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MAGNESIUM CARBONATE ICSC: 0969
October 1995
Magnesite
Carbonic acid, magnesium salt

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CAS # 546-93-0 MgCO 3
RTECS # OM2470000 Molecular mass: 84.3

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID /    FIRE FIGHTING   
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.

In case of fire in the surroundings: all extinguishing agents allowed.
EXPLOSION


EXPOSURE
PREVENT DISPERSION OF DUST!

Inhalation Cough.
Avoid inhalation of fine dust and mist. Local exhaust or breathing protection.
Fresh air, rest.
Skin
Protective gloves.
Rinse skin with plenty of water or shower.
Eyes
Safety spectacles.

Ingestion



SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into covered containers; if appropriate, moisten first to prevent dusting (extra personal protection: P1 filter respirator for inert particles).


EMERGENCY RESPONSE STORAGE

Separated from acids.

IMPORTANT DATA
PHYSICAL STATE; APPEARANCE:
WHITE POWDER.

CHEMICAL DANGERS:
The substance decomposes on heating producing acrid smoke and irritating fumes. Reacts with acids liberating carbon dioxide gas.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: ppm; 10 mg/m 3 (as TWA) (ACGIH 1995-1996).
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its aerosol.

INHALATION RISK:
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly on spraying or when dispersed, especially if powdered.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
The substance may have effects on the lungs if the magnesite contains more than 1% crystalline silica.

PHYSICAL PROPERTIES
Melting point (decomposes): 350°C
Relative density (water = 1): 2.95
Solubility in water, g/100 ml: none
 

ENVIRONMENTAL DATA


NOTES
If magnesite contains >1% crystalline silica, also consult ICSC # 0808.

IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission

© IPCS 1999
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.



Updated by AS. Approved by EC. Last update: 10.10.2000.