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2-NAPHTHYLAMINE ICSC: 0610
May 2003
beta-Naphthylamine
2-Aminonaphthalene
PDF for printing Explanation of fields
CAS No: 91-59-8
RTECS No: QM2100000
UN No: 1650
EC No: 612-022-00-3
    C10H9N
Molecular mass: 143.2

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION         FIRE FIGHTING   
FIRE Combustible. Gives off irritating or toxic fumes (or gases) in a fire. NO open flames. Dry powder, foam, water spray.
EXPLOSION      
 
EXPOSURE   AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!
Inhalation Blue lips or finger nails. Blue skin. Confusion. Dizziness. Convulsions. Headache. Nausea. Unconsciousness. Closed system and ventilation. Fresh air, rest. Refer for medical attention.
Skin MAY BE ABSORBED! (See Inhalation). Protective gloves. Protective clothing. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
Eyes   Face shield, or eye protection in combination with breathing protection if powder. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion (See Inhalation). Do not eat, drink, or smoke during work. Wash hands before eating. Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into covered containers. Carefully collect remainder, then remove to safe place. Do NOT let this chemical enter the environment. Chemical protection suit including self-contained breathing apparatus. T Symbol
N Symbol
R: 45-22-51/53
S: 53-45-61
Note: E
UN Hazard Class: 6.1
UN Pack Group: II

Do not transport with food and feedstuffs.


EMERGENCY RESPONSE STORAGE
Transport Emergency Card: TEC (R)-61S1650 Separated from food and feedstuffs. Well closed.

IMPORTANT DATA
Physical State; Appearance
WHITE TO REDDISH FLAKES, WITH CHARACTERISTIC ODOUR. TURNS RED ON EXPOSURE TO AIR.

Chemical dangers
The substance decomposes on burning producing toxic and corrosive fumes.

Occupational exposure limits
TLV: A1 (ACGIH 2003).
MAK: Carcinogen category: 1; H; (DFG 2002).

Routes of exposure
The substance can be absorbed into the body by inhalation and through the skin and by ingestion.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

Effects of short-term exposure
The substance may cause effects on the blood, resulting in the formation of methaemoglobin. The substance may cause effects on the bladder, resulting in inflammation and blood in urine. Medical observation is indicated. The effects may be delayed. See Notes.

Effects of long-term or repeated exposure
This substance is carcinogenic to humans.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Boiling point: 306°C
Melting point: 110.2-113°C
Density: 1.061 g/cm³
Solubility in water: poor
Relative vapour density (air = 1): 4.95
Flash point: 157°C
Octanol/water partition coefficient as log Pow: 2.28
 

NOTES
Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
Do NOT take working clothes home.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2003
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

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