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DIALLYLAMINE ICSC: 0866
November 1998
Di-2-propenylamine
N-2-propenyl-2-propen-1-amine
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CAS # 124-02-7 C 6H 1 1N / (CH 2=CHCH 2) 2NH
RTECS # UC6650000 Molecular mass: 97.2
UN # 2359

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID /    FIRE FIGHTING   
FIRE Highly flammable. Gives off irritating or toxic fumes (or gases) in a fire.
NO open flames, NO sparks, and NO smoking.
Powder, AFFF, foam, carbon dioxide.
EXPLOSION Vapour/air mixtures are explosive.
Closed system, ventilation, explosion-proof electrical equipment and lighting. Do NOT use compressed air for filling, discharging, or handling.
In case of fire: keep drums, etc., cool by spraying with water.
EXPOSURE
PREVENT GENERATION OF MISTS! STRICT HYGIENE!

Inhalation Cough. Shortness of breath.
Local exhaust or breathing protection.
Fresh air, rest. Refer for medical attention.
Skin Redness. Pain.
Protective gloves. Protective clothing.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes Redness. Pain.
Face shield, or eye protection in combination with breathing protection.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Burning sensation. Cough.
Do not eat, drink, or smoke during work.
Rinse mouth. Do NOT induce vomiting. Give plenty of water to drink. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer. (extra personal protection: chemical protection suit including self-contained breathing apparatus).
UN Hazard Class: 3
UN Subsidiary Risks: 6.1 and 8
UN Pack Group: II
Do not transport with food and feedstuffs.

EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-30G33
Fireproof. Separated from strong oxidants, strong acids, food and feedstuffs.

IMPORTANT DATA
PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR.

PHYSICAL DANGERS:
The vapour mixes well with air, explosive mixtures are easily formed.

CHEMICAL DANGERS:
The substance decomposes on burning producing toxic fumes of nitrogen oxides. The solution in water is a medium strong base. Reacts violently with acids and oxidants. Attacks copper, tin, aluminium and zinc.

OCCUPATIONAL EXPOSURE LIMITS:
TLV not established.
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its vapour, through the skin and by ingestion.

INHALATION RISK:
No indication can be given about the rate in which a harmful concentration in the air is reached on evaporation of this substance at 20°C.

EFFECTS OF SHORT-TERM EXPOSURE:
The vapour irritates the eyes, the skin and the respiratory tract.


PHYSICAL PROPERTIES
Boiling point: 112°C
Melting point: -88.4°C
Relative density (water = 1): 0.76
Solubility in water, g/100 ml at 20°C: 9
Vapour pressure, kPa at 20°C: about 2.3
Relative vapour density (air = 1): 3.4
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.06
Flash point: 21°C
Octanol/water partition coefficient as log Pow: 1.08

ENVIRONMENTAL DATA


NOTES


IPCS
International
Programme on
Chemical Safety
Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission

© IPCS 1999
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.



Updated by AS. Approved by EC. Last update: 10.10.2000.