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CAMPHECHLOR ICSC: 0843
April 1997
Toxaphene
Chlorinated camphene (60%)
Polychlorocamphene
PDF for printing Explanation of fields
CAS No: 8001-35-2
RTECS No: XW5250000
UN No: 2761
EC No: 602-044-00-1
    C10H10Cl8 (approx.)
Molecular mass: 413.8 (average)

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.   Foam, powder, carbon dioxide. NO water.
EXPLOSION The explosion hazard will depend on the solvent used in the formulation.   In case of fire: keep drums, etc., cool by spraying with water but NO direct contact with water.
 
EXPOSURE   STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!
Inhalation   Local exhaust or breathing protection. Fresh air, rest.
Skin MAY BE ABSORBED! Redness. Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes Redness. Safety goggles, or face shield. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Convulsions. Dizziness. Nausea. Vomiting. Do not eat, drink, or smoke during work. Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Rest. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Do NOT wash away into sewer. Sweep spilled substance into sealable containers. Carefully collect remainder, then remove to safe place. T Symbol
R: 23/24/25-36/38
S: (2-)13-44
UN Hazard Class: 6.1

Do not transport with food and feedstuffs. Marine pollutant.


EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-61G53b Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Keep in the dark.

IMPORTANT DATA
Physical State; Appearance
YELLOW TO AMBER WAXY SOLID, WITH CHARACTERISTIC ODOUR.

Chemical dangers
The substance decomposes on heating, on burning and/or under influence of alkali, strong sunlight, and catalysts like iron producing toxic fumes. Attacks iron. Incompatible with strongly alkaline pesticides.

Occupational exposure limits
TLV: 0.5 mg/m³ (as TWA) (skin) (ACGIH 1997).
TLV (as STEL): 1 mg/m³ (skin) (ACGIH 1997). PDK not established.

Routes of exposure
The substance can be absorbed into the body through the skin, by ingestion.

Effects of short-term exposure
The substance irritates mildly the skin. The substance may cause effects on the central nervous system, resulting in tremors and convulsions. Exposure at high level may result in death.

Effects of long-term or repeated exposure
This substance is possibly carcinogenic to humans.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Melting point: 65-90°C
Relative density (water = 1): 1.65
Solubility in water: None
Vapour pressure, Pa at 25°C: 53
Relative vapour density (air = 1): 14.3
Octanol/water partition coefficient as log Pow: 3.3
This substance may be hazardous to the environment; special attention should be given to water organisms, some terrestrial species, and birds. In the food chain important to humans, bioaccumulation takes place, specifically in aquatic species.

NOTES
Decomposes near boiling point. Camphechlor is a reaction mixture of chlorinated camphenes containing 67-69% chlorine.
Use of this organochlorine pesticide should be discouraged, except where there is no adequate alternative.
Depending on the degree of exposure, periodic medical examination is indicated.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.
Alltox, Chem-Phene, M 5055, Clor Chem T-590, Crestoxo, Estonox, Fasco-Terpene, Geniphene, Gy-phene, Hercules 3956, Melipex, Penphene, Phenacide, Phenatox, Strobane-T, Toxakil, Toxyphene, Toxon 63 are trade names.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2002
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

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