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NAPHTHENIC ACIDS ICSC: 1654
April 2007
Carboxylic-acids, -naphthenic-
Acidic petroleum fraction
PDF for printing Explanation of fields
CAS No: 1338-24-5
RTECS No: QK8750000
    CnH2n-1COOH
Molecular mass: 180 - 350

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Combustible. NO open flames. Special powder. Carbon dioxide. Foam. Water may be ineffective.
EXPLOSION     In case of fire: keep drums, etc., cool by spraying with water.
 
EXPOSURE      
Inhalation Cough. Dizziness. Local exhaust. Fresh air, rest.
Skin Redness. Pain. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes Redness. Pain. Safety goggles First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Nausea. Vomiting. Diarrhoea. Drowsiness. Do not eat, drink, or smoke during work. Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Collect leaking liquid in covered containers. Do NOT let this chemical enter the environment. GHS classification
Signal: Danger
Excl mark-Health haz-Enviro
Harmful if swallowed
Causes damage to nervous system through prolonged or repeated exposure if swallowed
Toxic to aquatic life


EMERGENCY RESPONSE SAFE STORAGE
NFPA Code: H2; F1; R0 Separated from strong oxidants and metals.

IMPORTANT DATA
Physical State; Appearance
LIGHT YELLOW TO BLACK VISCOUS LIQUID

Chemical dangers
The substance decomposes on heating, producing irritating fumes. Attacks metal.

Occupational exposure limits
TLV not established.
MAK not established.

Routes of exposure
The substance can be absorbed into the body through the skin by ingestion.

Inhalation risk
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

Effects of short-term exposure
The substance is irritating to the eyes and the skin. The substance may cause effects on the central nervous system.

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the liver and central nervous system.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Boiling point: 140-370°C
Melting point: -35 to 2°C
Relative density (water = 1): 0.982 (liquid)
Solubility in water: poor
Flash point: 149 °C o.c.
Explosive limits, vol% in air: lower 1%
Octanol/water partition coefficient as log Pow: 5 - > 6 (calculated)
The substance is toxic to aquatic organisms.

NOTES
Composition may change physical and toxicological properties.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2006
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

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