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AMMONIUM PERCHLORATE ICSC: 1255
April 2006
Perchloric acid, ammonium salt PDF for printing Explanation of fields
CAS No: 7790-98-9
RTECS No: SC7520000
UN No: 1442
EC No: 017-009-00-0
    NH4ClO4
Molecular mass: 117.5

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Not combustible but enhances combustion of other substances. Many reactions may cause fire or explosion. Gives off irritating or toxic fumes (or gases) in a fire. See Notes. NO contact with combustibles, reducing agents and organic materials. In case of fire in the surroundings: water in large amounts, water spray.
EXPLOSION Risk of fire and explosion, see Chemical Dangers. Do NOT expose to heat, friction or shock. In case of fire: keep drums, etc., cool by spraying with water. Combat fire from a sheltered position.
 
EXPOSURE   PREVENT DISPERSION OF DUST!  
Inhalation Cough. Local exhaust or breathing protection. Fresh air, rest.
Skin Redness. Pain. Protective gloves. Protective clothing. First rinse with plenty of water, then remove contaminated clothes and rinse again.
Eyes Redness. Pain. Safety goggles, or eye protection in combination with breathing protection if powder. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Burning sensation. Nausea. Vomiting. Diarrhoea. Do not eat, drink, or smoke during work. Rinse mouth. Give one or two glasses of water to drink.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Evacuate danger area! Consult an expert! Personal protection: P2 filter respirator for harmful particles. Moisten first, then sweep spilled substance into covered containers, then remove to safe place. Do NOT absorb in saw-dust or other combustible absorbents. Do NOT let this chemical enter the environment. EU classification
O Symbol
R: 9-44
S: (2-)14-16-27-36/37
Note: G
UN classification
UN Hazard Class: 5.1
UN Pack Group: II


EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-51S1442
NFPA Code: H1; F0; R4
Fireproof. Separated from combustible and reducing substances, and metals. See Chemical Dangers. Well closed.

IMPORTANT DATA
Physical State; Appearance
WHITE HYGROSCOPIC CRYSTALS

Chemical dangers
May decompose explosively on shock, friction, or concussion. and on heating. The substance is a strong oxidant and reacts violently with combustible and reducing materials and metals, producing toxic and corrosive fumes, including ammonia and hydrogen chloride, causing fire and explosion hazard.

Occupational exposure limits
TLV not established.
MAK not established.

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Inhalation risk
A harmful concentration of airborne particles can be reached quickly when dispersed

Effects of short-term exposure
The aerosol is irritating to the eyes, the skin and the respiratory tract.

Effects of long-term or repeated exposure
The substance may have effects on the thyroid, resulting in reduced levels of thyroid hormones.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Decomposes at >200 °C (See Notes)
Density: 1.95 g/cm³
Solubility in water, g/100 ml at 25°C: 20
This substance may be hazardous in the environment; special attention should be given to crustacea.

NOTES
Different decomposition temperatures are given in the literature. Unstabilized substance may explode on heating.
Health effects of exposure to the substance have not been investigated
adequately.
Rinse contaminated clothes (fire hazard) with plenty of water.
Card has been partially updated in January 2008: see Physical Properties.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2006
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

Top of page (Ctrl-Home) Updated by AS. Approved by GS. Last update: 29.01.2008