ICSC 0226 - BERYLLIUM

[List of Chemicals] [Risk Notes] [Risk Phrases] [Safety Phrases] [Danger Symbols]

BERYLLIUM

ICSC: 0226
_{October 1999}

Glucinium

CAS No: 7440-41-7
RTECS No: DS1750000
UN No: 1567
EC No: 004-001-00-7

Be
Atomic mass: 9.0

TYPES OF HAZARD / EXPOSURE	ACUTE HAZARDS / SYMPTOMS	PREVENTION	FIRST AID / FIRE FIGHTING
FIRE	Combustible.	NO open flames.	Special powder, dry sand, NO other agents.
EXPLOSION	Finely dispersed particles form explosive mixtures in air.	Prevent deposition of dust; closed system, dust explosion-proof electrical equipment and lighting.

EXPOSURE		PREVENT DISPERSION OF DUST! AVOID ALL CONTACT!	IN ALL CASES CONSULT A DOCTOR!
Inhalation	Cough. Shortness of breath. Sore throat. Weakness. Symptoms may be delayed (see Notes).	Local exhaust. Breathing protection.	Fresh air, rest. Refer for medical attention.
Skin	Redness.	Protective gloves. Protective clothing.	Remove contaminated clothes. Rinse skin with plenty of water or shower.
Eyes	Redness. Pain.	Face shield or eye protection in combination with breathing protection if powder.	First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion		Do not eat, drink, or smoke during work. Wash hands before eating.	Rinse mouth. Do NOT induce vomiting. Refer for medical attention.

SPILLAGE DISPOSAL	PACKAGING & LABELLING
Evacuate danger area! Consult an expert! Carefully collect the spilled substance into containers; if appropriate moisten first, then remove to safe place. Chemical protection suit including self-contained breathing apparatus. Do NOT let this chemical enter the environment.	EU classification T+ Symbol R: 49-25-26-36/37/38-43-48/23 S: 53-45 Note: E UN classification UN Hazard Class: 6.1 UN Subsidiary Risks: 4.1 UN Pack Group: II	Unbreakable packaging; put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs.

EMERGENCY RESPONSE	SAFE STORAGE
Transport Emergency Card: TEC (R)-61GTF3-II NFPA Code: H3; F1; R0	Separated from strong acids, bases, chlorinated solvents, food and feedstuffs. Store in an area without drain or sewer access.

IMPORTANT DATA

Physical State; Appearance
GREY TO WHITE POWDER.

Physical dangers
Dust explosion possible if in powder or granular form, mixed with air.

Chemical dangers
Reacts with strong acids and strong bases forming flammable/explosive gas (hydrogen - see ICSC0001). Forms shock sensitive mixtures with some chlorinated solvents, such as carbon tetrachloride and trichloroethylene.

Occupational exposure limits
TLV: 0.002 mg/m³ as TWA, 0.01 mg/m³ as STEL; A1 (confirmed human carcinogen); (ACGIH 2004). Intended change 0.00002 mg/m³ Skin, Inhal. SEN (ACGIH 2005).
MAK: sensitization of respiratory tract and skin (Sah); Carcinogen category: 1; (DFG 2004).

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Inhalation risk
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.

Effects of short-term exposure
The aerosol of this substance is irritating to the respiratory tract. Inhalation of dust or fumes may cause chemical pneumonitis. Exposure may result in death. The effects may be delayed. Medical observation is indicated.

Effects of long-term or repeated exposure
Repeated or prolonged contact may cause skin sensitization. Lungs may be affected by repeated or prolonged exposure to dust particles, resulting in chronic beryllium disease (cough, weight loss, weakness). This substance is carcinogenic to humans.

PHYSICAL PROPERTIES	ENVIRONMENTAL DATA
Boiling point: above 2500°C Melting point: 1287°C Density: 1.9 g/cm³ Solubility in water: none	The substance is very toxic to aquatic organisms.

NOTES

Depending on the degree of exposure, periodic medical examination is suggested.
Do NOT take working clothes home.
Card has been partly updated in October 2005. See sections Occupational Exposure Limits, Emergency Response.
Card has been partially updated in January 2008: see Storage.

IPCS
International
Programme on
Chemical Safety

Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2006

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Updated by AS. Approved by GS. Last update: 29.01.2008