|METHYL 2-CYANOACRYLATE||ICSC: 1272 (April 2000)|
|2-Propenoic acid, 2-cyano-, methyl ester
2-Cyanoacrylic acid methyl ester
| CAS #: 137-05-3
|EC Number: 205-275-2
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Above 79°C explosive vapour/air mixtures may be formed.||NO open flames. Above 79°C use a closed system and ventilation.||Use foam, powder, carbon dioxide. NO water. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water.|
|AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Cough. Headache. Sore throat.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||Dry skin. Redness. Pain.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Redness. Pain.||Wear face shield or eye protection in combination with breathing protection.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Do not eat, drink, or smoke during work.|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: face shield and filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Ventilation. Remove all ignition sources. Do NOT wash away into sewer. Absorb liquid in sand or inert absorbent. Let solidify.||
According to UN GHS Criteria
|Separated from incompatible materials. See Chemical Dangers. Well closed. Store only if stabilized.|
|METHYL 2-CYANOACRYLATE||ICSC: 1272|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: C5H5NO2 / CH2=C(CN)COOCH3
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.2 ppm as TWA; 1 ppm as STEL; (DSEN); (RSEN).
MAK: 9.2 mg/m3, 2 ppm; peak limitation category: I(1); pregnancy risk group: D
|Depending on the degree of exposure, periodic medical examination is suggested.
The symptoms of asthma often do not become manifest until a few hours have passed and they are aggravated by physical effort.
Rest and medical observation are therefore essential.
Anyone who has shown symptoms of asthma due to this substance should avoid all further contact.
An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.
Symbol: Xi; R: 36/37/38; S: (2)-23-24/25-26
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