|m-PHENYLENEDIAMINE||ICSC: 1302 (March 1999)|
| CAS #: 108-45-2
| UN #: 1673
|EC Number: 203-584-7
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire.||NO open flames.||Use water spray, powder.|
|STRICT HYGIENE! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Blue lips, fingernails and skin. Confusion. Convulsions. Dizziness. Headache. Nausea. Unconsciousness.||Use local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||MAY BE ABSORBED! Redness. Further see Inhalation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain.||Wear safety goggles, face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||See Inhalation.||Do not eat, drink, or smoke during work.||Rinse mouth. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: complete protective clothing including self-contained breathing apparatus. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Separated from strong oxidants and food and feedstuffs. Keep in the dark. Well closed.|
|Do not transport with food and feedstuffs.|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C6H8N2 / C6H4(NH2)2
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.1 mg/m3, as TWA; A4 (not classifiable as a human carcinogen).
MAK: skin absorption (H); sensitization of skin (SH); carcinogen category: 3
|The substance is toxic to aquatic organisms.|
|Depending on the degree of exposure, periodic medical examination is suggested.
Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.
See ICSC 0805.
Symbol: T, N; R: 23/24/25-36-43-50/53-68; S: (1/2)-28-36/37-45-60-61
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