Refrigerant gas R1114
| CAS #: 116-14-3|
| UN #: 1081
|EC Number: 204-126-9
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Highly flammable. Cylinder may explode in heat of fire. Gives off irritating or toxic fumes (or gases) in a fire. Risk of fire and explosion on contact with air. See Chemical Dangers. Gas/air mixtures are explosive.||NO open flames, NO sparks and NO smoking. NO contact with air. Closed system, ventilation, explosion-proof electrical equipment and lighting. Use non-sparking handtools.||Evacuate area, fight fires only from an explosion-resistant location. Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with water spray. In case of fire: keep cylinder cool by spraying with water.|
|AVOID ALL CONTACT!|
|Inhalation||Dizziness. Headache. Visual disturbances. Suffocation. Unconsciousness.||Use ventilation.||Fresh air, rest. Seek medical attention if you feel unwell.|
|Skin||ON CONTACT WITH LIQUID: FROSTBITE.||Cold-insulating gloves. Protective clothing.||ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer immediately for medical attention.|
|Eyes||ON CONTACT WITH LIQUID: FROSTBITE.||Wear face shield.||ON FROSTBITE: rinse with plenty of water. Refer immediately for medical attention.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Evacuate danger area! Consult an expert! Personal protection: self-contained breathing apparatus. Remove all ignition sources. Shut off cylinder if possible. Ventilation. Remove gas with fine water spray.||
According to UN GHS Criteria
DANGERExtremely flammable gas
Contains gas under pressure; may explode if heated
May cause cancer if inhaled
May cause damage to kidneys, liver and blood if inhaled
|Fireproof. Cool. Keep in a well-ventilated room. Refer to the manufacturer's instructions for proper storage conditions. Separated from : see Chemical Dangers.|
|Transport only if stabilized.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 8.2 mg/m3, 2 ppm, as TWA; A3 (confirmed animal carcinogen with unknown relevance to humans).
MAK: carcinogen category: 2
|Check oxygen content before entering area.
High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.
If not stabilized, the substance may spontaneously polymerize on contact with air and under the influence of increasing temperature and/or pressure. Consult your supplier.