)25-36/37
PHOSPHOROTHIOATE
2,6-DIMETHYL-4-TRIDECYLMORPHOLINE 24602-86-6 Xn 21/22 (2-)25-36/37
2,2-DIMETHYLTRIMETHYLENE DIACRYLATE 2223-82-7 T 24-36/38-43 (1/2-)28-39-45 Note D
DIMETILAN 644-64-4 T 21-25 (1/2-)36/37-45
DIMEXANO 1468-37-7 Xn 22 (2)
DINEX 131-89-5 T 23/24/25 (1/2-)13-45
DINEX, SALTS and ESTERS T 23/24/25 (1/2-)13-45 Note A
DINICKEL TRIOXIDE 1314-06-3 T 49-43 53-45
2,4-DINITROANILINE 97-02-9 T+,N 26/27/28-33-51/53 (1/2-)28-36/37-45-61
DINITROBENZENE, all isomers 25154-54-5 T+,N 26/27/28-33-50/53 (1/2-)28-36/37-45-60-61 Note C
4,6-DINITRO-o-CRESOL, AMMONIUM SALT 2980-64-5 T+ 26/27/28-33 (1/2-)13-28-45
4,6-DINITRO-o-CRESOL, POTASSIUM SALT 5787-96-2 T 23/24/25-33 (1/2-)13-45
4,6-DINITRO-o-CRESOL, SODIUM SALT 2312-76-7 T 23/24/25-33 (1/2-)13-45
DINITROGEN TETROXIDE 10544-72-6 T+ 26-34 (1/2-)9-26-28-36/37/39-45
2,6-DINITRO-4-OCTYLPHENYL and 39300-45-3 Xn 22-38 (2-)37
2,4-DINITRO-6-OCTYLPHENYL CROTONATES
DINITROPHENOL 25550-58-7 T 23/24/25-33 (1/2-)28-37-45 Note C
DINITROPHENOL, SALTS T 23/24/25-33 (1/2-)28-37-45 Note A
DINITROTOLUENE 25321-14-6 T 23/24/25-33 (1/2-)28-37-45 Note C
DINOBUTON 973-21-7 T 25 (1/2-)37-45
DINOCAP 39300-45-3 Xn 22-38 (2-)37
DINOCTON 63919-26-6 Xn 22 (2)
DINOCTON-6 8069-76-9 Xn 22 (2)
8,9-DINORBORN-5-ENE-2,3-DICARBOXYLIC 123748-85-6 Xn 22-36/37/38-42 (2-)39 Note C
ANHYDRIDE
DINOSAM 4097-36-3 T 23/24/25 (1/2-)13-45
DINOSAM, SALTS and ESTERS T 23/24/25 (1/2-)13-45 Note A
DINOSEB 88-85-7 T,N 61-62-24/25-36-44-50/53 53-45-60-61 Note E
DINOSEB, SALTS and ESTERS T 61-62-24/25-36-44 53-45 Note A, E
DINOTERB 1420-07-1 T 61-23/24/25-36-44 53-45 Note E
DINOTERB, SALTS and ESTERS T 61-23/24/25 53-45 Note A, E
DIOXACARB 6988-21-2 T 25 (1/2-)37-45
1,4-DIOXANE 123-91-1 F,Xn 11-19-36/37-40 (2-)16-36/37
1,4-DIOXAN-2,3-DIYL-O,O,O',O'-TETRAETHYL 78-34-2 T+ 24-26/28 (1/2-)28-36/37-45
DI(PHOSPHORODITHIOATE)
DIOXATHION 78-34-2 T+ 24-26/28 (1/2-)28-36/37-45
1,3-DIOXOLANE 646-06-0 F 11 (2-)16
2-(1,3-DIOXOLAN-2-YL)PHENYL METHYLCARBAMATE 6988-21-2 T 25 (1/2-)37-45
N-(4-(4-(2,5-DIOXOPYRROL- Xi,N 43-50/53 (2-)24-37-60-61
