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CALCIUM CHLORIDE (ANHYDROUS) ICSC: 1184
October 1995
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CAS # 10043-52-4 CaCl 2
RTECS # EV9800000 Molecular mass: 111.0
EC # 017-013-00-2

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID /    FIRE FIGHTING   
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST!

Inhalation Cough. Sore throat.
Local exhaust or breathing protection.
Fresh air, rest.
Skin Dry skin. Redness.
Protective gloves.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes
Safety spectacles.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Burning sensation. Nausea. Vomiting.
Do not eat, drink, or smoke during work.
Rinse mouth. Give plenty of water to drink. Rest.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Wash away remainder with plenty of water (extra personal protection: P2 filter respirator for harmful particles).
Xi Symbol
R: 36
S: 2-22-24
Airtight.

EMERGENCY RESPONSE STORAGE

Separated from zinc. Dry. Well closed.

IMPORTANT DATA
PHYSICAL STATE; APPEARANCE:
ODOURLESS, VERY HYGROSCOPIC COLOURLESS CRYSTALS.

CHEMICAL DANGERS:
The substance decomposes on heating at high temperature and on burning producing toxic and corrosive fumes. The solution in water is a weak base. Attacks zinc in presence of water forming highly flammable hydrogen gas. Dissolves violently in water with liberation of much heat.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol.

INHALATION RISK:
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

EFFECTS OF SHORT-TERM EXPOSURE:
The substance irritates the skin and the respiratory tract.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the nasal mucous membrane , resulting in ulcerations.

PHYSICAL PROPERTIES
Boiling point: 1935°C
Melting point: 772°C
Relative density (water = 1): 2.16
Solubility in water, g/100 ml at 20°C: 74.5
 

ENVIRONMENTAL DATA


NOTES


IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission

© IPCS 1999
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.


Updated by AS. Approved by EC. Last update: 10.10.2000.