| CAS #: 74-86-2|
| UN #: 1001
|EC Number: 200-816-9
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Extremely flammable. Gas/air mixtures are explosive.||NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Prevent build-up of electrostatic charges (e.g., by grounding). Use non-sparking handtools. Flame arrester to prevent flash-back from burner to cylinder.||Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water.|
|Inhalation||Dizziness. Lethargy. Headache. Suffocation.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.|
|Eyes||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Do not eat, drink, or smoke during work.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Remove all ignition sources. Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Ventilation.||
According to UN GHS Criteria
|Fireproof. See Chemical Dangers. Cool.|
|Special insulated cylinder.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
|Piping material for this gas must not contain over 63% of copper.
Check oxygen content before entering area.
After use for welding, turn valve off; regularly check tubing, etc., and test for leaks with soap and water.
The technical product may contain impurities which alter the health effects; for further information see ICSC0694 Phosphine.
Symbol: F+; R: 5-6-12; S: (2)-9-16-33
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