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MALEIC ACID ICSC: 1186
October 1997
(Z)-Butenedioic acid
cis-1,2-Ethylenedicarboxylic acid
Malenic acid

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CAS # 110-16-7 C 4H 4O 4 / HOOHCH=CHCOOH
RTECS # OM9625000 Molecular mass: 116.1
UN # 1759
EC # 607-095-00-3

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID /    FIRE FIGHTING   
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames.
Powder, water spray, foam, carbon dioxide.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST! STRICT HYGIENE!

Inhalation Cough. Laboured breathing.
Local exhaust or breathing protection.
Fresh air, rest. Half-upright position. Refer for medical attention.
Skin Redness. Skin burns.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes Redness. Pain. Blurred vision.
Safety goggles, or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Burning sensation. (Further see Inhalation).
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Do NOT wash away into sewer. Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water. (Extra personal protection: P2 filter respirator for harmful particles).
Xn Symbol
R: 22-36/37/38
S: 2-26-28-37
UN Hazard Class: 8
UN Pack Group: III
Do not transport with food and feedstuffs. Marine pollutant.

EMERGENCY RESPONSE STORAGE

Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Dry.

IMPORTANT DATA
PHYSICAL STATE; APPEARANCE:
WHITE CRYSTALS.

CHEMICAL DANGERS:
The substance decomposes on heating and on burning producing highly irritating fumes including maleic anhydride. The solution in water is a medium strong acid.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation and by ingestion.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates severely the eyes, the skin and the respiratory tract.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the kidneys.

PHYSICAL PROPERTIES
Decomposes below boiling point at 135°C
Melting point: 131°C
Relative density (water = 1): 1.59
Solubility in water, g/100 ml at 25°C: 78
Octanol/water partition coefficient as log Pow: -0.5

ENVIRONMENTAL DATA
The substance is toxic to aquatic organisms.

NOTES


IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission

© IPCS 1999
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.



Updated by AS. Approved by EC. Last update: 10.10.2000.