ICSC 0995 - 1,3-DICHLOROPROPENE (MIXED ISOMERS)

[List of Chemicals] [Risk Notes] [Risk Phrases] [Safety Phrases] [Danger Symbols]

1,3-DICHLOROPROPENE (MIXED ISOMERS)

ICSC: 0995
_{October 2004}

1,3-Dichloropropylene
Dichloropropene
3-Chloroallyl chloride
DCP

CAS No: 542-75-6
RTECS No: UC8310000
UN No: 2047
EC No: 602-030-00-5

C₃H₄Cl₂
Molecular mass: 111.0

TYPES OF HAZARD / EXPOSURE	ACUTE HAZARDS / SYMPTOMS	PREVENTION	FIRST AID / FIRE FIGHTING
FIRE	Flammable. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames, NO sparks, and NO smoking.	Powder, water spray, foam, carbon dioxide.
EXPLOSION	Above 25°C explosive vapour/air mixtures may be formed.	Above 25°C use a closed system, ventilation, and explosion-proof electrical equipment.	In case of fire: keep drums, etc., cool by spraying with water.

EXPOSURE		AVOID ALL CONTACT!	IN ALL CASES CONSULT A DOCTOR!
Inhalation	Cough. Sore throat. Headache. Dizziness. Nausea. Vomiting. Unconsciousness.	Ventilation, local exhaust, or breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	MAY BE ABSORBED! Redness. Pain. (Further see Inhalation).	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
Eyes	Redness. Pain.	Safety goggles, or eye protection in combination with breathing protection.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion	Laboured breathing. (Further see Inhalation).	Do not eat, drink, or smoke during work.	Give plenty of water to drink. Refer for medical attention.

SPILLAGE DISPOSAL	PACKAGING & LABELLING
Ventilation. Remove all ignition sources. Chemical protection suit including self-contained breathing apparatus. Collect leaking and spilled liquid in sealable plastic containers as far as possible. Do NOT let this chemical enter the environment.	T Symbol N Symbol R: 10-20/21-25-36/37/38-43-50/53 S: (1/2-)36/37-45-60-61 UN Hazard Class: 3 UN Pack Group: III

EMERGENCY RESPONSE	SAFE STORAGE
Transport Emergency Card: TEC (R)-30GF1-III NFPA Code: H2; F3; R0	Fireproof. Separated from metals and oxidants. Well closed.

IMPORTANT DATA

Physical State; Appearance
COLOURLESS LIQUID, WITH PUNGENT ODOUR.

Physical dangers
The vapour is heavier than air and may travel along the ground; distant ignition possible.

Chemical dangers
The substance decomposes on burning producing toxic and corrosive fumes including hydrogen chloride. Reacts with oxidants, metals.

Occupational exposure limits
TLV: 1 ppm as TWA; (skin); A3; (ACGIH 2004).
MAK: H; Sh; Carcinogen category: 2; (DFG 2004).

Routes of exposure
The substance can be absorbed into the body by inhalation of its vapour and through the skin and by ingestion.

Inhalation risk
A harmful contamination of the air can be reached very quickly on evaporation of this substance at 20°C.

Effects of short-term exposure
The substance is irritating to the eyes, the skin and the respiratory tract. The substance may cause effects on the central nervous system.

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization. This substance is possibly carcinogenic to humans.

PHYSICAL PROPERTIES	ENVIRONMENTAL DATA
Boiling point: 108°C Melting point: <-50°C Relative density (water = 1): 1.22 Solubility in water, g/100 ml at 20°C: 0.2 Vapour pressure, kPa at 20°C: 3.7 Relative vapour density (air = 1): 3.8 Relative density of the vapour/air-mixture at 20°C (air = 1): 1.1 Flash point: 25°C c.c. Explosive limits, vol% in air: 5.3-14.5 Octanol/water partition coefficient as log Pow: 1.82	The substance is toxic to aquatic organisms.

NOTES

The technical product may contain 1% other materials.

IPCS
International
Programme on
Chemical Safety

Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004

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