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ENDRIN ICSC: 1023
October 2000
  PDF for printing Explanation of fields
CAS No: 72-20-8
RTECS No: IO1575000
UN No: 2761
EC No: 602-051-00-X
    C12H8Cl6O
Molecular mass: 380.9

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Not combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.   In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION      
 
EXPOSURE   PREVENT DISPERSION OF DUST! STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!
Inhalation (See Ingestion). Local exhaust or breathing protection. Fresh air, rest. Refer for medical attention.
Skin MAY BE ABSORBED!(See Ingestion). Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
Eyes   Face shield or eye protection in combination with breathing protection if powder. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Dizziness. Weakness. Headache. Nausea. Vomiting. Convulsions. Do not eat, drink, or smoke during work. Wash hands before eating. Give a slurry of activated charcoal in water to drink. Rest. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Do NOT wash away into sewer. Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. (Extra personal protection: chemical protection suit including self-contained breathing apparatus). T+ Symbol
N Symbol
R: 24-28-50/53
S: (1/2-)22-36/37-45-60-61
UN Hazard Class: 6.1
UN Pack Group: I

Do not transport with food and feedstuffs. Severe marine pollutant.


EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-61G41a
NFPA Code: H3; F0; R; 0
Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed. Keep in a well-ventilated room.

IMPORTANT DATA
Physical State; Appearance
WHITE CRYSTALS.

Chemical dangers
The substance decomposes on heating above 245°C, producing hydrogen chloride, phosgene.

Occupational exposure limits
TLV: 0.1 mg/m³ (skin) (ACGIH 2000).

Routes of exposure
The substance can be absorbed into the body by inhalation, through the skin and by ingestion.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.

Effects of short-term exposure
The substance may cause effects on the central nervous system, resulting in convulsions and death. The effects may be delayed. Medical observation is indicated.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Decomposes below boiling point at 245°C
Melting point: 200°C
Density: 1.7 g/cm³
Solubility in water, g/100 ml at 25°C: none
Vapour pressure, Pa at 25°C: negligible
Octanol/water partition coefficient as log Pow: 5.34
The substance is very toxic to aquatic organisms. This substance may be hazardous to the environment; special attention should be given to honey bees, birds and mammals.
It is strongly advised not to let the chemical enter into the environment because it persists in the environment. In the food chain important to humans, bioaccumulation takes place, specifically in fish and seafood.
Avoid release to the environment in circumstances different to normal use.

NOTES
If the substance is formulated with solvent(s) also consult the card(s) (ICSC) of the solvent(s).
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2000
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

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