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LINDANE ICSC: 0053
April 2007
gamma-1,2,3,4,5,6-Hexachlorocyclohexane
gamma-BHC
gamma-HCH
PDF for printing Explanation of fields
CAS No: 58-89-9
RTECS No: GV4900000
UN No: 2761
EC No: 602-043-00-6
    C6H6Cl6
Molecular mass: 290.8

TYPES OF
HAZARD /
EXPOSURE
ACUTE HAZARDS / SYMPTOMS      PREVENTION      FIRST AID / FIRE FIGHTING
FIRE Not combustible. Liquid formulations containing organic solvents may be flammable. Gives off irritating or toxic fumes (or gases) in a fire.   In case of fire in the surroundings: use appropriate extinguishing media.
EXPLOSION Risk of fire and explosion if formulations contain flammable/explosive solvents.   In case of fire: keep drums, etc., cool by spraying with water.
 
EXPOSURE   PREVENT DISPERSION OF DUST! STRICT HYGIENE!  
Inhalation see Ingestion. Avoid inhalation of fine dust and mist. Local exhaust or breathing protection. Fresh air, rest. Refer for medical attention.
Skin MAY BE ABSORBED! See Ingestion. Protective gloves. Protective clothing. Wear protective gloves when administering first aid. Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention.
Eyes Redness. Face shield or eye protection in combination with breathing protection. First rinse with plenty of water (remove contact lenses if easily possible). Refer for medical attention.
Ingestion Convulsions. Nausea. Dizziness. Headache. Hypersalivation Diarrhoea. Vomiting. Do not eat, drink, or smoke during work. Wash hands before eating. Refer immediately for medical attention. Do NOT induce vomiting. Rinse mouth. Give a slurry of activated charcoal in water to drink. Rest.

SPILLAGE DISPOSAL PACKAGING & LABELLING
Personal protection: P3 filter respirator for toxic particles. Chemical protection suit. protective gloves. Sweep spilled substance into non-metallic sealable containers, then remove to safe place. Do NOT let this chemical enter the environment. EU classification
T Symbol
N Symbol
R: 20/21-25-48/22-64-50/53
S: (1/2-)36/37-45-60-61
UN classification
UN Hazard Class: 6.1
UN Pack Group: III
GHS classification
Signal: Danger
Skull-Health haz-Enviro
Fatal if swallowed
Fatal in contact with skin
Harmful if inhaled dust
May cause harm to breast-fed children
Causes damage to central nervous system
Causes damage to liver through prolonged or repeated exposure
Very toxic to aquatic life with long lasting effects

Do not transport with food and feedstuffs. Severe marine pollutant.


EMERGENCY RESPONSE SAFE STORAGE
Transport Emergency Card: TEC (R)-61GT7-III Provision to contain effluent from fire extinguishing. Separated from bases, metals, food and feedstuffs. Store in an area without drain or sewer access.

IMPORTANT DATA
Physical State; Appearance
WHITE CRYSTALLINE POWDER.

Chemical dangers
On contact with hot surfaces or flames this substance decomposes forming toxic and corrosive fumes. The substance decomposes on contact with bases, producing trichlorobenzene, and on contact with powdered metals.

Occupational exposure limits
TLV: 0.5 mg/m³ as TWA; (skin); A3 (confirmed animal carcinogen with unknown relevance to humans); (ACGIH 2006).
MAK: 0.1 mg/m³; (Inhalable fraction) Peak limitation category: II(8); skin absorption (H); Carcinogen category: 4; Pregnancy risk group: C; BAT issued; (DFG 2006).

Routes of exposure
The substance can be absorbed into the body by inhalation through the skin and by ingestion.

Inhalation risk
A harmful concentration of airborne particles can be reached quickly when dispersed

Effects of short-term exposure
The substance may cause effects on the central nervous system, resulting in convulsions. Exposure may result in death. Medical observation is indicated.

Effects of long-term or repeated exposure
The substance may have effects on the liver. Tumours have been detected in experimental animals but may not be relevant to humans.


PHYSICAL PROPERTIES ENVIRONMENTAL DATA
Boiling point: 323°C
Melting point: 113°C
Relative density (water = 1): 1.87
Solubility in water, g/100 ml at 20°C: 0.0007
Vapour pressure, Pa at 20°C: 0.0012
Octanol/water partition coefficient as log Pow: 3.61- 3.72
The substance is very toxic to aquatic organisms. Bioaccumulation of this chemical may occur in fish. This substance does enter the environment under normal use. Great care, however, should be given to avoid any additional release, e.g. through inappropriate disposal.

NOTES
Depending on the degree of exposure, periodic medical examination is suggested.
Carrier solvents used in commercial formulations may change physical and toxicological properties.
Do NOT take working clothes home.

IPCS
International
Programme on
Chemical Safety
WHO ILO UNEP EC Prepared in the context of cooperation between the International Programme on Chemical Safety and the European Commission
© IPCS 2006
LEGAL NOTICE Neither the EC nor the IPCS nor any person acting on behalf of the EC or the IPCS is responsible for the use which might be made of this information.

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