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PENTACHLORONAPHTHALENE ICSC: 0935
March 2001
  PDF for printing Explanation of fields
CAS No: 1321-64-8
RTECS No: QK0300000
EC No: 602-041-00-5
    C10H3Cl5
Molecular mass: 300.4

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.   Water spray, foam, powder, carbon dioxide.
EXPLOSION      
 
EXPOSURE   PREVENT DISPERSION OF DUST! STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!
Inhalation   Local exhaust or breathing protection. Fresh air, rest.
Skin MAY BE ABSORBED! Redness. Pain. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
Eyes Redness. Pain. Face shield or eye protection in combination with breathing protection. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion   Do not eat, drink, or smoke during work. Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into sealable containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. Chemical protection suit. Personal protection: P2 filter respirator for harmful particles. Xn Symbol
N Symbol
R: 21/22-36/38-50/53
S: (2-)35-60-61
Note: C

EMERGENCY RESPONSE SAFE STORAGE
  Separated from strong oxidants, food and feedstuffs.

IMPORTANT DATA
Physical State; Appearance
PALE YELLOW OR WHITE SOLID, WITH CHARACTERISTIC ODOUR.

Chemical dangers
The substance decomposes on heating producing toxic fumes of hydrogen chloride. Reacts with strong oxidants.

Occupational exposure limits
TLV: 0.5 mg/m³; (skin); (ACGIH 2004).
MAK: IIb (not established but data is available); skin absorption (H); (DFG 2004).

Routes of exposure
The substance can be absorbed into the body by inhalation of fumes and through the skin.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly.

Effects of short-term exposure
The substance is irritating to the eyes and the skin.

Effects of long-term or repeated exposure
Repeated or prolonged contact with skin may cause dermatitis (chloracne). The substance may have effects on the liver, resulting in liver impairment.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Boiling point: 327-371°C
Melting point: 120°C
Density: 1.7 g/cm³
Solubility in water: none
Vapour pressure, Pa at 20°C: <0.1
Relative vapour density (air = 1): 10.4
Octanol/water partition coefficient as log Pow: 8.73-9.13
Bioaccumulation of this chemical may occur along the food chain, for example in fish. It is strongly advised not to let the chemical enter into the environment because it persists in the environment. The substance may cause long-term effects in the aquatic environment.

NOTES
Halowax is a trade name
for chlorinated naphthalenes. Card has been partly updated in April 2005. See section Occupational Exposure Limits.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

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