|PHENYL ISOCYANATE||ICSC: 1131 (May 2002)|
| CAS #: 103-71-9
| UN #: 2487
|EC Number: 203-137-6
|ACUTE HAZARDS||PREVENTION||FIRE FIGHTING|
|FIRE & EXPLOSION||Flammable. Gives off irritating or toxic fumes (or gases) in a fire. Above 51°C explosive vapour/air mixtures may be formed.||NO contact with hot surfaces. NO contact with oxidizing agents. Above 51°C use a closed system, ventilation and explosion-proof electrical equipment.||Use dry powder, carbon dioxide, alcohol-resistant foam. NO water. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water.|
|AVOID ALL CONTACT! IN ALL CASES CONSULT A DOCTOR!|
|Inhalation||Cough. Sore throat. Burning sensation. Laboured breathing. Shortness of breath. Symptoms may be delayed. See Notes.||Use ventilation, local exhaust or breathing protection.||Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention.|
|Skin||Redness. Blisters. Pain. Skin burns.||Protective clothing. Protective gloves.||Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .|
|Eyes||Watering of the eyes. Redness. Pain. Severe deep burns.||Wear safety goggles or face shield.||First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.|
|Ingestion||Burning sensation. Abdominal pain. Shock or collapse.||Do not eat, drink, or smoke during work.||Rinse mouth. Give one or two glasses of water to drink. Do NOT induce vomiting. Refer for medical attention .|
|SPILLAGE DISPOSAL||CLASSIFICATION & LABELLING|
|Personal protection: chemical protection suit including self-contained breathing apparatus. Ventilation. Remove all ignition sources. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.||
According to UN GHS Criteria
|Fireproof. Keep in a well-ventilated room. Dry.|
|Do not transport with food and feedstuffs.|
|PHENYL ISOCYANATE||ICSC: 1131|
|PHYSICAL & CHEMICAL INFORMATION|
Physical State; Appearance
|EXPOSURE & HEALTH EFFECTS|
Routes of exposure
Effects of short-term exposure
Effects of long-term or repeated exposure
|OCCUPATIONAL EXPOSURE LIMITS|
TLV: 0.005 ppm as TWA; 0.015 ppm as STEL; (skin); (SEN).
MAK sensitization of respiratory tract and skin (SAH)
|Anyone who has shown symptoms of asthma due to this substance should avoid all further contact.
The symptoms of asthma often do not become manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation are therefore essential.
Do NOT take working clothes home.
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