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GRAPHITE (NATURAL) ICSC: 0893
October 1997
Plumbago
Black lead
Mineral carbon

PDF file for printing   Explanation of fields
CAS # 7782-42-5 C
RTECS # MD9659600

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID /    FIRE FIGHTING   
FIRE Combustible under specific conditions.
NO open flames.
Powder, water spray, foam, carbon dioxide.
EXPLOSION Finely dispersed particles form explosive mixtures in air.
Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT DISPERSION OF DUST!

Inhalation Cough.
Ventilation, local exhaust, or breathing protection.
Fresh air, rest.
Skin Roughness.
Protective gloves.
Rinse and then wash skin with water and soap.
Eyes
Safety spectacles, or eye protection in combination with breathing protection if powder.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion

Rinse mouth. Rest.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Then wash away with plenty of water. Wash away remainder with plenty of water (extra personal protection: P1 filter respirator for inert particles).


EMERGENCY RESPONSE STORAGE

Separated from strong oxidants. Dry. Keep in a well-ventilated room.

IMPORTANT DATA
PHYSICAL STATE; APPEARANCE:
BLACK FLAKES, LUMPS, POWDER , CHIPS.

PHYSICAL DANGERS:
Dust explosion possible if in powder or granular form, mixed with air.

CHEMICAL DANGERS:
The substance is a strong reducing agent and reacts with oxidants.

OCCUPATIONAL EXPOSURE LIMITS:
TLV: ppm; 2.0 mg/m 3 as respirable dust (ACGIH 1996-1997).
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation.

INHALATION RISK:
Evaporation at 20°C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly.

EFFECTS OF LONG-TERM OR REPEATED EXPOSURE:
Lungs may be affected by repeated or prolonged exposure to dusts , resulting in graphite pneumoconiosis.

PHYSICAL PROPERTIES
Sublimation point: 3652°C
Relative density (water = 1): 2.09-2.23
Solubility in water: insoluble
 

ENVIRONMENTAL DATA


NOTES
See Synthetic graphite CAS 7440-44-0. Synthetic and natural graphite may be mixed and many graphite products contain deliberate additives such as cristobalite, clay, coal, and petroleum products. Natural Graphite is usually found associated with impurities such as mica, iron oxide, granite and free silica. Content can range 2-25%.

IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission

© IPCS 1999
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.



Updated by AS. Approved by EC. Last update: 10.10.2000.