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ZINC OXIDE ICSC: 0208
April 2004
Zinc white
Zinc monoxide
C.I. Pigment White 4
PDF for printing Explanation of fields
CAS No: 1314-13-2
RTECS No: ZH4810000
EC No: 030-013-00-7
    ZnO
Molecular mass: 81.4

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Not combustible.   In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION      
 
EXPOSURE   PREVENT DISPERSION OF DUST!  
Inhalation Sore throat. Headache. Fever or elevated body temperature. Nausea. Vomiting. Weakness. Chills. Muscular pain. Symptoms may be delayed (see Notes). Local exhaust or breathing protection. Fresh air, rest. Refer for medical attention.
Skin   Protective gloves. Rinse and then wash skin with water and soap.
Eyes   Safety goggles. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor.
Ingestion Abdominal pain. Diarrhoea. Nausea. Vomiting. Do not eat, drink, or smoke during work. Rinse mouth. Refer for medical attention.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Sweep spilled substance into containers; if appropriate, moisten first to prevent dusting. Carefully collect remainder, then remove to safe place. Personal protection: P2 filter respirator for harmful particles. N Symbol
R: 50/53
S: 60-61

EMERGENCY RESPONSE SAFE STORAGE
   

IMPORTANT DATA
Physical State; Appearance
WHITE POWDER

Chemical dangers
Reacts violently with with aluminium and magnesium powders, and with chlorinated rubber on heating causing fire and explosion hazard.

Occupational exposure limits
TLV: (as respirable fraction) 2 mg/m³ as TWA; (ACGIH 2004).
TLV: (as respirable fraction) 10 mg/m³ as STEL; (ACGIH 2004).
MAK: (as fume) 1 mg/m³, Respirable fraction; Peak limitation category: I(1); (DFG 2003).

Routes of exposure
The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Inhalation risk
A harmful concentration of airborne particles can be reached quickly especially for zinc oxide fume particles.

Effects of short-term exposure
Inhalation of fumes may cause metal fume fever. The substance as a fume is irritating to the respiratory tract. The effects may be delayed. See Notes.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Melting point: 1975°C
Density: 5.6 g/cm³
Solubility in water: none
 

NOTES
The symptoms of metal fume fever do not become manifest until a few hours have passed.
Card has been partly updated in October 2004. See sections Occupational Exposure Limits, EU classification, Emergency Response.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2004
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

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