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[List of Chemicals] [Risk Notes] [Risk Phrases] [Safety Phrases] [Danger Symbols] |  |
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TYPES OF
HAZARD / EXPOSURE |
ACUTE HAZARDS / SYMPTOMS | PREVENTION | FIRST AID / FIRE FIGHTING |
| FIRE |
Highly flammable.
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NO open flames, NO sparks, and NO smoking.
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AFFF, alcohol-resistant foam, powder, carbon dioxide.
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| EXPLOSION |
Vapour/air mixtures are explosive.
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Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Do NOT use compressed air for filling, discharging, or handling.
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In case of fire: keep drums, etc., cool by spraying with water.
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| EXPOSURE |
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| Inhalation |
Cough. Dizziness. Drowsiness. Dullness. Headache. Sore throat.
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Ventilation, local exhaust, or breathing protection.
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Fresh air, rest. Refer for medical attention.
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| Skin |
Dry skin. Redness.
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Protective gloves. Protective clothing.
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Remove contaminated clothes. Rinse skin with plenty of water or shower.
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| Eyes |
Redness. Pain.
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Safety goggles, or eye protection in combination with breathing protection.
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First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
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| Ingestion |
Abdominal pain. Nausea. (see Inhalation).
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Do not eat, drink, or smoke during work.
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Rinse mouth. Do NOT induce vomiting. Refer for medical attention.
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| SPILLAGE DISPOSAL | PACKAGING & LABELLING |
Ventilation. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT wash away into sewer.
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UN Hazard Class: 3
UN Pack Group: II |
| EMERGENCY RESPONSE | STORAGE |
Transport Emergency Card: TEC (R)-30G30 NFPA Code: H2; F3; R0
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Fireproof.
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| IMPORTANT DATA | |
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PHYSICAL STATE; APPEARANCE:
COLOURLESS LIQUID , WITH CHARACTERISTIC ODOUR. PHYSICAL DANGERS: The vapour mixes well with air, explosive mixtures are easily formed. As a result of flow, agitation, etc., electrostatic charges can be generated. CHEMICAL DANGERS: Reacts violently with strong oxidants, strong bases, amines and isocyanates. OCCUPATIONAL EXPOSURE LIMITS: TLV: 200 ppm; 705 mg/m 3 (as TWA); 250 ppm; 881 mg/m 3 (as STEL) (ACGIH 1997). |
ROUTES OF EXPOSURE:
The substance can be absorbed into the body by inhalation of its vapour and by ingestion. INHALATION RISK: A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C. EFFECTS OF SHORT-TERM EXPOSURE: The substance irritates the eyes, the skin and the respiratory tract. Exposure above OEL could cause lowering of consciousness. EFFECTS OF LONG-TERM OR REPEATED EXPOSURE: Repeated or prolonged contact with skin may cause dermatitis. |
| PHYSICAL PROPERTIES | |
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Boiling point: 102°C
Melting point: -78°C Relative density (water = 1): 0.8 Solubility in water, g/100 ml at 20°C: 4 (moderate) Vapour pressure, kPa at 20°C: 1.6 Relative vapour density (air = 1): 3.0 |
Relative density of the vapour/air-mixture at 20°C (air = 1): 1.03
Flash point: 7°C c.c. Auto-ignition temperature: 505°C Explosive limits, vol% in air: 1.5-8.2 Octanol/water partition coefficient as log Pow: 0.91 |
| ENVIRONMENTAL DATA | |
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| NOTES | |
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