1-YL)BENZYL)PHENYL)ACETAMIDE
DIPENTENE 138-86-3 Xi 10-38 (2-)28
DIPHACINONE 82-66-6 T+ 28-48/23/24/25 (1/2-)36/37-45
DIPHENAMID 957-51-7 Xn 22 (2)
DIPHENYL 92-52-4 Xi,N 36/37/38-50/53 (2-)23-60-61
DIPHENYLAMINE 122-39-4 T,N 23/24/25-33-50/53 (1/2-)28-36/37-45-60-61
1,2-DIPHENYLHYDRAZINE 122-66-7 T 45-22 53-45 Note E
DIPHENYLMETHANEDIISOCYANATE, isomers 9016-87-9 Xn 20-36/37/38-42 (2-)26-28-38-45 Note C
and homologues
DIPHENYLMETHANE-2,2'-DIISOCYANATE 2536-05-2 Xn 20-36/37/38-42 (2-)26-28-38-45 Note C
DIPHENYLMETHANE-2,4'-DIISOCYANATE 5873-54-1 Xn 20-36/37/38-42 (2-)26-28-38-45 Note C
DIPHENYLMETHANE-4,4'-DIISOCYANATE 101-68-8 Xn 20-36/37/38-42 (2-)26-28-38-45 Note C
DIPICRYLAMINE, AMMONIUM SALT 2844-92-0 E,T+,N 1-26/27/28-33-51/53 (1/2-)28-36/37-45-61
Page No. 17
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Substance CAS number Symbol Risk-phrases Safety phrases
DIPROPYLAMINE 142-84-7 F,C 11-20/21/22-35 (1/2-)16-26-36/37/39-45
DIPROPYLENETRIAMINE 56-18-8 T+,C 22-24-26-35-43 (1/2-)26-28-36/37/39-45
DI-n-PROPYL ETHER 111-43-3 F 11-19 (2-)9-16-33
DIPROPYL KETONE 123-19-3 - 10 (2-)23
DIQUAT 2764-72-9 T 24/25-36/37/38 (1/2-)22-36/37/39-45
DIQUAT, SALTS T 24/25-36/37/38 (1/2-)22-36/37/39-45 Note A
DISODIUM N-CARBOXYMETHYL-N-(2- 92511-22-3 Xi 41 (2-)26-39
(2-HYDROXYETHOXY)ETHYL)GLYCINATE
DISODIUM ETHYLENEBISDITHIOCARBAMATE 142-59-6 Xn 22-37-43 (2-)8-24/25-46
DISODIUM S,S'-HEXANE-1,6-DIYLDI(THIOSULPHATE) Xi 43-52/53 (2-)22-24-37-61
DIHYDRATE
DISODIUM METASILICATE 6834-92-0 C 34-37 (1/2-)13-24/25-36/37/39-45
DISODIUM 7-OXABICYCLO(2,2,1)HEPTANE-2,3- 129-67-9 T 21-25-36/37/38 (1/2-)36/37/39-45
DICARBOXYLATE
DISULFOTON 298-04-4 T+,N 27/28-50/53 (1/2-)28-36/37-45-60-61
DISULPHUR DICHLORIDE 10025-67-9 C 14-34-37 (1/2-)26-45
DITALIMFOS 5131-24-8 Xi 38-43 (2-)36/37
DITHALLIUM SULPHATE 7446-18-6 T+ 28-38-48/25 (1/2-)13-36/37-45
DITHIANON 3347-22-6 Xn 22 (2-)24
DIURON 330-54-1 Xn 48/22 (2-)22-37
DIXANTHOGEN 502-55-6 Xn 22 (2-)24
DNOC 534-52-1 T+ 27/28-33-36-40-44 (1/2-)36/37-45
DNOC, AMMONIUM SALT 2980-64-5 T+ 26/27/28-33 (1/2-)13-28-45
