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ALUMINIUM SULFATE ICSC: 1191
October 1994
Aluminium sulphate
Aluminium trisulfate
Alum

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CAS # 10043-01-3 Al 2S 3O 1 2/Al 2(SO 4) 3
RTECS # BD1700000 Molecular mass: 342.14

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID /    FIRE FIGHTING   
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION

In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT DISPERSION OF DUST! STRICT HYGIENE!

Inhalation Cough. Shortness of breath. Sore throat.
Avoid inhalation of fine dust and mist. Local exhaust or breathing protection.
Fresh air, rest. Refer for medical attention.
Skin Redness. Pain.
Protective gloves. Protective clothing.
Rinse skin with plenty of water or shower. Refer for medical attention.
Eyes Corrosive. Redness. Severe deep burns.
Safety goggles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Abdominal pain. Burning sensation. Nausea. Vomiting.
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting (extra personal protection: P2 filter respirator for harmful particles).
UN Hazard Class
UN Pack Group


EMERGENCY RESPONSE STORAGE

Separated from strong bases. Dry.

IMPORTANT DATA
PHYSICAL STATE; APPEARANCE:
ODOURLESS WHITE, LUSTROUS CRYSTALS OR POWDER.

CHEMICAL DANGERS:
The substance decomposes on heating or on burning producing toxic and corrosive fumes including sulfur oxides. The solution in water is a medium strong acid. Reacts with alkalis and attacks many metals in presence of water.

OCCUPATIONAL EXPOSURE LIMITS:
TLV (as Al soluble salt): ppm; 2 mg/m 3 (ACGIH 1993-1994).
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the eyes, the skin and the respiratory tract. Corrosive on ingestion.


PHYSICAL PROPERTIES
Melting point (decomposes): 770°C
Relative density (water = 1): 2.71
Solubility in water: good
 

ENVIRONMENTAL DATA
This substance may be hazardous to the environment; special attention should be given to fish.

NOTES
Cake alum, pickle alum, filter alum, papermaker's alum and pearl alum are other common names of aluminium sulfate. Occurs in nature as the mineral alunogenite.

IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission

© IPCS 1999
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.


Updated by AS. Approved by EC. Last update: 10.10.2000.