ICSC 1084 - 1-HEXANOL

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1-HEXANOL

ICSC: 1084
_{October 2002}

Hexyl alcohol
n-Hexanol
n-Hexyl alcohol
1-Hydroxyhexane
Amyl carbinol
Caproyl alcohol

CAS No: 111-27-3
RTECS No: MQ4025000
EC No: 603-059-00-6

C₆H₁₄O / CH₃(CH₂)₄CH₂OH
Molecular mass: 102.2

TYPES OF HAZARD / EXPOSURE	ACUTE HAZARDS / SYMPTOMS	PREVENTION	FIRE FIGHTING
FIRE	Combustible.	NO open flames.	Alcohol-resistant foam, dry powder, carbon dioxide.
EXPLOSION	Above 63°C explosive vapour/air mixtures may be formed.	Above 63°C use a closed system, ventilation.	In case of fire: keep drums, etc., cool by spraying with water.

EXPOSURE
Inhalation	Cough. Sore throat.	Ventilation, local exhaust, or breathing protection.	Fresh air, rest.
Skin	Dry skin.	Protective gloves.	Rinse and then wash skin with water and soap.
Eyes	Redness. Pain.	Safety goggles.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion	Burning sensation.	Do not eat, drink, or smoke during work.	Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink.

SPILLAGE DISPOSAL	PACKAGING & LABELLING
Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. (Extra personal protection: filter respirator for organic gases and vapours.)	Xn Symbol R: 22 S: (2-)24/25

EMERGENCY RESPONSE	STORAGE
NFPA Code: H1; F2; R0	Separated from strong oxidants.

IMPORTANT DATA

Physical State; Appearance
COLOURLESS LIQUID, WITH CHARACTERISTIC ODOUR.

Chemical dangers
Reacts with strong oxidants.

Occupational exposure limits
TLV not established.

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion.

Inhalation risk
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

Effects of short-term exposure
The substance is irritating to the respiratory tract and the skin. The substance is severely irritating to the eyes. If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis.

Effects of long-term or repeated exposure
The liquid defats the skin.

PHYSICAL PROPERTIES

ENVIRONMENTAL DATA

Boiling point: 157°C
Melting point: -44.6°C
Relative density (water = 1): 0.82
Solubility in water, g/100 ml at 20°C: 0.59
Vapour pressure, kPa at 25°C: 0.124
Relative vapour density (air = 1): 3.52
Relative density of the vapour/air-mixture at 20°C (air = 1): 1
Flash point: 63°C c.c.
Auto-ignition temperature: 290°C
Explosive limits, vol% in air: 1.2-7.7 calculated
Octanol/water partition coefficient as log Pow: 2.03

NOTES

IPCS
International
Programme on
Chemical Safety

Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2002

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Updated by AS. Approved by EC. Last update: 21.03.2003