DNOC, POTASSIUM SALT 5787-96-2 T 23/24/25-33 (1/2-)13-45
DNOC, SODIUM SALT 2312-76-7 T 23/24/25-33 (1/2-)13-45
DODECYLQUANIDIUM ACETATE 2439-10-3 Xn 22-36/38 (2-)26
DODECYL 3,4,5-TRIHYDROXYBENZOATE 1166-52-5 Xi 43 (2-)24-37
DODEMORPH 1593-77-7 Xi 36/37/38 (2-)26
DODINE 2439-10-3 Xn 22-36/38 (2-)26
DRAZOXOLON 5707-69-7 T 25 (1/2-)22-24-36/37-45
EDIFENPHOS 17109-49-8 T 23/24/25 (1/2-)28-36/37-45
ENDOSULFAN 115-29-7 T,N 24/25-36-50/53 (1/2-)28-36/37-45-60-61
ENDOTHAL 145-73-3 T 21-25-36/37/38 (1/2-)36/37/39-45
ENDOTHAL-SODIUM 129-67-9 T 21-25-36/37/38 (1/2-)36/37/39-45
ENDOTHION 2778-04-3 T 24/25 (1/2-)36/37-45
ENDRIN 72-20-8 T+,N 24-28-50/53 (1/2-)22-36/37-45-60-61
EPHEDRINE 299-42-3 Xn 22 (2-)22-25
EPHEDRINE, SALTS Xn 22 (2-)22-25 Note A
EPICHLOROHYDRIN 106-89-8 T 45-10-23/24/25-34-43 53-45 Note E
EPN 2104-64-5 T+,N 27/28-50/53 (1/2-)22-36/37-45-60-61
(EPOXYETHYL)BENZENE 96-09-03 T 45-21-36 53-45 Note E
1,2-EPOXY-4-EPOXYETHYLCYCLOHEXANE 106-87-6 T 23/24/25-40 (1/2-)23-24-45
2,3-EPOXY-1,4,5,6,7,8,8-HEPTACHLORO- 1024-57-3 T,N 25-33-40-50/53 (1/2-)36/37-45-60-61
3a,4,7,7a-TETRAHYDRO-4,7-METHANOINDANE
1,2-EPOXY-3-PHENOXYPROPANE 122-60-1 Xn 21-43 (2-)24/25
1,2-EPOXYPROPANE 75-56-9 F+,T 45-12-20/21/22-36/37/38 53-45 Note E
2,3-EPOXY-1-PROPANOL 556-52-5 T 21/22-23-36/37/38-42/43 (1/2-)45
2,3-EPOXYPROPYL ACRYLATE 106-90-1 T 23/24/25-34-43 (1/2-)26-36/37/39-45 Note D
2,3-EPOXYPROPYL-2-ETHYLCYCLOHEXYL ETHER 130014-35-6 Xi 36/38-43 (2-)26-28-37/39
2,3-EPOXYPROPYL METHACRYLATE 106-91-2 Xn 20/21/22-36/38-43 (2-)26-28 Note D
EPOXYRESIN, reaction product: 25068-38-6 Xi 36/38-43 (2-)28-37/39
BISPHENOL-A(EPICHLOROHYDRIN), average
molecule weight <700
1,2-EPOXY-3-(TOLYLOXY)PROPANE 26447-14-3 Xi 38 (2-)26-28 Note C
EPTC 759-94-4 Xn 22 (2-)23
ERBON 136-25-4 Xn 22 (2)
ERIONITE 12510-42-8 T 45 53-45
ESERIN 57-47-6 T+ 26/28 (1/2-)25-45
ETHANAL 75-07-0 F+,Xn 12-36/37-40 (2-)16-33-36/37
ETHANE 74-84-0 F+ 12 (2-)9-16-33
ETHANEDIOL 107-21-1 Xn 22 (2)
ETHANE-1,2-DIONE 107-22-2 Xi 36/38 (2-)26-28 Note B
ETHANETHIOL 75-08-1 F,Xn 11-20 (2-)16-25
