|IRON (III)-o-ARSENITE, PENTAHYDRATE||ICSC: 1241 (April 2017)|
| CAS #: 63989-69-5
| UN #: 1607
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Not combustible. Gives off irritating or toxic fumes (or gases) in a fire.||In case of fire in the surroundings, use appropriate extinguishing media.|
|AVOID ALL CONTACT!|
|Inhalation||Cough. Sore throat. Weakness. See Ingestion.||Use closed system, ventilation or breathing protection.||Fresh air, rest. Refer for medical attention.|
|Skin||Redness. Burning sensation.||Protective gloves. Protective clothing.||Remove contaminated clothes. Rinse and then wash skin with water and soap.|
|Eyes||Redness. Pain.||Wear safety goggles or eye protection in combination with breathing protection if powder.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Abdominal pain. Burning sensation. Diarrhoea. Nausea. Vomiting. Symptoms may be delayed.||Do not eat, drink, or smoke during work. Wash hands before eating.||Rinse mouth. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Vacuum with specialist equipment (See Notes) or carefully sweep into containers. Carefully collect remainder. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
DANGERFatal if swallowed
Causes skin and eye irritation
May cause cancer
Causes damage to organs
Causes damage to organs through prolonged or repeated exposure
May cause long lasting harmful effects to aquatic life
|Separated from food and feedstuffs. Provision to contain effluent from fire extinguishing.|
Put breakable packaging into closed unbreakable container.
Do not transport with food and feedstuffs.
|IRON (III)-o-ARSENITE, PENTAHYDRATE||ICSC: 1241|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
Formula: As2Fe2O6.Fe2O3. 5H2O
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: (as As): 0.01 mg/m3, as TWA; A1 (confirmed human carcinogen); BEI issued.
MAK: (as As): skin absorption (H); carcinogen category: 1; germ cell mutagen group: 3A.
EU-OEL: (inhalable fraction): 0.01 mg/m3 as TWA; (see Notes)
|This substance may be hazardous to the environment. Special attention should be given to plants, air quality and water quality. It is strongly advised not to let the chemical enter into the environment.|
|NEVER use a domestic-type vacuum cleaner to vacuum the substance, only use specialist equipment.
Do NOT take working clothes home.
Depending on the degree of exposure, periodic medical examination is suggested.
The symptoms of poisoning do not become manifest until 0.5 to several hours.
See ICSC 0013 and ICSC 0378.
For the copper smelting sector, the EU OEL value shall apply from 11 July 2023.
Symbol: T, N; R: 23/25-50/53; S: (1/2)-20/21-28-45-60-61; Note: A, 1
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