ILO Home
  

ICSC index [List of Chemicals]  [Risk Notes]  [Risk Phrases]  [Safety Phrases]  [Danger Symbols] Bottom of page (Ctrl-End)
SODIUM PERBORATE TETRAHYDRATE ICSC: 1046
October 2004
Perboric acid, sodium salt, tetrahydrate PDF for printing Explanation of fields
CAS No: 10486-00-7
RTECS No: SC7350000
UN No: 1479
    NaBO3. 4H2O / NaBO2. H2O2. 3H2O
Molecular mass: 153.9

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Not combustible but enhances combustion of other substances. Gives off irritating or toxic fumes (or gases) in a fire. NO contact with flammable substances. In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION Risk of fire and explosion on contact with heat or combustible substances.   In case of fire: cool drums, etc., by spraying with water but avoid contact of the substance with water.
 
EXPOSURE      
Inhalation Cough. Shortness of breath. Local exhaust or breathing protection. Fresh air, rest.
Skin   Protective gloves. First rinse with plenty of water, then remove contaminated clothes and rinse again.
Eyes Redness. Pain. Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Nausea. Vomiting. Diarrhoea. Do not eat, drink, or smoke during work. Rinse mouth. Give a slurry of activated charcoal in water to drink. Rest. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into dry, sealable containers. Do NOT absorb in saw-dust or other combustible absorbents. Do NOT let this chemical enter the environment. Personal protection: P2 filter respirator for harmful particles. UN Hazard Class: 5.1
UN Pack Group: II


EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-51GO2-I+II+III
NFPA Code: H1; F1; R0
Well closed. Separated from combustible and reducing substances, strong acids.

IMPORTANT DATA
Physical State; Appearance
WHITE CRYSTALLINE POWDER

Chemical dangers
The substance decomposes on warming above 60°C producing toxic fumes including sodium oxide and on contact with water producing boric acid and hydrogen peroxide. The substance is a strong oxidant and reacts with combustible and reducing materials. The solution in water is a weak base.

Occupational exposure limits
TLV not established.
MAK not established.

Routes of exposure
The substance can be absorbed into the body by inhalation and by ingestion.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered.

Effects of short-term exposure
The substance is irritating to the eyes and the respiratory tract.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Melting point (decomposes): about 60-65.5°C
Solubility in water, g/100 ml at 20°C: 2.3
The substance is harmful to aquatic organisms.

NOTES
Rinse contaminated clothes (fire hazard) with plenty of water.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

Top of page (Ctrl-Home) Updated by {ModOper}. Approved by {ModAppr}. Last update: {ModDate}