Page No. 18
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Substance CAS number Symbol Risk-phrases Safety phrases
ETHANOL 64-17-5 F 11 (2-)7-16
ETHANOLAMINE 141-43-5 Xn 20-36/37/38 (2)
ETHIOFENCARB 29973-13-5 Xn 22 (2)
ETHION 563-12-2 T 21-25 (1/2-)25-36/37-45
ETHIRIMOL 23947-60-6 Xn 21 (2-)36/37
ETHOATE-METHYL 116-01-8 Xn 21/22 (2-)36/37
ETHOPROPHOS 13194-48-4 T+ 25-27 (1/2-)36/37/39-45
ETHOXIDES, ALKALI F,C 11-14-34 (1/2-)8-16-26-43-45 Note A
2-ETHOXYANILINE 94-70-2 T 23/24/25-33 (1/2-)28-36/37-45 Note C
4-ETHOXYANILINE 156-43-4 T 23/24/25-33 (1/2-)28-36/37-45 Note C
N-ETHOXYCARBONYL-N-METHYLCARBAMOYLMETHYL 2595-54-2 T,N 24/25-50/53 (1/2-)36/37-45-60-61
O,O-DIETHYL PHOSPHORODITHIOATE
6-ETHOXY-1,2-DIHYDRO-2,2,4-TRIMETHYLQUINOLINE 91-53-2 Xn 22 (2-)24
2-ETHOXYETHANOL 110-80-5 T 60-61-10-20/21/22 53-45 Note E
2-ETHOXYETHYL ACETATE 111-15-9 T 60-61-20/21/22 53-45 Note E
ETHOXYQUIN 91-53-2 Xn 22 (2-)24
ETHYL ACETATE 141-78-6 F 11 (2-)16-23-29-33
ETHYL ACRYLATE 140-88-5 F,Xn 11-20/21/22-36/37/38-43 (2-)9-16-33-36/37 Note D
ETHYL ALCOHOL 64-17-5 F 11 (2-)7-16
ETHYLAMINE 75-04-7 F+,Xi 12-36/37 (2-)16-26-29
2-ETHYLAMINO-4-ISOPROPYLAMINO-6-METHYLTHIO- 834-12-8 Xn 22 (2-)36
1,3,5-TRIAZINE
N-ETHYLANILINE 103-69-5 T 23/24/25-33 (1/2-)28-37-45
ETHYLBENZENE 100-41-4 F,Xn 11-20 (2-)16-24/25-29
ETHYL BROMIDE 74-96-4 Xn 20/21/22 (2-)28
ETHYL BROMOACETATE 105-36-2 T+ 26/27/28 (1/2-)7/9-26-45
2-ETHYLBUTAN-1-OL 97-95-0 Xn 21/22 (2)
2-ETHYL BUTANOL 97-95-0 Xn 21/22 (2)
ETHYL CARBAMATE 51-79-6 T 45 53-45
S-(N-ETHYLCARBAMOYLMETHYL) O,O-DIMETHYL 116-01-8 Xn 21/22 (2-)36/37
PHOSPHORODITHIOATE
ETHYL CHLORIDE 75-00-3 F+,Xn 12-40-52/53 (2-)9-16-33-36/37-61
ETHYL CHLOROACETATE 105-39-5 T,N 23/24/25-50 (1/2-)7/9-45-61
ETHYL CHLOROFORMATE 541-41-3 F,T+ 11-22-26-34 (1/2-)9-16-26-28-33-36/37/39-45
ETHYL CYCLOHEXYL GLYCIDYL ETHER 130014-35-6 Xi 36/38-43 (2-)26-28-37/39
ETHYL 5-(1,2,3,5,6,7,8,9,10,10-DECACHLORO- 4234-79-1 T 22-24 (1/2-)36/37-45
-4-HYDROXYPENTACYCLO[5.2.1.02,6.03,9.05,8]
DEC-4-YL)OXOVALERATE
