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FERROCENE ICSC: 1512
April 2004
Dicyclopentadienyl iron
Di-2,4-cyclopentadien-1-yl iron
PDF for printing Explanation of fields
CAS No: 102-54-5
RTECS No: LK0700000
    C10H10Fe / C5H5FeC5H5
Molecular mass: 186.0

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION         FIRE FIGHTING   
FIRE Combustible. NO open flames. Powder, alcohol-resistant foam, water spray, carbon dioxide.
EXPLOSION      
 
EXPOSURE   PREVENT DISPERSION OF DUST!  
Inhalation Sore throat. Local exhaust or breathing protection. Fresh air, rest.
Skin Redness. Protective gloves. Rinse and then wash skin with water and soap.
Eyes Redness. Pain. Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion   Do not eat, drink, or smoke during work. Rinse mouth.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Personal protection: P1 filter respirator for inert particles.  

EMERGENCY RESPONSE STORAGE
  Separated from strong oxidants.

IMPORTANT DATA
Physical State; Appearance
ORANGE CRYSTALS, WITH CHARACTERISTIC ODOUR.

Chemical dangers
On combustion, forms toxic fumes. Reacts violently with ammonium perchlorate or tetranitromethane. Reacts with mercury (II) nitrate.

Occupational exposure limits
TLV: (as Fe) 10 mg/m³ as TWA; (ACGIH 2001).
MAK not established.

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

Effects of short-term exposure
May cause mechanical irritation.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Boiling point: 249°C
Sublimation point: above 100°C
Melting point: 173°C
Solubility in water: none
Vapour pressure, Pa at 40°C: 4
 

NOTES
 

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

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