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CHLORDECONE ICSC: 1432
May 2003
1,1a,3,3a,4,5,5,5a,5b,6-Decachloro-octahydro-1,3,4-metheno-2H-cyclobuta(cd)pentalen-2-one
Kepone
Decachloroketone
PDF for printing Explanation of fields
CAS No: 143-50-0
RTECS No: PC8575000
UN No: 2761
EC No: 606-019-00-6
    C10Cl10O
Molecular mass: 490.6

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION         FIRE FIGHTING   
FIRE Gives off irritating or toxic fumes (or gases) in a fire.   In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION      
 
EXPOSURE   AVOID ALL CONTACT! AVOID EXPOSURE OF (PREGNANT) WOMEN! AVOID EXPOSURE OF BREASTFEEDING WOMEN! IN ALL CASES CONSULT A DOCTOR!
Inhalation Loss of movement co-ordination. Headache. Tremor. Weakness. Local exhaust or breathing protection. Fresh air, rest. Refer for medical attention.
Skin MAY BE ABSORBED! Protective clothing. Protective gloves. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
Eyes   Face shield. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion (See Inhalation). Do not eat, drink, or smoke during work. Wash hands before eating. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). See Notes. Give a slurry of activated charcoal in water to drink. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. (Extra personal protection: P3 filter respirator for toxic particles.) T Symbol
N Symbol
R: 24/25-40-50/53
S: (1/2-)22-36/37-45-60-61
UN Hazard Class: 6.1
UN Pack Group: II

Airtight. Do not transport with food and feedstuffs. Marine pollutant.


EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-61GT7-II Provision to contain effluent from fire extinguishing. Separated from acids.

IMPORTANT DATA
Physical State; Appearance
WHITE CRYSTALS

Chemical dangers
On combustion, forms chlorine fumes and hydrogen chloride. The substance decomposes on contact with acids producing toxic fumes.

Occupational exposure limits
TLV not established.
MAK: Carcinogen category: 3B; (DFG 2002).

Routes of exposure
The substance can be absorbed into the body through the skin, by ingestion and by inhalation.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

Effects of short-term exposure
The substance may cause effects on the central nervous system and liver, resulting in impaired functions and liver impairment. The effects may be delayed.

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the endocrine system. This substance is possibly carcinogenic to humans. Causes toxicity to human reproduction or development.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Sublimation point: 350°C (decomposes)
Solubility in water, g/100 ml at 20°C: poor
Octanol/water partition coefficient as log Pow: 3.45
The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur in fish, in mammals and in milk.

NOTES
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
Consult national legislation.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2003
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

Top of page (Ctrl-Home) Updated by AS. Approved by EC. Last update: 22.08.2003