ETHYL 2-(DIMETHOXYPHOSPHINOTHIOYLTHIO)-2- 2597-03-7 Xn 21/22 (2-)22-36/37
PHENYLACETATE
ETHYLDIMETHYLAMINE 598-56-1 F+,C 12-20/22-34 (1/2-)3-16-26-36-45
ETHYL trans-3-DIMETHYLAMINOACRYLATE 924-99-2 Xi 43 (2-)24-37
S-ETHYL DIPROPYLTHIOCARBAMATE 759-94-4 Xn 22 (2-)23
ETHYLENE 74-85-1 F+ 12 (2-)9-16-33
ETHYLENE BIS(TRICHLOROACETATE) 2514-53-6 Xi 38 (2)
ETHYLENE CHLOROHYDRIN 107-07-3 T+ 26/27/28 (1/2-)7/9-28-45
ETHYLENEDIAMINE 107-15-3 C 10-21/22-34-42/43 (1/2-)23-26-36/37/39-45
ETHYLENE DIAMMONIUM O,O-BIS(OCTYL) C,N 22-34-50/53 (1/2-)24/25-26-28-39-45-60-61
PHOSPHORODITHIOATE, mixture of isomers
ETHYLENE DIBROMIDE 106-93-4 T,N 45-23/24/25-36/37/38- 53-45-61 Note E
51/53
ETHYLENE DICHLORIDE 107-06-2 F,T 45-11-22-36/37/38 53-45 Note E
ETHYLENE DIMETHACRYLATE 97-90-5 Xi 36/37 (2) Note D
ETHYLENE DINITRATE 628-96-6 E,T+ 2-26/27/28-33 (1/2-)33-35-36/37-45
2,2'-(ETHYLENEDIOXY)DIETHYL DIACRYLATE 1680-21-3 Xi 36/38-43 (2-)26-28 Note D
ETHYLENE GLYCOL 107-21-1 Xn 22 (2)
ETHYLENE GLYCOL DIMETHACRYLATE 97-90-5 Xi 36/37 (2) Note D
ETHYLENE GLYCOL DIMETHYL ETHER 110-71-4 Xn 10-19-20 (2-)24/25
ETHYLENE GLYCOL DINITRATE 628-96-6 E,T+ 2-26/27/28-33 (1/2-)33-35-36/37-45
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 Xn 20/21/22-37 (2-)24/25
ETHYLENE GLYCOL MONOETHYL ETHER 110-80-5 T 60-61-10-20/21/22 53-45 Note E
ETHYLENE GLYCOL MONOISOPROPYL ETHER 109-59-1 Xn 20/21-36 (2-)24/25
ETHYLENE GLYCOL MONOMETHYL ETHER 109-86-4 T 60-61-10-20/21/22 53-45 Note E
Page No. 19
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Substance CAS number Symbol Risk-phrases Safety phrases
2-ETHYLHEXYL 3,5-BIS(1,1-DIMETHYLETHYL)- 80387-97-9 T 61-43 53-45
4-HYDROXYPHENYL METHYL THIOACETATE
ETHYLENEIMINE 151-56-4 F,T+,N 45-46-11-26/27/28-34- 53-45-61 Note D, E
51/53
ETHYLENE OXIDE 75-21-8 F+,T 45-46-12-23-36/37/38 53-45 Note E
ETHYLENE THIOUREA 96-45-7 T 61-22 53-45 Note E
ETHYL FORMATE 109-94-4 F 11 (2-)9-16-33
ETHYL GLYCOL 110-80-5 T 60-61-10-20/21/22 53-45 Note E
ETHYLGLYCOL ACETATE 111-15-9 T 60-61-20/21/22 53-45 Note E
2-ETHYLHEXANE-1,3-DIOL 94-96-2 Xi 36 (2-)26
2-ETHYLHEXANOIC ACID |
