ICSC 1569 - ETHYLENE GLYCOL DIETHYL ETHER

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ETHYLENE GLYCOL DIETHYL ETHER

ICSC: 1569
_{October 2004}

1,2-Diethoxyethane
1,2-Ethanol, diethyl ether
Ethyl glyme
3,6-Dioxaoctane
EGDEE

CAS No: 629-14-1
RTECS No: KI1225000
UN No: 1153

C₆H₁₄O₂ / CH₃CH₂OCH₂CH₂OCH₃
Molecular mass: 118.2

TYPES OF HAZARD / EXPOSURE	ACUTE HAZARDS / SYMPTOMS	PREVENTION	FIRST AID / FIRE FIGHTING
FIRE	Flammable.	NO open flames, NO sparks, and NO smoking.	Water spray, foam, powder, carbon dioxide.
EXPLOSION	Above 35°C explosive vapour/air mixtures may be formed.	Above 35°C use a closed system, ventilation.	In case of fire: keep drums, etc., cool by spraying with water.

EXPOSURE	See EFFECTS OF LONG-TERM OR REPEATED EXPOSURE.	AVOID ALL CONTACT!
Inhalation	Cough.	Ventilation, local exhaust, or breathing protection.	Fresh air, rest.
Skin	MAY BE ABSORBED! Redness.	Protective clothing. Protective gloves.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes	Redness. Pain.	Safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion	Nausea.	Do not eat, drink, or smoke during work.	Rinse mouth. Give plenty of water to drink.

SPILLAGE DISPOSAL	PACKAGING & LABELLING
Remove all ignition sources. Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Personal protection: filter respirator for organic gases and vapours.	UN Hazard Class: 3 UN Pack Group: III

EMERGENCY RESPONSE	SAFE STORAGE
Transport Emergency Card: TEC (R)-30GF1-III NFPA Code: H2; F3; R0	Fireproof. Separated from strong oxidants.

IMPORTANT DATA

Physical State; Appearance
COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR.

Chemical dangers
The substance can presumably form explosive peroxides. Reacts violently with strong oxidants.

Occupational exposure limits
TLV not established.
MAK not established.

Routes of exposure
The substance can be absorbed into the body by ingestion, by inhalation and through the skin.

Inhalation risk
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

Effects of short-term exposure
The substance is irritating to the eyes, and is mildly irritating to the skin and the respiratory tract.

Effects of long-term or repeated exposure
Animal tests show that this substance possibly causes toxicity to human reproduction or development.

PHYSICAL PROPERTIES	ENVIRONMENTAL DATA
Boiling point: 121.4°C Melting point: -74°C Relative density (water = 1): 0.85 Solubility in water: moderate Vapour pressure, kPa at 20°C: 1.2 Relative vapour density (air = 1): 4.07 Flash point: 35°C o.c. Auto-ignition temperature: 208°C Octanol/water partition coefficient as log Pow: 0.66

NOTES

Check for peroxides prior to distillation; eliminate if found.
Diethyl cellosolve is a trade name.

IPCS
International
Programme on
Chemical Safety

Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004

LEGAL NOTICE

Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

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