ICSC 0430 - DIALLYL PHTHALATE

[List of Chemicals] [Risk Notes] [Risk Phrases] [Safety Phrases] [Danger Symbols]

DIALLYL PHTHALATE

ICSC: 0430
_{October 2006}

o-Phthalic acid, diallyl ester
1,2-Benzenedicarboxylic acid, di-2-propenyl ester
DAP

CAS No: 131-17-9
RTECS No: CZ4200000
UN No: 3082
EC No: 607-086-00-4

C₆H₄(CO₂CH₂CHCH₂)₂
Molecular mass: 246.3

TYPES OF HAZARD / EXPOSURE	ACUTE HAZARDS / SYMPTOMS	PREVENTION	FIRST AID / FIRE FIGHTING
FIRE	Combustible. Gives off irritating or toxic fumes (or gases) in a fire.	NO open flames.	Powder, carbon dioxide, foam.
EXPLOSION

EXPOSURE		PREVENT GENERATION OF MISTS!
Inhalation		Ventilation.	Fresh air, rest.
Skin		Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse and then wash skin with water and soap.
Eyes	Redness.	Safety spectacles	Rinse with plenty of water (remove contact lenses if easily possible).
Ingestion		Do not eat, drink, or smoke during work.	Rinse mouth.

SPILLAGE DISPOSAL	PACKAGING & LABELLING
Ventilation. Collect leaking liquid in covered containers. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment.	EU classification Xn Symbol N Symbol R: 22-50/53 S: (2-)24/25-60-61 UN classification UN Hazard Class: 9 UN Pack Group: III GHS classification Signal: Warning Excl mark-Enviro Harmful if swallowed Harmful if inhaled May cause allergic skin reaction Very toxic to aquatic life

EMERGENCY RESPONSE	SAFE STORAGE
NFPA Code: H1; F1; R1; Transport Emergency Card: TEC (R)-90GM6-III	Separated from strong oxidants, strong bases, acids. Store only if stabilized. Store in an area without drain or sewer access.

IMPORTANT DATA

Physical State; Appearance
COLOURLESS LIQUID

Chemical dangers
The substance will polymerize due to heating or in the presence of a catalyst, if not inhibited. On combustion, forms toxic gases. Reacts with strong oxidants, acids and bases.

Occupational exposure limits
TLV not established.
MAK: IIb (not established but data is available) (DFG 2006).

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Inhalation risk
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster.

Effects of short-term exposure
If this liquid is swallowed, aspiration into the lungs may result in chemical pneumonitis.

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization.

PHYSICAL PROPERTIES	ENVIRONMENTAL DATA
Boiling point: 290°C Melting point: -70°C Relative density (water = 1): 1.1 Solubility in water, g/100 ml at 20°C: 0.015 (very poor) Vapour pressure, Pa at 25°C: 0.02 Relative vapour density (air = 1): 8.3 Flash point: 166°C c.c. Auto-ignition temperature: 385°C Octanol/water partition coefficient as log Pow: 3.23	The substance is very toxic to aquatic organisms. It is strongly advised that this substance does not enter the environment.

NOTES

An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.

IPCS
International
Programme on
Chemical Safety

Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2006

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Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

Updated by AS. Approved by GS. Last update: 29.01.2008